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41.
Shengmei Chen Yiran Ying Shengnan Wang Longtao Ma Haitao Huang Xiaoqi Wang Xu Jin Shengchi Bai Prof. Chunyi Zhi 《Angewandte Chemie (International ed. in English)》2023,62(19):e202301467
Though massive efforts have been devoted to exploring Br-based batteries, the highly soluble Br2/Br3− species causing rigorous “shuttle effect”, leads to severe self-discharge and low Coulombic efficiency. Conventionally, quaternary ammonium salts such as methyl ethyl morpholinium bromide (MEMBr) and tetrapropylammonium bromide (TPABr) are used to fix Br2 and Br3−, but they occupy the mass and volume of battery without capacity contribution. Here, we report an all-active solid interhalogen compound, IBr, as a cathode to address the above challenges, in which the oxidized Br0 is fixed by iodine (I), thoroughly eliminating cross-diffusing Br2/Br3− species during the whole charging and discharging process. The Zn||IBr battery delivers remarkably high energy density of 385.8 Wh kg−1, which is higher than those of I2, MEMBr3, and TPABr3 cathodes. Our work provides new approaches to achieve active solid interhalogen chemistry for high-energy electrochemical energy storage devices. 相似文献
42.
Dr. Zixuan Xu Zhaoyu Wang Dr. Wei Yao Yanhua Gao Yuxin Li Dr. Huifang Shi Prof. Wei Huang Prof. Zhongfu An 《Angewandte Chemie (International ed. in English)》2023,62(24):e202301564
Dynamic room temperature phosphorescence (RTP) materials have potential applications in optoelectronics, which inevitably suffer from poor processability, flexibility or stretchability. Herein, we report a concise strategy to develop supercooled liquids (SCLs) with dynamic RTP behavior using terminal hydroxyl engineering. The terminal hydroxyls effectively hinder the nucleation process of molecules for the formation of stable SCLs after thermal annealing. Impressively, the SCLs show reversible RTP emission via alternant stimulation by UV light and heat. Photoactivated SCLs have phosphorescent efficiency of 8.50 % and a lifetime of 31.54 ms under ambient conditions. Regarding the dynamic RTP behavior and stretchability of SCLs, we demonstrate the applications in erasable data encryption and patterns on flexible substrates. This finding provides a design principle for obtaining SCLs with RTP and expands the potential applications of RTP materials in flexible optoelectronics. 相似文献
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44.
设计了一款体积紧凑、工作在特高频波段的宽带高功率微波源,系统利用24 V蓄电池供电,Marx发生器作为驱动源,采用四分之一波长开关振荡器调制产生宽带电磁脉冲,激励高功率微带平板天线辐射,测试结果显示系统工作中心频率为425 MHz,远场辐射场强-距离积峰峰值为91.5 kV@1 m,该微波源体积尺寸为871 mm×370 mm×330 mm,含电池质量小于43 kg,拓展了宽带高功率微波技术在无人机、机器人等平台的应用前景。 相似文献
45.
《Arabian Journal of Chemistry》2022,15(3):103689
Bi2S3/g-C3N4 (BSCN) samples with different mass ratios of CN to BS were prepared by a facile and practicable hydrothermal method with 2D g-C3N4 nanosheets (CN). The microscopic morphology and structure of pure CN, BS and BSCN were measured by multiple testing methods. Analysis results show that the BSCN was prepared successfully, and the Bi2S3 nanoparticles closely and uniformly adhered to the surface of CN with sheet-like structure. The introduction of Bi2S3 did not change the structure of the CN. The results of the ultraviolet–visible spectroscopic analysis, photoluminescence spectra and electrochemical performance indicated that BSCN showed superior visible-light response compared with CN, and the separation and transfer efficiency of photogenerated carriers was significantly improved. With the decrease of mass ratio of CN/BS, the photocatalytic activity of BSCN initially increased and then decreased for 20 ppm of Rhodamine B solution (RhB), and the Bi2S3/g-C3N4-B with a mass ratio of 8:1 for CN to BS showed optimal photocatalytic performance (98.98%). Furthermore, the Bi2S3/g-C3N4-B exhibited apparent degradation effects (1.021 x10-2, 0.879 x10-2 and 0.793 x10-2 min?1) to three kinds of antibiotics (tetracycline, ciprofloxacin, and oxytetracycline). The BSCN samples still maintained higher degradation efficiency after five cycles of degradation to tetracycline. The capture experiments and the electron spin resonance (ESR) spectra analysis indicated that the h+ and ·O2? played a major role, and ·OH played secondary role during the photocatalytic reaction. 相似文献
46.
