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41.
42.
Effect of substrate temperature on microstructure and optical properties of single-phased Ag20 film deposited by using radio-frequency reactive magnetron sputtering method 下载免费PDF全文
Using a radio-frequency reactive magnetron sputtering technique, a series of the single-phased Ag20 films are deposited in a mixture of oxygen and argon gas with a flow ratio of 2:3 by changing substrate temperature (Ts). Effects of the Ts on the microstructure and optical properties of the films are investigated by using X-ray diffractometry, scanning electron microscopy and spectrophotometry. The single-phased Ag20 films deposited at values of Ts below 200℃ are (111) preferentially oriented, which may be due to the smallest free energy of the (111) crystalline face. The film crystallization becomes poor as the value of Ts increases from 100℃ to 225℃. In particular, the Ag20 film deposited at Ts=225℃ loses the (111) preferential orientation. Correspondingly, the film surface morphology obviously evolves from a uniform and compact surface structure to a loose and gullied surface structure. With the increase of Ts value, the transmissivity and the reflectivity of the films in the transparent region are gradually reduced, while the absorptivity gradually increases, which may be attributed to an evolution of the crystalline structure and the surface morphology of the films. 相似文献
43.
Zhilun Lu Qinglin Pan Xiaoyan Liu Yinjiang Qin Yunbin He Sufang Cao 《Mechanics Research Communications》2011,38(3):192-197
The behavior of the flow stress of Al-Cu-Mg-Ag heat-resistant aluminum alloys during hot compression deformation was studied by thermal simulation test. The temperature and the strain rate during hot compression were 340-500 °C, 0.001 s−1 to 10 s−1, respectively. Constitutive equations and an artificial neural network (ANN) model were developed for the analysis and simulation of the flow behavior of the Al-Cu-Mg-Ag alloys. The inputs of the model are temperature, strain rate and strain. The output of the model is the flow stress. Comparison between constitutive equations and ANN results shows that ANN model has a better prediction power than the constitutive equations. 相似文献
44.
A novel synthesized Ag/C fibrous catalyst based on in situ thermally induced redox reaction of PVA/AgNO3 composite fibers was proposed. Utilizing the plasticization and complexation of AgNO3 solution, the melt spinning of PVA/AgNO3 composites was accomplished. Through the in situ thermally induced redox reaction on PVA/AgNO3 composite fibers combined with carbonization of PVA and reduction of Ag+, the synthesized Ag/C fibrous catalyst was prepared with nanosilver particles with average diameter of 130 nm immobilized on the loose microstructural carbon layers. The synthesized Ag/C fibrous catalyst exhibited excellent catalytic activity and reused for at least five cycles for the reduction of 4‐nitrophenol, which may hold great promise in effective and eco‐friendly waste water treatment. 相似文献
45.
Meng Ding Juanjuan Zhou Hongcen Yang Ruya Cao Shouwei Zhang Minghui Shao Xijin Xu 《中国化学快报》2020,31(1):71-76
Graphene-like C3N4/Ag3PO4 photocatalysts are synthesized by calcination and solutions precipitating method.The obtained g-C3N4/Ag3PO4 composites display excellent photocatalytic activity for the degradation of methylene orange(MO),rhodamine B(RhB)and tetracycline(TC)under visible light irradiation.The solutions containing RhB(10 mg/L)and MO(10 mg/L)can be efficiently degraded within15 min and 30 min.Especially,nearly 80%of TC(50 mg/L)is degraded within 20 min.which are much better than those of pure g-C3N4 nanosheets and Ag3PO4,implying that strong interaction and reasonable energy band alignment in the contact interface can effectively transfer the carries.Furthermore,the g-C3N4/Ag3PO4 composites exhibit the improved stability,and only a slight decrease is observed after three recycling runs.Moreover,the impact of inorganic ions and PH values on the degradation performance is rather small.The Z-scheme photocatalytic mechanism of the g-C3N4/Ag3PO4 composites based on the active species trapping experimental is proposed.This work demonstrates the promising applications of the g-C3N4/Ag3PO4 composites in environmental issues. 相似文献
46.
