纳米金/三聚氰胺修饰电极检测亚硝酸盐

采用电聚合方法制备三聚氰胺(MA)膜修饰玻碳电极(GCE),然后采用原位恒电位沉积法制备金纳米颗粒(Au),并将其修饰于膜电极表面,制得纳米金/三聚氰胺修饰玻碳电极(Au/MA/GCE)。用扫描电子显微镜(SEM)对修饰电极进行表面形貌和元素成分分析。用循环伏安法研究亚硝酸根(NO2-)在该修饰电极上的电化学行为发现,NO2-在0.85 V出现一灵敏的氧化峰。在优化的实验条件下,NO2-在1.0×10-5～1.0×10-3mol/L浓度范围内与其氧化峰电流成线性关系,检测下限为8.9×10-7mol/L。将修饰电极用于实际样品中NO2-的检测,效果良好。     

The influence of Isospin Dependence of In-Medium NN Cross Sections on the Ratio of Emitted Neutrons to Protons in HICs

The influence of isospin dependence of in-medium nucleon-nucleon cross sections on the nip ratios for emitted nucleons in reactions 96Zr-j-96Zr and 96Ru-j-96RH at Eb z 400 AMeV is investigated by means of an improved quantum molecular dynamics model. Our results show that the high energy part of the spectra of the n//p ratios for emitted nucleons is sensitive to the isospin dependence of in-medium nucleon-nucleon cross sections for neutron-rich reaction systems. Therefore, we propose that the nip ratio of emitted high energy nucleons in a very neutron-rich reaction system at several hundreds of AMeV can be taken as sensitive observables to constrain the isospindependence of in-medium nucleon-nucleon cross sections.     

PCA/GC电极同时测定尿酸(UA)和抗坏血酸(AA)

制备聚肉桂酸(PCA)修饰电极(PCA/GC),研究尿酸(UA)和抗坏血酸(AA)在该电极上的电化学行为.结果表明,在UA和AA共存体系中,UA、AA在PCA/GC电极上氧化峰电流增大且峰电位分别负移至50mV、330mV,二者相差280mV,据此可同时检测UA和AA.在pH6.0磷酸盐缓冲液中,UA、AA的氧化峰电流与其浓度分别在2.0×10-6～1.0×10-4mol·L-1、2.0×10-5～6.0×10-4mol·L-1范围内呈线性关系.该电极重现性好,适用于尿样中UA的检测.     

Equation of State for Isospin Asymmetric Matter of Nucleons and Deltas

An investigation on the equation of state of the isospin asymmetric, hot, dense matter of nucleons and deltas is performed based on the relativistic mean field theory. The QHD-Ⅱ-type effective Lagrangian extending to the delta degree of freedom is adopted. Our re,sults show that the equation of state is softened due to the inclusion of the delta degree of freedom. The baryon resonance isomer may occur depending on the delta-meson coupling. The results show that the densities for appearing the baryon resonance isomer, the densities for starting softening the equation of state and the extent of the softening depend not only on the temperature, the coupling strengths but also the isospin asymmetry of the baryon matter.     

Tb4+掺杂Co0.6Zn0.4Ni0.8Fe1.2O4尖晶石红外辐射材料的合成

用常规固相合成法成功地制备出TB4+掺杂Co0.6 Zn0.4 Ni0.8 Fe1.2 O4尖晶石型材料,并通过XRD、HWF-1红外辐射率测量仪测试了材料的微观结构,分析了材料的结构特征与红外辐射性能的关系,发现Tb4+的掺杂导致Tb4+以一定的配位形式进入Co0.6 Zn0.4 Ni0.8 Fe1.2 O4尖晶石体系中,并形成了有限置换型固溶体结构.数据分析可知,温度、压力及Tb4+掺杂浓度都对材料的红外辐射性能存在一定的影响,样品Tb0.50在全波段的积分辐射率为0.75,而在8-14μm波段的平均辐射率最高值可达0.92.     