G. Yasin S. Ibraheem S. Ali M. Arif S. Ibrahim R. Iqbal A. Kumar M. Tabish M.A. Mushtaq A. Saad H. Xu W. Zhao 《Materials Today Chemistry》2022
Controllable tailoring of metal-free/carbon-based nanostructures tends an encouraging way to enhance the bifunctional activity of electrodes, but a great challenge owing to the sluggish kinetics of oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). Herein, a facile tempted-defects assisted fractionation strategy is presented to synthesize N, S, and O tri-doped metal-free catalyst (DE-TDAP). Due to this effective tempted-defects and heteroatoms interlinking in DE-TDAP, it delivers the lowest overpotential toward both the OER (346 mV) and HER (154 mV) at 10 mA cm?2. Remarkably, the DE-TDAP-electrode carries only a cell voltage of 1.81 V at 10 mA cm?2 for overall water splitting and long-term stability. Considerably, the density functional theory (DFT) calculation exposes that the tailored-defects in tri-doped interlinking could enhance bifunctional catalytic performance devising from lower Gibbs free energy of OER/HER intermediates on active sites. This struggle henceforth provides a perceptive understanding of the synergetic principles of heteroatom-interlinking-tailoring nanostructures in water splitting. 相似文献
47.
Jing Sun Junsen Jia Bo Zhao Jingjing Yang Manjeet Singh Zhongfu An Hua Wang Bingshe Xu Wei Huang 《中国化学快报》2021,32(4):1367-1371
A purely organic D-π-A-π-D type emitter showing thermally activated delayed fluorescence(TADF) and room temperature phosphorescence(RTP) was designed and synthesized by utilizing the benzophenone as an acceptor and the N-phenyl-2-napthylamine as a donor moiety.It exhibits considerable TADF character in doped PMMA film and room temperature phosphorescence with a long lifetime of 74 ms at466 nm in solid state.The devices with the configuration of ITO/Mo_2 O_3(4 nm)/mCP(30 nm)/mCP:x wt%NP2 BP/TmTyPB(60 nm)/LiF(1.5 nm)/AI(100 nm) were prepared by vacuum evaporation to explore their electroluminescent performance.Intere stingly,the non-doped device has obtained near-white emission with a fluorescence emission peak at 475 nm and a phosphore scence emission peak at 563 nm having the CIE coordinate of(0.23,0.32) and the maximum external quantum efficiency of 1.09%. 相似文献
48.
The metabolic disorder of glucose in human body will cause diseases such as diabetes and hyperglycemia.Hence the determination of glucose content is very important in clinic diagnosing.In recent years,researchers have proposed various non-invasive wearable sensors for rapid and real-time glucose monitoring from human body fluids.Unlike those reviews which discussed performances,detection environments or substrates of the wearable glucose sensor,this review focuses on the sensing nanomaterials since they are the key elements of most wearable glucose sensors.The sensing nanomaterials such as carbon,metals,and conductive polymers are summarized in detail.And also the structural characteristics of different sensing nanomaterials and the corresponding wearable glucose sensors are highlighted.Finally,we prospect the future development requirements of sensing nanomaterials for wearable glucose sensors.This review would give some insights to the further development of wearable glucose sensors and the modern medical treatment. 相似文献
49.