固相微萃取-气相色谱法测定鱼肉中五氯酚

经匀浆的鱼肉样品置于20 mL顶空瓶中,加入氯化钠3.0 g,水1 mL及pH 2.0硫酸溶液9 mL,于40℃超声萃取30 min。将顶空瓶放入带固相微萃取装置的Combi PAL全自动进样器中,于90℃温度下加热20 min后,用85μm聚丙烯酸酯萃取头固相微萃取10 min,于280℃热解3 min,用HP-5毛细管柱分离后,用气相色谱法(电子捕获检测器)测定五氯酚的含量。五氯酚的线性范围在0.05~100μg.L-1之间,方法的检出限(3S/N)为0.02μg.L-1。在3个浓度水平(1.0,5.0,50.0μg.kg-1)上对方法的回收率进行试验,测得回收率在81.2%~89.4%之间,测定值的相对标准偏差(n=6)在4.2%~7.1%之间。     

HPLC同时测定烤肉中的丙烯酰胺和杂环胺

建立了高效液相色谱法同时测定烤肉中丙烯酰胺和杂环胺的新方法.选择适宜的样品前处理方法提取和净化样品,经TSK-gel ODS-80TM柱分离并以配备二极管阵列和紫外检测器的HPLC对丙烯酰胺和杂环胺进行测定.结果表明,该方法的线性范围为0.02-32.0μg/mL,检出限为0.2-0.4ng/g;回收率为67.3％-9...     

A note on a generalized network flow model for manufacturing process

Manufacturing network flow （MNF） is a generalized network model that overcomes the limitation of an ordinary network flow in modeling more complicated manufacturing scenarios, in particular the synthesis of different materials into one product and/or the distilling of one type of material into many different products. Though a network simplex method for solving a simplified version of MNF has been outlined in the literature, more research work is still needed to give a complete answer whether some classical duality and optimality results of the classical network flow problem can be extended in MNF. In this paper, we propose an algorithmic method for obtaining an initial basic feasible solution to start the existing network simplex algorithm, and present a network-based approach to checking the dual feasibility conditions. These results are an extension of those of the ordinary network flow problem.     

Sensitive Fluorescence Detection of Etimicin Based on Derivatives of Formaldehyde and Acetylacetone

A novel fluorescence method for the determination of etimicin is described. Etimicin reacts with acetylacetone and formaldehyde in pH 4.0 Britton-Robinson (B.R.) buffer solution to from a fluorescent substance [I]. Emission spectra of [I] and the reagent blank were overlapped, so the arithmetic emission spectra of the fluorescent substance were obtained by subtracted form the spectra of [I] to the spectra of the reagent blank using the Fluorescence Data Software. There is a linear relationship between the intensity of the arithmetic emission spectra and the concentration of etimicin. Effects of pH, amount of acetylacetone-formaldehyde, and heating time on the determination of etimicin have been examined. Etimicin can be determined over the concentration range of 1.0 to 10.0 μg?mL^?1 with a correlation coefficient of 0.9991. The relative standard deviation (RSD) for 11 repetitive determinations of 5.0 μg?mL^?1 etimicin is 0.22 %. The utility of this method was demonstrated by determining etimicin in commercial samples.     

生物芯片波导共振光散射扫描装置的研制

以光波导(Optical/Light waveguide)作为激发方式,利用共振光散射(Resonance light-scattering,RLS)原理,研制微阵列生物芯片(Microarray)波导共振光散射扫描装置。此装置主要由光源部件、波导激发部件、光电转换部件、机械传动部件和上位机软件组成。其最小扫描分辨率可达5μm,最大扫描范围100 mm。通过使用新的激发方式,有效提高了RLS的信噪比。使用白光作为激发光源,降低了设备的成本。对金纳米粒子标记的单糖芯片、DNA芯片和多肽芯片的检测结果表明,此装置对溶液中的伴刀豆球蛋白凝集素(ConA)和靶标DNA的检出限分别为1 ng/mL和100 pmol/L,对芯片表面固定的多肽的检出限为100 fg,较现有的商品生物芯片扫描仪降低1～2个数量级。本装置结构简单,成本低廉。     

Angular-modulated spatial distribution of ultrahigh-order modes assisted by random scattering

In designing an optical waveguide with metallic films on a nanometer scale, the random scattering by the natural roughness of the thin film is always ignored. In this paper, we demonstrate that for the ultrahigh-order modes (UOMs) in the symmetric metal cladding waveguide, such a scattering leads to drastic variations in their spatial distribution at different incident angles. Owing to the high mode density of the UOMs, the random scattering induced coupling can be easily related to different modes with different propagation directions or wavenumbers. At small incident angles, the intra-mode coupling dominates, which results in a spatial distribution in the form of concentric rings. At large incident angles, the inter-mode coupling plays the most important role and leads to an array-like pattern. Experimental evidence via optically trapped nanoparticles support the theoretical hypothesis.     

基于随机参照点的均值-风险分析

本文依据参照依赖偏好模型提出了基于随机参照点的风险度量方法,进而构建了均值-风险模型,并讨论了该决策方法与随机占优之间的一致性。研究发现,该决策方法不仅与一级随机占优是一致的而且与二级随机占优也是一致的。由于二级随机占优与期望效用理论的一致性,因而所构建的均值-风险模型与期望效用理论也是一致的。     

基于WSAN的道路积水监控系统的设计与实现

强降雨及城市排水系统的老化,使得城市道路低洼处积水严重,对市民人身安全、财产、路基、城市交通产生不容忽视的影响。针对该问题,采用无线传感器/执行器网络（WSAN）技术,设计了道路积水监控系统。该系统分为传感/执行层、网络层和应用层三层。传感/执行层的传感器节点使用超声波传感器采集积水信息,执行器节点使用执行器水泵进行排水;网络层网关及汇聚节点使用ZigBee网络和GPRS网络相结合来实现传感/执行层与应用层之间的数据双向传输;应用层服务器储存采集的道路积水信息,调用百度地图API将实时信息显示在web端,并通过网络层发送指令控制积水区域内的执行器水泵动作,实现闭环控制。该系统能够简洁有效地实现道路积水信息的实时共享,可以实现及时排水,具有实际的应用价值。     

A novel criterion for cluster synchronization of complex dynamical networks with coupling time-varying delays

This paper investigates the cluster synchronization problem for the time-varying delays coupling networks with nonidentical delayed dynamical systems by using pinning control method. We derive some simple and useful criteria for cluster synchronization for any initial values through an effective feedback control scheme and propose an adaptive feedback strategy that adjusts automatically the coupling strength. Finally, some numerical examples are then given to illustrate the theoretical results.