影响高浓度氧化石墨烯分散液流变行为的重要因素及群体平衡动力学分析

氧化石墨烯(GO)片的基面和边缘上存在大量的含氧官能团,能很好地分散在水中,因而具有很好的加工性和广阔的应用前景。在较高浓度范围下,GO水分散液中存在着强烈的竞争性相互作用,从而对流变行为产生较大影响。在本文中,通过稳态、动态等流变实验以及理论分析,研究了pH值、温度和不同的有机溶剂对GO分散液流变行为的影响。结果表明,降低pH值、适当增加温度以及加入吡啶均可促进GO水分散液从粘弹性液体到凝胶态的转变。利用DLVO (Deryagin-Landau-Verwey-Overbeek)理论,探讨了GO片之间的范德华作用力以及双电层排斥作用的相互关系,及其对流变性能的影响。通过群体平衡模型(PBE)分析了GO分散液的屈服应力与体积分数的正相关关系。同时,通过蠕变和松弛实验发现,高浓度的GO分散液中结构变化及流变行为在很多方面与高聚物相似,利用Poyting-Thomson模型能较好地拟合其粘弹性行为。上述研究结果为深入研究复杂的GO分散体系提供理论支撑和实验依据。     

基于DFT密度泛函理论的聚酯热降解反应机理研究

本文应用密度泛函理论（DFT）研究钛系催化剂催化聚酯热降解的反应机理。分别以Ti(OEt)4化合物以及Ti(OEt)3 阳离子化合物为催化剂,探讨了二苯甲酸乙二酯（EDB）解聚反应的Lewis酸催化热降解反应机理（M1机理）和烷氧基配位催化热降解反应机理（M2机理）。结果表明,Lewis酸催化热降解反应机理在两种催化剂下的解聚反应能垒与无催化剂反应非常相似,未表现出明显促进作用;Ti(OEt)3 催化剂在M2机理中明显降低了解聚反应能垒,是聚酯热降解反应的催化活性中心。经轨道相互作用分析发现,阳离子催化剂和反应物EDB之间存在较为明显的轨道相互作用。     

飞机－道面－土基动力耦合系统有限元分析

本文将飞机－道面－土基作为一个相互作用的动力系统，对飞机滑行情况下，弹性半空间地基上刚性道面板的动响应，采用有限元法进行了计算分析。结果表明，本文计算结果与现场实测值吻合很好。由于考虑了飞机和道面之间的耦合作用，避免了实测飞机对道面作用荷载的繁琐工作，因此本文方法具有明显的实用意义。     

FLOW STRUCTURE FORMATION AND EVOLUTION IN CIRCULATING GAS-FLUIDIZED BEDS

The occurrence of heterogeneous flow structures in gas-particle flows seriously affects the gas-solid contacting and transport processes in high-velocity gas-fluidized beds. Particles do not disperse uniformly in the flow but pass through the bed in a swarm of clusters. The so-called “core-annulus“ structure in the radial direction and “S“ shaped axial distribution of solids concentration characterize the typical flow structure in the system. A computational study, using the discrete particle approach based on molecular dynamics techniques, has been carried out to explore the mechanisms underlying formation of the clusters and the core-annulus structure. Based on energybudget analysis including work done by the drag force, kinetic energy, rotational energy, potential energy, and energy dissipation due to particle-particle and particle-wall collisions, the role of gas-solid interaction and inelastic collisions between the particles are elucidated. It is concluded that the competition between gas-solid interaction and particle-particle interaction determines the pattern formation in high-velocity gas-solid flows: if the gas-solid interaction (under elevated pressure) dominates, most of particle energy obtained by drag from the gas phase is partitioned such that particle potential energy is raised, leading to a uniform flow structure. Otherwise, a heterogeneous pattern exists, which could be induced by both particle -particle collisions and gas-solid interaction. Although both factors could cause the flow instability, the non-linear drag force is demonstrated to be the necessary condition to trigger heterogeneous flow structure formation. As gas velocity increases and goes beyond a critical value, the fluid-particle interaction suppresses particle collisional dissipation, and as a consequence a more homogeneous flow regime is formed.     

