一种新的光子多普勒速度频谱分析方法

光子多普勒速度计可给出飞层表面某一速度带内颗粒群速度随时间演化的频谱数据, 在冲击动力学实验尤其是微喷射及其混合研究中得到广泛应用. 本文提出一种新的光子多普勒频谱数据分析方法, 可推断出混合区厚度变化和前端等效颗粒尺度. 利用该方法, 对一些典型状态下喷射混合速度频谱开展分析, 获得了不同冲击压力、气体条件下颗粒度数据, 证实了气体环境下喷射颗粒的气动破碎现象, 以及破碎后尺度与初始条件的依赖性, 为喷射混合物理规律研究提供了重要依据.     

A universal algorithm for calculating the backscattering factor in Auger-electron spectroscopy

We describe a universal Monte Carlo algorithm that can be used for the efficient calculation of backscattering factors (BFs) for quantitative Auger-electron spectroscopy (AES). This algorithm makes use of the continuous slowing-down approximation and the electron stopping power instead of simulation of individual inelastic-scattering events. This approach is attractive because it can be applied to any material with an empirical formula for the stopping power, available data for differential elastic-scattering cross sections, and an empirical formula for inner-shell ionization cross sections. We report BFs for the Si KL₂₃L₂₃, Cu L₃M₄₅M₄₅, Ag M₅N₄₅N₄₅, and Au M₅N₆₇N₆₇ Auger transitions in the corresponding elemental solids. These BFs were calculated for normal incidence of the primary beam, primary energies from near threshold for ionization of the relevant core levels to 20 keV, and Auger-electron emission angles of 10°, 60°, and 80°. We found satisfactory agreement between these BFs and values obtained from a more accurate algorithm in which individual inelastic-scattering events were simulated. Percentage deviations between BFs from the two algorithms were <2% for Au, <5% for Ag, <7% for Cu, and <10% for Si for primary energies likely to be used in practical AES. These deviations arise mainly from our use of stopping powers from the empirical formula rather than more reliable values calculated from experimental optical data.     

日冕物质抛射引起地磁扰动的分类预报

对1997—2003年期间引起地磁扰动的72个加速日冕物质抛射(CME)事件和69个减速CME事件进行了特性分析，并针对经行星际闪烁(IPS)认证的32个加速CME引起的地磁扰动事件和32个减速CME引起的地磁扰动事件分类建立了新的从属函数μ_T和新的磁扰开始时间修正项, 经验证预报效果得到显著提高.对于加速CME引起的地磁扰动事件，磁扰开始时间的预报值T_pre与观测值T_obs比较，相对误差ΔT_pre/T_obs≤10%的事件占总事件数的21.86%；ΔT_pre/T_obs≤30%的事件为78.13%；而ΔT_pre/T_obs>50%的事件为9.36%；对于减速CME引起的地磁扰动事件相对误差ΔT_pre/T_obs≤10%的事件占总事件数的25.00%；ΔT_pre/T_obs≤30%的事件为84.37%；而ΔT_pre/T_obs>50%的事件仅为3.13%.这表明该预报方法对空间灾害性事件的磁扰动的定量预报具有很大的现实可能性. 关键词： 日冕物质抛射 地磁扰动 从属函数     

An electron paramagnetic resonance study of the influence of spermine on the photophysical reactions of tryptophan in aqueous solution at 77–200 K

The influence of the antioxidant spermine of the UV-induced formation of free radicals from tryptophan in frozen aqueous solutions was studied by electron paramagnetic resonance (EPR) instrumentation, and the stability of the radicals was investigated in the range 95–200 K. Without spermine, the tryptophan cation and neutral tryptophan radical were stabilized at 77 K; cations were formed by electron ejection from an excited singlet state, and neutral radicals by hydrogen donation from tryptophan in the triplet state. When present, spermine trapped the ejected photoelectrons; the rates of the two photoreactions of tryptophan were also influenced by spermine. Firstly, at low tryptophan concentrations, the yield of cations was reduced, due to diminished charge transfer from the excited singlet state to the solvation shell. Secondly, at high concentrations, minute additions of spermine enhanced intersystem crossing (which is quenched, in the absence of spermine, by dimerization) and, consequently, the yield of neutral radicals was increased. At 180 K, the electrons trapped by spermine were released and reacted with molecular oxygen to form the superoxide radical; at 190 K, the tryptophan radicals were thermally annealed.     

