可离去和/或可修饰导向基团辅助的C—H键官能化反应研究进展

过渡金属催化的导向基团辅助的C—H键官能团化反应是当前有机化学的研究热点之一.近年来,利用可离去和/或可修饰导向基团进行C—H键官能团化反应正受到化学家的特别关注并且发展迅速.借助可离去或可修饰导向基团,不但能够大大扩展可利用的碳氢底物,而且对于快速构建分子多样性具有重要作用.作者按不同杂原子(氮、氧、硫、硅等)导向基团进行分类,全面综述了近年来关于可离去和/或可修饰导向基团辅助的各种C—H键官能团化反应的研究进展及合成应用.最后,对该领域所存在的问题和局限性进行了总结,并对今后的发展方向作了展望.     

Ultra-compact variable optical attenuator based on slow light photonic crystal waveguide

An ultra-compact variable optical attenuator based on slow light photonic crystal waveguide with thermooptic effect is demonstrated. Along with power consumption of as low as 30.7 mW, a variable attenuation range of 10 dB is experimentally achieved by shifting the transmission spectrum at about 4.6 nm. The length of the proposed device is only 20 μm.     

Zero-Dispersion Slow Light with Wide Bandwidth in Photonic Crystal Coupled Waveguides

By introducing an adjustment waveguide besides the incident waveguide, zero-dispersion slow light with wide bandwidth can be realized due to anticrossing of the incident waveguide mode and the adjustment waveguide mode. The width of the adjustment waveguide （W2） and the hole radii of the coupling region （r＇） will change the dispersion of incident waveguide mode. Theoretical investigation reveals that zero dispersion at various low group velocity vg in incident waveguide can be achieved. In particular, proper W2 and r＇ can lead to the lowest vg of 0.0085c at 1550 nm with wide bandwidth of 202 GHz for zero dispersion.     

Fluid Sensor Based on Transmission Dip Caused by Mini Stop-Band in Photonic Crystal Slab

We propose a fluid sensor based on transmission dip caused by mini stop-band in photonic crystal slabs. Simulation results show that this novel type of sensors has large detective range （more than 1.5） and relative high sensitivity （4.3×10^-5 in certain conditions）. The central frequency and bandwidth of the mini stop-bands depend on the structure parameters of PC waveguides, which makes it possible to optimize the detective range and detective sensitivity.     

A Silicon Shallow-Ridge Waveguide Integrated Superconducting Nanowire Single Photon Detector Towards Quantum Photonic Circuits

A silicon shallow-ridge waveguide integrated superconducting nanowire single photon detector is designed and fabricated.At the bias current of 11.6μA,4% on-chip detection efficiency near 1550 nm wavelength is achieved with the dark count rate of 3 Hz and a timing jitter of 75 ps.This device shows the potential application in the integration of superconducting nanowire single photon detectors with a complex quantum photonic circuit.     

螺纹管内污垢热阻的对比实验研究

本文对一冷却塔中的7根螺纹管进行了长时间污垢实验研究.螺纹管几何参数范围:螺纹数18～45,螺纹角25°～45°,螺纹高0.33～0.55 mm.污垢是颗粒污垢和析晶污垢的混合物.本文基于普朗特类比,引入修正因子β(β=(A_w/A_(wp))/(A_c/A_(cp)),A_w为润湿面积,A_c为截面积,下标p表示光管),对半经验污垢预测模型进行修正,证明了螺纹管内参数对污垢热阻的形成影响很大,并建立了不同结构参数的螺纹管的统一结垢模型,对工程实际有一定指导意义.     

Erratum： Experimental Study on Preparation Efficiency of Microstructured-Fiber Based Heralded Single-Photon Source at 1.5 μm [Chin. Phys. Lett. 26（2009）034206]

As the definition in the Letter, the preparation efficiency should be calculated according to Eq. （2）. However, the data in Fig. 4 were not divided by ηΩSPD2 = 0.15, while all the pertinent discussion is correct. We correct this mistake and show the revised figure here.     

Frequency locking,quasiperiodicity,and chaos in dual-frequency loss-modulated erbium-doped fiber lasers

Dynamic behaviors of the erbium-doped fiber laser （EDFL） with dual-frequency loss modulation are experimentally investigated. Frequency-locked states with their winding numbers which form the devil＇s staircase are observed in this kind of lasers. In the unlocked regions, the output state changes from quasiperiodicity to chaos under increasing modulation index, which demonstrates a different route to chaos from the conventional loss-modulated EDFLs with a single modulation frequency. The chaos output in the dual-frequency loss-modulated EDFLs shows less harmonic components of the modulation frequency in the corresponding power spectrum, indicating the improvement of the randomness of the chaotic signals.     

损耗调制型掺铒光纤环形激光器混沌现象的实验研究

报道了损耗调制型掺铒光纤环形激光器中的混沌现象.在单频损耗调制型掺铒光纤环形激光器中,改变调制频率或调制电压,观察到倍周期分岔和阵发两种进入混沌途径的共存现象,与抽运调制型掺铒光纤环形激光器的实验结果相一致.提出了一种采用两个正弦信号驱动的损耗调制型掺铒光纤环形激光器,在调制信号频率比近似等于黄金分割数和白银分割数时,增加调制电压,发现激光器通过准周期途径进入混沌.当调制信号两频率比不同时,发生转变所需的调制电压也不同. 关键词： 掺铒光纤环形激光器 混沌 倍周期分岔 准周期     

PbI2对远红外Te基硫系玻璃光学性能的影响

用传统的熔融淬冷法制备了一系列新型Ge-Te-PbI₂硫系玻璃,并且讨论了玻璃的形成区域. 利用X射线衍射(XRD)、差热分析(DTA)、可见/近红外吸收光谱、红外透过光谱等技术,研究重金属卤化物PbI₂对Ge-Te硫系玻璃组成、结构和性能的影响. 利用Tauc方程计算了样品的直接和间接光学带隙,根据金属标准和能量带隙理论讨论了玻璃光学带隙与组分变化的关系. 结果表明:PbI₂的引入,提高了Te玻璃的形成能力,而且玻璃的热稳定性良好;随着PbI₂含量的增加,玻璃的密度和折射率均增大,光学带隙减小,短波吸收截止边发生红移,玻璃的红外截止波长基本不变,达到了25 μm. 该系列玻璃可用于制备远红外长波波导器件. 关键词： Te基玻璃 2')" href="#">PbI₂ 光学带隙 红外光谱