Dynamic characteristic analysis of a 3-D semi-submerged body as a fluid-structure interaction system

An Arnoldi‘s method with new iteration pattern, which was designed for solving a large unsymmetric eigenvalue problem introduced by displacement-pressure FE (Finite Element) pattern of a fluid-structure interaction system, was adopted here to get the dynamic characteristics of the semi-submerged body. The new iteration pattern could be used efficiently to obtain the Arnoldi‘s vectors in the shift-frequency technique, which was used for the zero-frequency problem. Numerical example showed that the fluid-structure interaction is one of the important factors to the dynamic characteristics of large semi-submerged thin-walled structures.     

ANALYSIS ON ACOUSTICAL SCATTERING BY A CRACKED ELASTIC STRUCTURE

The acoustical scattering by a cracked elastic structure is studied. The mixed method of boundary element and fractal finite element is adopted to solve the cracked structure-acoustic coupling problem. The fractal two-level finite element method is employed for the cracked structure, which can reduce the degree of freedoms (DOFs) greatly, and the boundary element method is used for the exterior acoustic field which can automatically satisfy Sommerfeld‘s radiation condition. Numerical examples show that the resonance frequency is lower with the crack‘s depth increase, and that the effect on the acoustical field by the crack is particularly pronounced in the vicinity of the crack tip. This mixed method of boundary element and finite element is effective in solving the scattering problem by a cracked structure.     

冰排与斜面结构作用时的破断长度分析

研究了冰排与斜面结构的相互作用过程．文中将冰排分为在斜面附近脱离水面部分和较远处漂浮于水面部分两个区域，建立了冰排因弯曲而发生破断的数学模型，根据弯矩分布分析了冰排可能的破断位置，从而得到冰排与斜面结构相互作用时的破断长度解析表达式．结果表明，冰排破断长度既不是冰厚的固定倍数，也不与冰排特征长度直接相关．计算结果与前人实验结果吻合较好，可以为近海冰区抗冰结构的设计提供参考．     

损伤体有效弹性性质的细观分析和不变性描述—— 一个考虑微缺陷相互作用的一般理论模式

通过引进微缺陷相互作用张量，建立了一个二维情况下考虑微缺陷（微裂纹或微孔洞）间相互作用的损伤固体有效弹性性质的一般理论模式模型中考虑了微缺陷的几何形状、取向分布和空间分布所造成的有效柔度张量的各向异性和材料中微缺陷之间的相互作用所引起的损伤柔度张量的高阶效应针对微椭圆孔、微圆孔和微裂纹问题，求得了相互作用张量的解析形式     

三维气泡与自由表面相互作用的直接数值模拟

采用VOF中的PLIC界面重构方法数值模拟了三维气泡在液流中上升并与自由表面相互作用的运动.分别考察了不同初始高度,有无来流及有无再生气泡对气泡上升高度、上升速度、压力及与自由表面相互作用等的影响.结果表明:气泡初始位置越低,顶端上升的高度越大,自由面隆起的范围更广.越靠近自由表面,底部射流横向发展越窄,而向上的压力梯度,气泡上升速度,底部射流上升高度越大,反之则反;但如果底部射流均在接近自由表面以前已横向发展充分,则差别不大.气泡外形、上升高度、破裂时间以及上升速度与来流无关.产生再生气泡后,原生气泡与再生气泡相吸,相互加速对方的上升;自由表面抬升的高度增幅较大,范围拓宽,上升速度也大大增加,且再生气泡越多,自由表面隆起的范围越大.     

土-桩-结构相互作用体系随机地震反应分析

本文采用随机振动理论与有限元技术相结合的方法，以基岩随机地震作为输入，对群桩基础和土-桩-结构相互作用体系进行了三维随机地震反应分析。文中首先以一3X3群桩基础作为分析模型，探讨了桩-土-桩动力相互作用对承台随机地震反应的影响；然后，用单自由度体系模拟上部结构，分析了上部结构惯性对桩基承台随机地震反应的影响。在此基础上，以某桥桥墩为背景，用多自由度体系模拟上部结构，建立了土-桩-结构相互作用体系的三维分析模型，获得了桩基承台的功率谱响应、以及桩顶处的主应力标准差和主应力速率标准差等结果，探讨了群桩顶部各桩主应力标准差的分布规律，得到了一些有应用价值的结果。