浅海孤子内波对水平纵向相关性的影响*

基于理论和模型仿真对孤子内波存在下的水平纵向相关系数的变化进行了研究。理论上推导出浅海孤子内波存在情况下的声场水平纵向相关系数随时间的变化规律,并且运用二维抛物方程模型（Ram）验证理论推导结果。结果表明,孤子内波会导致水声纵向相关系数的变化,并且水平纵向相关系数的变化是由于简正波的干涉所导致。我们给出特定环境下的水平纵向相关系数随时间变化的结果,当环境中第一、二号简正波占主导地位时,水平纵向相关系数会呈现出周期变化的结果。     

手性金属-有机骨架材料[Mn3（HCOO）4（D-Cam）]n用于气相色谱的分离性能

以具有单一手性链的三维手性金属-有机骨架材料[Mn₃（HCOO）₄（D-Cam）] _n作为固定相,制备了毛细管手性柱 A（30 m×250 μm i.d.）和柱 B（5 m×75 μm i.d.）,用于气相色谱分离. 分别采用扫描电子显微镜和热重分析考察了固定相的涂敷性能和热稳定性. 选用一些外消旋体、 正构烷烃和位置异构体作为测试物用柱B进行了分离,结果表明该固定相对这些有机物具有较好的分离能力.     

An Efficient Three-Dimensional Coupled Normal Mode Model and Its Application to Internal Solitary Wave Problems

We present an efficient three-dimensional coupled-mode model based on the Fourier synthesis technique. In principle, this model is a one-way model, and hence provides satisfactory accuracy for problems where the forward scattering dominates. At the same time, this model provides an efficiency gain of an order of magnitude or more over two-way coupled-mode models. This model can be applied to three-dimensional range-dependent problems with a slowly varying bathymetry or internal waves. A numerical example of the latter is demonstrated in this work. Comparisons of both accuracy and efficiency between the present model and a benchmark model are also provided.     

超高分子量聚乙烯材料的应力松弛研究

采用实验方法研究超高分子量聚乙烯(UHMWPE)材料,在不同温度、应变率和初始应变的条件下进行单轴压缩应力松弛实验,得出松弛应力与时间成非线性关系,且温度越高、应变率越大、初始应变越小,则最终稳定的应力值越小的结论．采用时间分数阶粘弹性模型,结合Boltzmann叠加原理推导出UHMWPE材料在整个加载段及松弛段的应力响应函数,并与实验数据最小二乘拟合．结果表明,时间分数阶Scott-Blair模型能很好地描述UHMWPE材料的粘弹性行为．     

不同含能取代基和桥基对碳桥联四唑-2-氮氧化物的性能影响密度泛函理论研究

Based on the parent tetrazole 2N-oxide, six series of novel carbon-linked ditetrazole 2N-oxides with different energetic substituent groups (-NH₂, -N₃, -NO₂, NF₂, -NHNO₂) and energetic bridge groups (-CH₂-, -CH₂-CH₂-, -NH-, -N=N-, -NH-NH-) were designed. The overall performance and the effects of different energetic substituent groups and energetic bridge groups on the performance were investigated by density functional theory and electrostatic potential methods. The results showed that most of designed compounds have oxygen balance around zero, high heats of formation, high density, high energy, and acceptable sensitivity, indicating that tetrazole N-oxide is a useful parent energetic compound employed for obtaining high energy compounds, even only combined with some very common energetic substituent groups and bridge groups. Comprehensively considering the effects on energy and sensitivity, the -NO₂, -NF₂, -NH-and -NH-NH-are appropriate substituent groups for combining tetrozale N-oxide to design new energetic compounds, while -NH₂, -N₃, -CH₂-CH₂-, and -N=N-are inappropriate.     

基于超材料结构的小型化可调滤波器

为了提高频谱资源的利用率,解决传统滤波器组体积大的问题,利用开口环结构的超材料具有高集成度的特性,设计了一款整体尺寸仅为15mm×20mm的滤波器.基于时域有限积分法分析了开口环结构滤波器的反射系数曲线与电磁参数之间的响应特性,通过在开口环缝隙处加载可调谐的二极管器件,实现了超材料滤波器在X波段(10.9~12GHz)的连续可调,扩展了滤波器的工作频带.该可调谐超材料滤波器的工作带宽达11.0%,通带内回波损耗最小值为32dB,插入损耗最大值为0.38dB,具有高集成度、宽频带、通带内选频特性良好的特点.     

ON THE STUDY OF SILICON NANO-WIRES SELF-ASSEMBLED AS PARTICLES

Two different types of Silicon nano-wires (SiNWs) have been observed by scanning and transmission electron microscopy. One are of free standing SiNWs deposited uniformly on the surface of silicon substrates, and the other are self-assembled into special shaped particles. These SiNWs were synthesized by thermal evaporation of SiO amorphous powders without any metal catalysts in the temperature range of 900-1250℃. Growth history reveals that the self-assembled SiNWs are formed by original nucleation from the surface of amorphous SiO_{x particle matrices through phase separation and silicon precipitation followed by further growth through oxide-assisted vapor-solid reactions. The above results provide a solid experimental support for the oxide-assisted growth model of SiNWs.}     

具有二阶消失矩的多进制对称Coiflet小波基

本文研究了具有二阶消失矩的多进制对称Coiflet小波的构造方法,分析了它们的特征,并给出了算例。     

A DOUBLE-TEMPERATURE-GRADIENT TECHNIQUE FOR THE GROWTH OF PURE C60 SINGLE CRYSTALS FROM THE VAPOR PHASE

Pure C₆₀ single crystals were grown by a sublimation-condensation method in an evacuated dosed quartz tube situated in a double-temperature-gradient furnace. Large C₆₀ single crystals, up to a size of 0.6 mm×1.0 mm×2.0 mm with quite smooth and shiny faces, were obtained. X-ray diffraction, electron diffraction and X-ray morphology were carried out and showed that the quality of large C₆₀ single crystals grown by the double-temperature-gradient technique is excellent. In this paper the experimental results of the growth of large C₆₀ single crystals are reported and the morphological and structural characterizations are discussed in detail.     

过渡金属卡宾配合物 VI:单、双核锰和双核铼的铁硫原子簇卡宾配合物-π-C5H5(CO)2MnC(C6H5)(μ-S)(μ-C6H5S)Fe2(CO)6和[π-C5H5(CO)2MC(C6H5)]2(μ-S)2Fe2(CO)6(M=Mn,Re)的合成和波谱

本文报道了锰和铼的阳离子卡拜配合物[π-C5H5(CO)2MCC6H5]BRr4(M=Mn, Re)分别与(μ-苯硫)六羰基二铁和双(μ-锂硫)六羰基二铁阴离子反应生成标题化合物. 产物的组成和结构由元素分析, IR, ^1H NMR和MS分析, 以及7的单晶X射线结构分析确定的. 文中还对合成和波谱研究结果进行了讨论.