该文构建了一种基于氯金酸刻蚀球形纳米银检测褪黑激素的简单、高灵敏比色探针。纳米银可被氯金酸氧化刻蚀为Ag+,同时还原生成的纳米金沉积在刻蚀后的纳米银表面,导致其溶液的吸光度降低和颜色增强(由黄色变为橘黄色)。当向体系中加入褪黑激素时,氯金酸被还原,抑制了纳米银的刻蚀,从而使得溶液吸光度增加和颜色变浅。结果显示,在0.1 nmol/L~1.0 mmol/L范围内,褪黑激素浓度对数值(lgC)与其吸光度改变值(ΔA)呈良好的线性关系,线性方程为ΔA=0.049 8+0.516lgC,相关系数(R2)为0.996 4,检出限为0.09 nmol/L。该方法成功应用于人体尿液和葡萄中的褪黑激素的测定。 相似文献
47.
Zhoulong Fan Katherine L. Bay Xiangyang Chen Zhe Zhuang Han Seul Park Kap‐Sun Yeung K. N. Houk Jin‐Quan Yu 《Angewandte Chemie (International ed. in English)》2020,59(12):4770-4777
A simple and efficient nitrile‐directed meta‐C?H olefination, acetoxylation, and iodination of biaryl compounds is reported. Compared to the previous approach of installing a complex U‐shaped template to achieve a molecular U‐turn and assemble the large‐sized cyclophane transition state for the remote C?H activation, a synthetically useful phenyl nitrile functional group could also direct remote meta‐C?H activation. This reaction provides a useful method for the modification of biaryl compounds because the nitrile group can be readily converted to amines, acids, amides, or other heterocycles. Notably, the remote meta‐selectivity of biphenylnitriles could not be expected from previous results with a macrocyclophane nitrile template. DFT computational studies show that a ligand‐containing Pd–Ag heterodimeric transition state (TS) favors the desired remote meta‐selectivity. Control experiments demonstrate the directing effect of the nitrile group and exclude the possibility of non‐directed meta‐C?H activation. Substituted 2‐pyridone ligands were found to be key in assisting the cleavage of the meta‐C?H bond in the concerted metalation–deprotonation (CMD) process. 相似文献
48.
In this paper we have measured second order nonlinear refractive index of Ag and Au nano-particles using the moiré deflectometry with a CW He-Ne laser at wavelength of 632.8 nm. The main advantages of this technique are its extreme experimental simplicity and low sensitivity to external distribution in comparison with other interfrometric methods that need very stable experimental set-up. Because of self-focusing (or self-defocusing) that is due to intensity dependent refractive index, presence of sample in the moiré deflectometry set-up lead to rotation of moiré fringes. By moving the sample in set-up we have measured these rotation angles in different displacements from focus point of lens used in this set-up and then we have calculated the nonlinear refractive index of Ag and Au nano-particles using their values. Also we have obtained the sign of n2 regard to the direction of rotations. Consequently by using the Mathematica software we have exhibited the suitable fitness of theoretical curve with experimental results. 相似文献
49.
Xiaomiao HouXiaoling Zhang Shutang ChenYan Fang Jilin YanNa Li Pengxu Qi 《Applied Surface Science》2011,257(11):4935-4940
A facile and novel way was reported here for the synthesis of hydrophobic Ag nanoparticles (NPs), using AgNO3, tri-n-octylphosphine (TOP) and sulfur (S) powder in process. TOP was used as solvent, reducing agent and stabilizer. S could chelate with excessive TOP to form trioctylphosphine sulfide (TOPS), which served as second capping agent. The hydrophobic Ag NPs could be transformed into hydrophilic state through ligand exchange. Furthermore, surface-enhanced Raman scattering (SERS) spectra of 4-aminothiophenol (4-ATP) were obtained on the hydrophobic and hydrophilic Ag NPs modified substrates, indicating that the as-synthesized Ag NPs had great potential for high sensitive optical detection applications. 相似文献
50.
Long Zheng Xia Zhang Xiaomin Ren Jing Gao Lei Shi Xiaolong Liu Qi Wang Yongqing Huang 《Optics & Laser Technology》2011,43(5):960-964
Surface plasmon resonance sensors based on Ag-metalized nanolayer in microstructured optical fibers are theoretically analyzed by using finite element method (FEM). In our simulations we use Drude-Lorentz model to describe the metal dielectric constant. The numerical results show that the sensitivity of Ag-metalized SPR sensor could reach 1167 nm/RIU and corresponding resolution is 8.57×10−5 RIU. Compared to conventional Au-metalized SPR sensors the performance of our device is obviously better. 相似文献