以含有阿魏酸和没食子酸的PAM纤维诱导制备聚苯胺纳米棒结构材料

为了研究化感物质的缓释载体材料, 分别以含有阿魏酸和没食子酸的聚丙烯酰胺(PAM)纤维诱导, 采用化学氧化聚合法, 以苯胺为单体, 过硫酸铵为氧化剂, 分别合成了阿魏酸、没食子酸掺杂的聚苯胺(PANI)纳米结构材料. 通过红外光谱(IR)、X射线粉末衍射(XRD)以及电子扫描电镜(SEM)对掺杂态PANI的结构和形态进行了表征. 结果表明, 所制备材料确为阿魏酸、没食子酸掺杂的PANI. SEM研究结果表明, PANI的形态表现为纳米棒状, 直径在200~300 nm范围内. 另外, 对纤维中酸含量以及不同氧化剂和苯胺单体摩尔比对PANI电导率的影响进行了探讨.     

原子吸收光谱分析中溶样方法研究现况

本文就近年来原子吸收光谱分析溶样方法的研究作了回顾和展望。同时重点讨论了微波溶样技术的原理，体系和方法。针对生物样品和食品样品的溶样方法予以介绍。     

Photonic crystal waveguides and their applications

Two-dimensional （2D） slab photonic crystal waveguides （PCWGs） on silicon-on-insulator （SOI） wafer were designed and fabricated. Full photonic band gap, band gap guided mode, and index guided mode were observed by measuring the transmission spectra. Mini-stop-bands in the PCWG were simulated with different structure parameters. Coupling characteristics of PCWG were investigated theoretically considering the imperfections during the fabrication process. It was found that suppressing power reservation effect can realize both short coupling length and high coupling efficiency.     

Multiwavelength Raman fiber ring laser with the spectrum profile broadened by parametric four wave mixing in highly nonlinear dispersion-shifted fibers

Stable continuous wave (CW) multiwavelength fiber lasers have been investigated extensively in recent years due to their wide applications in wavelength division multiplexing (WDM) optical communication systems, fiber sensing, fiber-optical components testing, and so on[1]. The initial attention was focused on the rare- earth-doped fiber lasers, especially on erbium-doped fiber (EDF) lasers (EDFLs), where special means are required for stable multiwavelength operation due to the relatively…     

压力诱导酌拓扑绝缘体化合物Bi2Te3常压相的超导性

通过高压电阻测量,发现了拓扑绝缘体化合物BizTe3压力诱导的超导性,在3-6GPa的压力范围内,超导临界温度L约为3K．高压下原位同步辐射的结果证明这个超导相来源于常压相结构．通过霍尔效应的测量,发现超导的Bi2Te3样品的载流子为P型．对高压同步辐射结果Reitveld精修得到的晶格参数和原子位置,并以此进行第一性...     

中红外空心Bragg光纤的制备及在气体传感中的应用

空心Bragg光纤可广泛用于气体传感, 但要求它的传输通带处于中红外波段, 以便与待测气体的基频吸收峰匹配. 本文提出了空心Bragg光纤传输通带的一种设计方法与波长控制工艺, 可以实现传输通带在2.5-12 μ m内任意波长的空心Bragg光纤的制备. 实验制备出一阶传输通带分别在10.6 μ m和 3.3 μ m的光纤样品, 利用截断法测量出其一阶传输通带损耗分别为5.9 dB/m和8.8 dB/m. 利用在传输通带在3.3 μ m的样品中注入和排出甲烷/氮气混合气体, 观察到了光纤样品透射谱随注入气体浓度的变化, 并用指数稀释法初步测量了该系统的浓度探测极限约为26 ppm, 验证了该光纤应用于气体传感的可行性.     

红外和拉曼光谱的煤灰矿物组成研究

研究煤灰中矿物质的性质通常从矿物组成的表征入手。为了分析两种高硅铝煤灰的矿物成分,采用傅里叶变换红外光谱(FTIR)、拉曼光谱和X射线衍射(XRD)技术对煤灰样进行了测试和综合表征,将FTIR和拉曼光谱的分析结果与XRD进行了比较。FTIR结果表明,在1 100~1 000 cm-1范围内高硅铝煤灰出现最强的特征峰,例如石英峰(1 089 cm-1)和偏高岭石峰(1 042 cm-1),它们都归属于Si-O伸缩振动。对原始红外谱图进行二阶导数处理后,可获得重叠峰的峰位,有助于更完整的解析矿物吸收峰,从而获得更丰富的矿物组成信息。煤灰中硬石膏的红外和拉曼光谱发现,在1 157,1 126和674 cm-1的拉曼光谱峰与在1 151,1 120和678 cm-1的红外光谱峰振动模式分别相同且峰位接近,还存在一些完全不同的拉曼光谱与红外光谱峰,表明这两种光谱存在互补性。尽管煤灰中锐钛矿含量很低,但由于Ti-O的极化率很高,因此拉曼光谱显示锐钛矿的144 cm-1峰远远强于石英的461 cm-1峰。XRD结果表明,煤灰中主要存在石英、云母、赤铁矿、硬石膏和未知的无定形相矿物,FTIR和拉曼光谱综合分析的结果表明除了这些矿物,还存在偏高岭石、无定形氧化硅、长石、方解石和锐钛矿等。在定性分析方面,将FTIR和拉曼光谱结合起来比XRD单独获得的矿物组成信息更为详细。     

一种用于均匀照明的衍射光学元件设计的快速模拟退火法

介绍了一种适用于均匀照明的衍射光学元件设计的自洽迭代和优化混合的快速模拟退火法,它引入Tsallis正则分布以及相应的效用函数思想,可以在接近1%的时间内得到和传统模拟退火法有着相同均方差(MSE)的理想模拟结果.     

Experimental Study on Preparation Efficiency of Microstructured-Fibre Based Heralded Single-Photon Source at 1.5μm

We present an experimental study on the microstructured-fibre （MSF） based heralded single photon source （HSPS） at 1.5 μm. The preparation efficiency is measured to be 8.7% under room temperature. The analysis of the experimental results shows that the preparation efficiency can be improved up to 22.9% by the Raman noise suppression with fibre cooling under the experimental setup parameters＇. Further efficiency improvement could be achieved by improving the collection efficiency and reducing dark counts of single photon detectors （SPDs）. The experimental results and analysis show great potential applications of the MSF in high efficient HSPSs.     

Slow Light by Two-Dimensional Photonic Crystal Waveguides

A simple and effective way to measure the group velocity ofphotonic crystal waveguides （PCWGs） is developed by using a fiber Mach-Zehnder interferometer. A PCWG with perfect air-bridge structure is fabricated and slow light with group velocity slower than c/80 is demonstrated.