人肝癌细胞HepG2与正常肝细胞L02的O-糖链的比较分析

以培养的原发性肝细胞癌HepG2细胞和正常肝细胞L02为研究对象, 用细胞裂解液提取总蛋白, 然后采用Carlson还原性β-消除法释放O-糖链, 以阳离子交换柱结合C₁₈柱纯化分离O-糖链, 用电喷雾电离质谱(ESI-MS)和串联质谱(MS/MS)对O-糖链进行序列鉴定, 以β-环糊精为内标对2种细胞系的O-糖链进行定量比较分析. 结果表明, 在肝癌细胞系HepG2中检测到10种O-糖链, 正常细胞系L02中检测到9种O-糖链, 其中9种O-糖链是2种细胞系中共有的, 但HepG2中存在癌细胞中特有的缩短的O-糖链N1A1(NeuAc-GalNAc, sialyl Tn 抗原). t检验结果表明, HepG2与L02相比, 在检测到的10种O-糖链中有5种的含量具有极显著性差异(P<0.01), 2种的含量具有显著性差异(P<0.05).     

并合不变中子质子产额比值角分布各向异性与对称能关系的研究

采用ImQMD05模型分析了非对称反应体系40Ar+197Au,124Sn在中低能区（E_beam=35~100 MeV/u）的半擦边反应的条件下的反应机制,并进一步探索了不同模型参数,如对称能斜率、碰撞参数等,对轻粒子并合不变中子质子产额之比角分布各向异性的影响。通过研究发现:对于出射动能大于每核子10 MeV的动力学出射的轻粒子而言,其并合不变的中子质子产额比值角分布各向异性与对称能的软硬具有明显的关联;碰撞参数对轻粒子动力学发射各向异性的影响最弱。By using the ImQMD05 code,we simulate the 40Ar+197Au,+124Sn at beam energy of 35,50 and 100 MeV/u and semi-peripheral collisions.The reaction mechanism,symmetry potential and Coulomb potential competition around the overlapped neck region and impact parameters effects are investigated for understanding the angular distribution of isospin contents of dynamical emitted light particles.Our results show that the angular anisotropy of the coalescence invariant neutron to proton yield ratios is sensitive to the stiffness of symmetry energy,especially for the dynamical emitted light particles with E_k>10 MeV.     

在重核和超重原子核中量子混沌问题的研究

通过观察和分析重核和超重核中量子谱的统计性质 ,研究有限物理体系中量子混沌的一些问题 .介绍了原子核中量子谱显示的有序 -混沌现象随激发能变化的实验数据 ,研究了超重核体系中量子谱相邻能级间距分布的规则性随体系的依赖关系 ,并预言了稳定的超重体系 .给出了原子核有序混沌相变现象与原子核形变以及原子核转动的依赖关系 ,讨论了量子体系中的对效应对有序 -混沌相变的影响 .最后 ,用有序 -混沌相变的概念解释和理解了核物理中一些重要的实验现象. Some aspects of quantum chaos in a finite system had been studied based on the analysis of statistical behaviors of quantum spectra in heavy and superheavy nuclei. The dependence of the transition from order to chaos on nuclear deformation and nuclear rotatation had been described. The influence of pairing effect on the statistical properties of spectra is also discussed. Some important experiment phenomena in nuclear physics had been understood from the point of view of interplay...     

气态ClO2体积分数与爆炸压力的关系

采用20 L柱状爆炸罐研究了气态ClO2的爆炸特性,得出了气态ClO2分解爆炸的体积分数下限为9.5%,不存在上限。在实验条件下,气态ClO2的爆炸压力随体积分数的增加而增大,体积分数为90%时,最大爆炸超压达到0.64 MPa,且气态ClO2的爆炸压力与其体积分数梯度有关。最大爆炸超压出现的时间随气态ClO2体积分数的增加而缩短,体积分数为10%时,最大爆压在2 195 ms时出现,当体积分数达到70%时,最大爆压出现的时间在10 ms以内,体积分数继续增加,最大爆压出现的时间基本维持在8 ms。     

1-苯基-3-甲基-5-吡唑啉酮(PMP)柱前衍生化寡糖链的HPLC分离及其激光解吸电离质谱分析

以1-苯基-3-甲基-5-吡唑啉酮(PMP)为衍生化试剂对寡糖链进行标记, 用氨水替代氢氧化钠溶液作碱性介质, 衍生化反应后氨水可通过干燥除去, 省去了脱盐处理过程, 衍生化的寡糖可直接进行激光解吸电离质谱分析. 建立起了PMP衍生化寡糖的RP-HPLC分离分析模式, 在此HPLC分析条件下, 可以对标记的寡糖链进行样品分离及制备.