Wavefront correction of Ti:sapphire terawatt laser with varying precision of phase conjugation between deformable mirror and wavefront sensor

The phase conjugation between the deformable mirror and the wavefront sensor in the aberration correction of a terawatt Ti:sapphire laser is studied experimentally and theoretically in this paper. At varying values of phase-conjugation precision, we focus the corresponding beams into spots of the same size of 5.1 μm×5.3 μm with a f/4 parabola in the 32 TW/36 fs Ti:sapphire laser system. The results show that the precision of conjugation can induce an intensity modulation but does not significantly affect the wavefront correction.     

18-冠-6修饰苝酰亚胺衍生物的合成及离子识别行为

合成了一种18-冠-6修饰的苝酰亚胺衍生物(1), 研究了其作为主体对金属离子与阴离子的选择性识别行为. 结果表明, 主体1对Ba²⁺离子具有一定的选择性响应, 并可以通过Ba²⁺调控主体1的堆积行为; 主体1还对F^-离子有选择性响应, F^-与苝酰亚胺单元之间发生了阴离子-π相互作用.     

光辐照对单根In掺杂ZnO纳米线电学性质的影响

通过化学气相沉积方法成功制备了高质量的In掺杂ZnO纳米线.选用325 nm的He-Cd激光器做为光源,进一步探究了单根In掺杂ZnO纳米线的光响应特性.结果表明:紫外光辐照可使金属电极与纳米线之间的有效肖特基接触势垒下降,使接触类型由肖特基接触转变到欧姆接触;撤去紫外光后,电极与纳米线之间的接触可以恢复到未光照时的肖特基接触.讨论了肖特基接触与欧姆接触之间转变的物理机制.     

非晶Nb-Ni薄膜用于Cu与Si之间阻挡层的性能和结构的研究

采用射频磁控溅射法架构了Cu(50 nm)/Nb-Ni(50 nm)/Si异质结,利用四探针电阻测试仪、X射线衍射仪和原子力显微镜等研究了样品在不同温度下高真空退火后的结构及输运性质.结果表明:经退火处理后的样品的方块电阻均小于常温下样品的方块电阻;X射线衍射图谱中,各个退火温度下均没有Nb-Ni结晶峰和其它杂峰出现;在AFM图像中,随着退火温度的上升,样品表面的粗糙度逐渐增加,晶粒的尺寸也在逐渐增大,直到当退火温度达到750℃左右,样品表面布满了岛状晶粒进而导致阻挡层失效.     

交联蚕蛹壳聚糖-谷氨酸阳离子交换树脂的制备

交联蚕蛹壳聚糖-谷氨酸阳离子交换树脂的制备;蚕蛹; 壳聚糖; L-谷氨酸; 阳离子交换树脂     

四苯基卟啉蒽醌化合物的质子化热力学

表观质子化常数;电子吸收光谱;PM3;四苯基卟啉蒽醌化合物的质子化热力学     

Synthesis of hexagonal monocrystal AlN microtubes and nanowires at low temperature

This paper reports that pure hexagonal aluminium nitride microtubes and nanowires growing along the [0001] direction have been successfully synthesized by directly reacting AlClh-AlN, microtubes, nanowires,h-AlN, microtubes, nanowiresProject supported by the National Natural Science Foundation of China (Grant No 10474078) and the Science Foundation of the Education Office of Shanxi Province, China.2006-11-23This paper reports that pure hexagonal aluminium nitride microtubes and nanowires growing along the [0001] direction have been successfully synthesized by directly reacting AlCl3 with NaN3 at low temperature （450℃） under condition of non-solvent system. The grey-white powder of reacting product was characterized by high-resolution transmission electron microscope （HRTEM）, which shows that the powder is long straight-wire morphology with outer diameter from 40nm to 300 nm and length up to several micrometres. The results of both electron diffraction （ED） and x-ray diffraction （XRD） indicate that the AlN microtubes have a pure hexagonal monocrystal tubular structure with the combination of the curled AlN nanobelts. Room-temperature photoluminescence spectrum of the synthesized sample showed an emission peak, which is closely related to the small size of the microtubes.     

La1-xPrxP5O14晶体的研究

用水热法研究了La1-xPrxP5O14(LaPrPP)(0＜x＜1,原子百分含量)晶体的生长,测定了La0.2Pr0.8PP晶体结构为单斜晶系,空间群为P21/c.晶体的密度为3.27g/cm3,分解温度为915℃.分析了室温下晶体在紫外、可见区的吸收、荧光和红外光谱,利用Judd-Ofeld理论计算了PrPP和La0.2Pr0.8PP晶体中Pr3+的实验振子强度,得到一些规律性结果,观察到Pr3+的3P0-3H6跃迁的红色发射很强.     

循环伏安方法制备掺杂二价金属离子的MnO2

循环伏安;掺杂;Cu2+;Co2+;MnO2;比电容     

“黑面包”实验新设计

“黑面包”实验是浓硫酸脱水性性质的经典验证。针对当前该实验中存在的问题,文章对这一实验进行了新设计,将该实验及其气体产物的检验放在较环保的条件下进行,药品用量少,实验现象明显。