(Fe1-xNix)_4N中Ni原子的磁体积和化学键效应

结合X射线衍射和⁵⁷Fe高压MÖssbauer谱,对Ni替代的Fe₄N的结构和超精细参数进行了研究。X射线的结果表明,Ni含量在0≤x≤0.6范围内可形成单相的Υ＇-(Fe_1-xNi_x)₄N化合物,且随着Ni含量的增加,材料的晶格常数很好地满足a₀(x)=3.7905-0.02157x-0.03167x²关系。用MÖssbauer谱区分了Ni原子的磁体积和化学键效应对Fe的超精细磁场和同质异能移的影响,并研究了不同晶位上这两种效应的成分依赖关系,发现两者的作用规律是不同的,但化学键效应对该材料性能的改变起主要作用。     

Characterization and Magnetic Properties of Iron-Based Alloy Antidot Arrays

Fe29Cerl and Fe19Ni81 antidot arrays, with different dimensions, are prepared with the rf magnetron sputtering method onto the porous alumina substrate. The size and shape of antidot arrays are characterized by scanning electron microscopy. The glancing angle x-ray diffraction patterns of Fe29C071 and FelgNi81 antidot arrays indicate the bcc and fcc structures, respectively. The coercivities of both the alloys show abnormal thickness dependence, which are discussed qualitatively by considering the pinning and the thickness effect to the films.     

用Diamond TG/DTA热重/差热综合热分析仪在外加磁场下研究磁性材料相转变

介绍综合热分析仪Diamond TG/DTA在磁性材料研究中的应用.提出在外加磁场作用下,得到样品的热重曲线(TG),由TG曲线分析样品磁性相变及样品居里温度变化的原因,看到稀土铁基金属间化合物样品替代的Co元素的站位和元素之间相互作用对居里温度有很大影响.作为一种测量居里温度的方法,拓展Diamond TG/DTA热分析仪应用研究领域.     

铁镍合金纳米线阵列的制备与穆斯堡尔谱研究

用交流电化学沉积方法在阳极氧化铝模板中成功地制备了直径约16nm,长度4μm的Fe_1-xNi_x(0关键词： 纳米线阵列 穆斯堡尔谱 铁镍合金     

NH4CNS与Fe3(CO)12反应的研究

Fe的簇合物,在温和的条件下(常压,低于200℃),可与各种不饱和分子生成各种有机功能团配位的簇合物。因此,我们想用Fe_3(CO)_(12)与NH_4CNS反应得到含-SCN的羰基铁簇合物。但实验中未得到这种化合物。不过,Fe_3(CO)_(12)与NH_4CNS的反应是一个新反应,穆斯堡尔谱的研究也得到了新信息。因此,我们认为报道研究结果仍然是十分有意义的。     

N~+注入修复外延Fe膜面内六重磁对称

为了研究离子注入对外延磁性薄膜面内磁各向异性的影响,用离子加速器对在有错切角的Si(111)面上外延生长的Fe膜进行了N~+注入实验.随着N~+注入剂量的增加,外延生长的Fe膜的面内磁各向异性逐渐从二重对称改变为六重对称.通过透射电子显微镜和刻蚀实验验证,发现离子辐照改变了Fe膜表面和界面的状态.未辐照Fe膜面内二重磁对称来自于由于Si(111)面的错切使得在薄膜界面和表面处形成的原子台阶.N~+注入的溅射作用使得Fe膜表面的原子台阶被擦除,N~+注入使得缓冲层和Fe膜界面处相互扩散导致界面处原子台阶消失.因此,外延Fe膜在大剂量N~+注入后表现出Fe(111)面诱导的六重磁对称.研究结果对于提高面内磁记录密度有潜在的应用价值.     

Magnetic and Distribution of Magnetic Moments in Amorphous Fe89.7P10.3 Alloy Nanowire Arrays

Binary amorphous Fe89.7P10.3 alloy nanowire arrays in been fabricated in an anodic aluminium oxide template diameter of about 40nm and length of about 3μm have by electrodeposition. Magnetic properties of the samples are investigated by mean of vibrating sample magnetometer, transmission Mossbauer spectroscopy and conversion electron Mossbauer spectroscopy at room temperature. It is found that the nanowire arrays have obvious perpendicular magnetic anisotropy, and are ferromagnetic at room temperature, with its Mossbauer spectra consisting of six broad lines. The average angles between the Fe and 28° at the end of the amorphous Fe89.7P10.3 alloy magnetic moment and the wire axis are about 14°inside nanowire arrays, respectively. The magnetic behaviour is decided by the shape anisotropy and the dipolar interaction between wires. In addition, the magnetic moments distribution is theoretically demonstrated by using the symmetric fanning mechanism of the spheres chain model.     

The effect of substrate on magnetic properties of Co/Cu multilayer nanowire arrays

Ordered Co/Cu multilayer nanowire arrays have been fabricated into anodic aluminium oxide templates with Ag and Cu substrate by direct current electrodeposition. This paper studies the morphology, structure and magnetic properties by transmission electron microscopy, selective area electron diffraction, x-ray diffraction, and vibrating sample magnetometer. X-ray diffraction patterns reveal that both as-deposited nanowire arrays films exhibit face-centred cubic structure. Magnetic measurements indicate that the easy magnetization direction of Co/Cu multilayer nanowire arrays films on Ag substrate is perpendicular to the long axis of nanowire, whereas the easy magnetization direction of the sample with Cu substrate is parallel to the long axis of nanowire. The change of easy magnetization direction attributed to different substrates, and the magnetic properties of the nanowire arrays are discussed.     

非线性偶极-交换表面自旋波的包络孤立子解

介绍了非线性表面自旋波理论研究的新进展 ,并对前人的理论做了推广 ,针对具有非均匀交换各向异性的偶极 交换铁磁介质的非线性表面自旋波的性质和行为进行了较为系统的理论研究. The new progress in the theoretical investigation on nonlinear surface spin waves is reviewed, and the theory mentioned above is generalized. A relatively systematical investigation on the behaviors and properties of the nonlinear surface spin waves in dipole-exchange ferromagnetic media with inhomogeneous exchange anisotropy is developed.