A rapid in vitro assay of cobalamin in human urine and medical tablets using ICP-MS

A rapid and simple as well as sensitive inductively coupled plasma mass spectrometry (ICP-MS) method for the determination of cobalamin is described. Cobalamin in human urine and medicine tablet solutions was converted on-line into free cobalt ions in acid medium, the cobalt ions were then detected by ICP-MS. Cobalamin was determined by measuring the increase of integral counts per second intensity, which was linear over the cobalamin concentration range of 1.0 × 10⁻¹⁰ g mL⁻¹ to 8.0 × 10⁻⁵ g mL⁻¹, and the limit of detection was 0.05 ng mL⁻¹ (3σ). At the pump rate of 30 rotations per minute, one analysis cycle of cobalamin, including sampling and washing, could be accomplished in 0.5 min with the relative standard deviations of less than 5 %. The proposed procedure was applied successfully in monitoring cobalamin in human urine without any pretreatment process and in rapid determination of cobalamin in multivitamin tablets.     

岩石脆性破坏临界信息综合识别

岩石脆性破坏导致的各种现象可以分为两类：①与物理力学参数和结构特征改变有关,表现为岩石本身变得破碎,承载力降低,变形速率增大,模量变小,渗透率增大,波速参数与电阻率值突变;②与能量释放及物理场参数变化有关,体现在声发射信号激增,电磁辐射强度增加,红外辐射加大。试验和理论分析表明：单轴条件下岩石破裂前临界特征点所对应的应力和岩石峰值应力比值的约在70%与80%之间,均值约为75%。通过本文分析可知,岩石脆性破坏的各种信息与岩石微破裂发展存在特定的关联性,利用综合信息源可以很好的进行脆性破坏临界点的识别。     

PMADQUAT/PSt-PAA聚离子复合物聚集体增强卟啉和富勒烯类衍生物单重态氧产率

采用原子转移自由基聚合(ATRP)法合成了嵌段共聚物聚苯乙烯-聚丙烯酸叔丁酯(PSt-PtBuA), 在酸性条件下水解得到聚苯乙烯-聚丙烯酸(PSt-PAA), 利用核磁共振氢谱(¹HNMR)、凝胶渗透色谱(GPC)等对产物进行了表征. PSt-PAA在Tris-HCl缓冲溶液中(pH=7.0)形成临界聚集浓度(CAC)为0.015 g/L的聚集体. PSt-PAA与聚2-甲基丙烯酰氧基乙基三甲基氯化铵(PMADQUAT)可通过静电相互作用形成聚离子复合物(polyion complex, PIC), 当 m_(PMADQUAT)/m_(PSt-PAA)=3时, 形成的聚离子复合物的CAC为0.005 g/L. 动态光散射(DLS)和透射电镜(TEM)结果表明, 形成聚离子复合物后, 聚集体粒径变小. 聚合物形成聚集体可包载二乙二醇单甲醚修饰的C₇₀(MDG-C₇₀)、原卟啉(PPIX)、四苯基锌卟啉(ZnTPP)和四苯基卟啉(TPP)等光敏剂, 并增强光敏剂在缓冲溶液中的溶解度. 光照条件下, MDG-C₇₀、PPIX、ZnTPP和TPP在聚离子复合物聚集体m_(PMADQUAT)/m_(PSt-PAA)=3的溶液中的单重态氧量子产率分别是在PSt-PAA聚集体溶液中的1.64、2.63、2.60和2.20倍. 而在缓冲溶液中,由于光敏剂的聚集作用,未能检测到单重态氧的产生。研究结果表明,聚离子复合物聚集体能够包载光敏剂,是提高单重态氧产率的一个有效途径.     

方板阶梯辐射体辐射声场的计算及测试

研究了一种同相弯曲振动方板阶梯辐射体。以边长50 mm的方形平板为例,材料为钢,厚度为6mm。其第四阶本征振型的频率为19332 Hz,用同频率的纵振换能器激励其中心,会出现节线与边长成45°夹角的响应(本征振型中无)。为了获得辐射体辐射声场的高指向性,在四个板角与四条节线围成的等腰直角三角形区域加阶梯,可将平板辐射体改进成阶梯辐射体。计算得到阶梯辐射体的指向性比平板辐射体的指向性尖锐,与方板活塞辐射体的指向性相似。实验测试辐射体指向性与计算结果基本一致。进一步计算发现,方板阶梯辐射体与线性尺寸相同的矩形、圆盘阶梯辐射体比较,其频率低,指向性同样尖锐,可望应用于超声测距、料位测试中。      

Quantum-Secret-Sharing Scheme Based on Local Distinguishability of Orthogonal Seven-Qudit Entangled States

The concept of judgment space was proposed by Wang et al. (Phys. Rev. A 95, 022320, 2017), which was used to study some important properties of quantum entangled states based on local distinguishability. In this study, we construct 15 kinds of seven-qudit quantum entangled states in the sense of permutation, calculate their judgment space and propose a distinguishability rule to make the judgment space more clearly. Based on this rule, we study the local distinguishability of the 15 kinds of seven-qudit quantum entangled states and then propose a (k, n) threshold quantum secret sharing scheme. Finally, we analyze the security of the scheme.     

