电子束敏感材料的原子尺度结构研究

分子筛和金属有机骨架(MOF)材料以其独特的孔道和骨架结构在催化、 储能、 干燥及净化和吸附分离等领域有着广泛应用, 对其结构的原子尺度表征对于深入理解其构效关系具有重要意义. 但其大孔道结构和有机骨架使得它们对电子束辐照极为敏感, 在常规透射电镜成像模式下结构会很快被破坏变为非晶, 从而无法获得孔道和骨架的原子排列信息. 最近发展起来的基于积分差分相位衬度扫描透射电子显微(iDPC-STEM)技术在电子敏感材料和轻元素组分成像方面展现出明显优势, 使得对多孔骨架材料及烃池物种的表征成为了可能. 本文综述了本课题组近期利用该技术对分子筛和MOF材料原子尺度结构方面的研究. 将iDPC-STEM技术应用到ZSM-5分子筛催化剂中, 实现了对该分子筛的原子级骨架结构的成像分析. 在MOF体系中, 利用该技术观察到MIL-101骨架内部有机连接体与金属节点的配位方式, 在此基础上解析了MIL-101结构中有机配体的连接和金属节点的苯环结构, 并观察了MOF的原子级表面、 界面和缺陷等局域结构特征. 最后对iDPC-STEM技术在原子尺度成像方面的应用潜力进行了总结与展望.     

“端点效应”在一类不等式恒成立问题中的应用与思考

在研究一道不等式恒成立问题的解法时发现,可以由“端点效应”得到符合题意的必要条件,给解决这类问题提供思路与方向,然后结合实例介绍“端点效应”方法在解决这类问题中的应用与思考.     

指对联袂不等式 切线隔离巧证明

在高考及模拟试题中,经常出现含有指数式和对数式的不等式证明或求参数取值范围问题,本文以一道成都市2023届高考模拟试题为例,通过切线法及放缩法找到“隔离函数”,大胆猜想结论,结合导数相关知识和方法巧妙进行证明,发展学生的数学运算等核心素养.     

一道东南地区数学奥林匹克试题的变式探究

第十九届中国东南地区数学奥林匹克中有一道不等式证明题,涉及到实系数一元三次方程根与系数的关系,本文先从代入法入手打开突破口,给出了两种思路自然的证法,在此基础上,对问题的变式做了比较深入的探究.     

AANA随机变量序列的完全矩收敛和积分收敛的等价条件

利用AANA随机变量的Rosenthal型矩不等式,得到了AANA随机变量序列的完全矩收敛和积分收敛的等价条件.这些结果完善了已有的结果.     

第二积分中值定理中值点唯n性渐近性再分析

在确定被积函数单调性的情况下继续研究第二积分中值定理中值点存在唯n(n=1,2,3,…)或充满一个区间的充要条件.在此基础上,又继续研究多中值点当x趋于端点和无穷时的渐近性态,所得结果改进和推广了所列文献的若干结果;最后应用Mathematica数学软件对以上理论结果给出了可视化实例验证.     

Finite Integral Transform Solutions for Free Vibrations of Rectangular Thin Plates With Mixed Boundary Constraints北大核心CSCD

Analytical solutions, with unique research value, can serve as benchmarks for empirical formulas and numerical methods, a tool for rapid parameter analysis and optimization, and a theoretical basis for experimental designs. Conventional analytical methods, e.g., the Lévy solution method, are only applicable to mechanical problems of plates and shells with opposite simply-supported edges, which, however, may fail to obtain analytical solutions for the issues with complex boundary constraints. In recent years, the finite integral transform method for plate and shell problems was developed to deal with non-Lévy-type plates and shells, but it is still infeasible to solve the mixed boundary constrains-induced complex boundary value problems of higher-order partial differential equations. Herein, for the first time, the finite integral transform method was combined with the sub-domain decomposition technique to solve the free vibrations of rectangular thin plates with mixed boundary constraints. The rectangular plate was first divided into 2 sub-domains according to the mixed boundary constraints, and the 2 sub-domains were solved analytically with the finite integral transform method. Finally, the continuity conditions were introduced to obtain the analytical solution of the original problem. Based on the side spot-welded cantilever plates commonly used in engineering, the free vibration problem of a rectangular thin plate with 1 edge subjected to clamped-simply supported constraints and the other 3 edges free, was analyzed. The obtained natural frequencies and mode shapes are in good agreement with those from the finite element method as well as the solutions in literature, thus verifying the accuracy of the proposed method. The solution procedure of the finite integral transform method can be implemented based on the governing equations without any assumption of the solution form. Therefore, this strict analytical method is widely applicable to complex boundary value problems of higher-order partial differential equations for such mechanical problems of plates and shells. © 2023 Editorial Office of Applied Mathematics and Mechanics. All rights reserved.     

用分项比较法巧证数列不等式

本文以部分数学竞赛试题为例,介绍了“分项比较法”在证明数列不等式中的应用,总结解题策略.     

巧借特殊值法，妙解高考真题

巧妙利用特殊值法,借助特殊值的选取,有时可以更加简捷地求解客观题.本文中结合2022年高考真题,剖析特殊值法的巧妙应用,总结特殊值法的解题技巧与规律.     

重方法，求效益：活用函数与方程思想

函数与方程思想是四大数学思想之一,也是高考中的重要考点之一.在解决一些非函数与方程问题时,借助函数或方程的转化,将不等式、数列、三角函数、平面向量、解析几何与立体几何等相关问题转化为对应的函数或方程问题,实现化归与转化,进而利用函数或方程来分析与求解,引领并指导复习备考.