新型喷射制冷循环的研究

本文提出了利用双元工质在降低压缩比的同时降低蒸发温度的新型喷射制冷循环,由于双元工质低温域蒸发产生的双相流压缩过程也得到了圆满的解决;并且对R11取代物进行了研究．文中介绍了R123,R141b,R123／R141b,R123／R141b和R141b／R142b的实验及数据分析结果．实验结果显示了新型喷射制冷循环的优越性．     

压缩/喷射制冷循环中喷射器引射室的最优压降

建立了蒸气压缩/喷射制冷循环稳定运行时两相喷射器的热力学模型,以常压沸点相差较大的制冷剂为工质,比较了两相喷射器引射室压降最优范围的差异,并在同一工况下,研究了不同工质压缩/喷射制冷循环的性能。结果表明:喷射器引射室压降存在最佳范围使压缩/喷射制冷循环性能接近最优值;在相同工况下不同制冷工质这个最佳范围不相同;在同一工况下,当采用压缩/喷射制冷循环时,不同工质的循环性能系数和单位容积制冷能力相比基本循环均增强了。研究结果为压缩/喷射制冷循环制冷工质的选择及两相喷射器结构的优化设计提供理论参考。     

Acoustic methods for high‐throughput protein crystal mounting at next‐generation macromolecular crystallographic beamlines

To take full advantage of advanced data collection techniques and high beam flux at next‐generation macromolecular crystallography beamlines, rapid and reliable methods will be needed to mount and align many samples per second. One approach is to use an acoustic ejector to eject crystal‐containing droplets onto a solid X‐ray transparent surface, which can then be positioned and rotated for data collection. Proof‐of‐concept experiments were conducted at the National Synchrotron Light Source on thermolysin crystals acoustically ejected onto a polyimide `conveyor belt'. Small wedges of data were collected on each crystal, and a complete dataset was assembled from a well diffracting subset of these crystals. Future developments and implementation will focus on achieving ejection and translation of single droplets at a rate of over one hundred per second.     

水-气界面下低速流体条带的喷射行为

对剪切水－气界面下湍流低速条带的喷射现象进行了细致的观测。喷射过程中，条带的一部分迅速离开水面近区下侵,与深层高速流动发生激烈的相互作用。这意味着条带喷射对水面剪切层中的湍流输运有重要影响。根据流动显示的图像资料获得的定量结果揭示出喷射行为的基本特征，包括喷射频率、喷射流体的轨迹和速度分布等。文中将这些特征与固壁湍流边界层中的对应情形作了比较。实验观察和喷射、猝发事件的时间分布特点表明，低速条带喷射是猝发过程的组成部分，喷射的时间间隔一般显著小于猝发，两种现象的出现都具有很强的随机性。将喷射与湍动能产生率的空间分布作比较，它们的形状极为相似，反映出喷射过程可能是水面附近湍流的主要贡献者。     

人/椅弹射救生系统穿盖过程的数值模拟

拟针对战斗机微爆索预破碎座舱盖弹射救生系统中人/椅系统穿盖过程中弹射通道的畅通性,座舱盖的破坏模式以及人体重要部位的冲击损伤程度。考虑微爆索在舱盖内表面沿中央和四周2种不同的切割布局,建立人/椅系统撞击舱盖的解耦模型,采用非线性动态显式算法对穿盖过程进行了数值模拟。模拟结果表明:第2种布局较第1种布局更有利于形成畅通的弹射通道,也有助于减轻人体的损伤,同时给出2种布局切割槽深度的临界值。研究结果可为弹射救生系统的优化设计和安全生产提供可靠依据。     

The backscattering factor for systems with a non-uniform surface region: Definition and calculations

It has been recently shown that the backscattering factor (BF) in Auger electron spectroscopy (AES) noticeably depends on the in-depth structure of the surface region. This is a particularly important problem in sputter depth profiling monitored by AES since the signal intensity cannot be described with a single BF value. The BF depends on the removed amount of material and thus varies with sputtering time.In the present work, the definition of the BF is generalized to extend its applicability to systems with an in-depth composition profile. The generalized definition of the BF was applied to the special case of a depth profile, i.e. a buried thin layer. It has been shown that the BF for this case is expressed by the excitation depth distribution function (EXDDF) which is equivalent to the “Phi-Rho-Z” function used in electron probe microanalysis (EPMA). Different algorithms for calculating the BF are discussed. Calculations of the BF for buried layer were performed for the Ag M₄N₄₅N₄₅ Auger transition in a thin layer of silver located at different depths in three matrix materials: Si, Cu, and Au. It was found that, indeed, the BF noticeably varies with the depth of the layer in the analyzed volume, although the extent of this variation depends on the matrix material. For Si, the variation is observed for the lowest primary beam energies considered, i.e., 1 and 2 keV. For Cu, a distinct depth dependence of the BF is visible at 10 keV and lower energies, while for Au, the BF varies with depth even at the highest considered energy, i.e. 30 keV.