Optical noise-free image encryption based on quick response code and high dimension chaotic system in gyrator transform domain

A novel optical image encryption scheme is proposed based on quick response code and high dimension chaotic system, where only the intensity distribution of encoded information is recorded as ciphertext. Initially, the quick response code is engendered from the plain image and placed in the input plane of the double random phase encoding architecture. Then, the code is encrypted to the ciphertext with noise-like distribution by using two cascaded gyrator transforms. In the process of encryption, the parameters such as rotation angles and random phase masks are generated as interim variables and functions based on Chen system. A new phase retrieval algorithm is designed to reconstruct the initial quick response code in the process of decryption, in which a priori information such as three position detection patterns is used as the support constraint. The original image can be obtained without any energy loss by scanning the decrypted code with mobile devices. The ciphertext image is the real-valued function which is more convenient for storing and transmitting. Meanwhile, the security of the proposed scheme is enhanced greatly due to high sensitivity of initial values of Chen system. Extensive cryptanalysis and simulation have performed to demonstrate the feasibility and effectiveness of the proposed scheme.     

Analytical investigation of response of birefringent fiber Bragg grating sensors in distributed monitoring system based on optical frequency domain reflectometry

When Fiber Bragg gratings (FBGs) are used as strain sensors, both longitudinal and lateral strain can be applied uniformly or non-uniformly over the length of the FBGs. In order for the demodulation of such FBG signal, this paper investigates the response of birefringent FBGs which are monitored by distributed measurement system based on optical frequency domain reflectometry. A numerical model of the distributed measurement system is built based on piece-wise uniform approach, which considers polarization states of propagating lights. The numerical model simulates analytical response of birefringent FBGs especially when birefringence induces power fluctuations in the distributed spectra, which can be noise or new opportunity for sensitive monitoring of birefringence. Simulation results show the relationships between the power fluctuations and the polarization states of the propagating lights. Consequently, appropriate methods of polarization control for sensitive distributed birefringent FBG monitoring are discussed.     

人体肱二头肌静态等长收缩振动模态研究*

本文研究肱二头肌静态收缩振动规律。利用多物理场有限元仿真软件COMSOL建立肱二头肌仿真模型,计算肱二头肌在静态时的本征频率及其模态,同时检测静态负荷弯举的肱二头肌肌声信号。模拟结果显示肱二头肌静态等长收缩振动模态主要有5种,且随振动频率的升高,振动模态趋于复杂。实验测量反映了肱二头肌静态收缩肌声振动能量集中在超低频区。仿真模拟结果与实验统计数据进行对比分析,发现肱二头肌在超低频区域振动的模态在y轴方向受力伸缩的同时,出现x轴和z轴方向的振动。振动主峰频率平均在12 Hz。     

联苯四甲酸及联吡啶构筑的一维链状银(Ⅰ)配合物的合成及晶体结构

采用水热法合成了一个新颖的配合物{[Ag(4,4′-bpy)][Ag2(H3btc)(H2btc)(4,4′-bpy)2].3H2O}n(1)(H4btc=联苯-2,2′,4,4′-四甲酸;4,4′-bpy=4,4′-联吡啶),并对其进行了元素分析、红外光谱和X射线单晶衍射测定。配合物1属于三斜晶系,空间群为P1,a=1.122 51(6)nm,b=1.554 01(8)nm,c=1.774 59(9)nm,β=91.641 0(10)°,V=2.830 8(3)nm3,Z=2,Dc=1.764 g.cm-3,μ=1.113 mm-1,F(000)=1 508,R1=0.045 0,wR2=0.086 2(I>2σ(I))。在1中,一维线性[Ag(4,4′-bpy)]+阳离子链包含在一维{[Ag2(H3btc)(H2btc)(4,4′-bpy)2]-阴离子双链与游离水分子通过分子间氢键组装成的三维超分子结构中。研究了配合物的热稳定性和电化学性质。     

几类Mycielske图的Smarandchely邻点可区别染色

本文根据路和圈、星的Mycielski图的结构性质.利用穷染递推,反证的方法,研究了图M(Pm)和M(Cm),以及M(Sm)的Smarandchely-邻点可区别边染色,得到了相应的边色数,分别给出它们的一种染色方案,推广了文献[9]的结果.