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21.
摘要 藉助模拟强度精修将九个镧系络合物晶体结构的空间群作了修正 .( 1) NaN[Nd(DMSO)5(H2O)3]Cl3· 3H2O从 P1修正为 P;( 2) Er(ClO4)3· 6(CH3)2NC(O)N(CH3)2从 P修正为 R;( 3) Nd(O3SCF3)3· DMF· 6H2O从 P1修正为 R3m;(4)[NaNCCH3][Nd{S2CN(CH2CH3)2}4]从 P修正为 C 2/c;(5)[(CH3)2NCS2]3La· 2DMSO从 Cc修正为 C 2/c;( 6) Yb(C9H7)2· 2THF从 Cc修正为 C 2/c;( 7) [(C6H5)3Ge]2Yb· 4THF从 P21修正为 P 2;(8)TlPr(C36H44N4)2从 Pna2,修正为 Pnma;(9)[CuLaSm(C4O4)4(H2O)16]· 2H2O从 P2修正为 P2.( 8)、( 9)两个络合物结构从非心修正到有心时,不仅改进了键长与键角值,而且影响到分子结构特征的描述 . 相似文献
22.
Ba—La—O—(F)催化剂和碱性及其OCM反应性能 总被引:2,自引:0,他引:2
采用XRD,TPD和高温原位IR光谱对La2O3,BaO/La2O3,BaF2/La2O3,LaOF和LaOF等催化剂的组成、结构和CO2在催化剂上的吸附状况进行了表征,并结合催化剂性能评价结果对该系列催化剂的碱性及其与OCM反应性能的关系进行了考察。结果表明,催化剂OCM反应性能与其酸碱性的强弱无简单的对应关系. 相似文献
23.
Hui Ming Jin Adriana Felix Majorri Aroyave 《中国化学快报》2007,18(5):577-580
The isothermal and cyclic oxidizing kinetics of Co-40Cr alloy and its lanthanum ion-implanted samples were studied at 1000℃ in air by thermal-gravity analysis (TGA). Scanning electronic microscopy (SEM) and transmission electronic microscopy (TEM)) were used to examine the oxidized film's morphology and the structure after oxidation. Secondary ion mass spectrum (SIMS) method was used to examine the binding energy change of chromium caused by La-doping and its in?uence on formation of Cr2O3 film. Laser Raman spectrum was used to examine the tress changes within oxidized films. It was found that lanthanum implantation remarkably reduced the isothermal oxidizing rate of Co-40Cr and improved the anti-cracking and anti-spalling properties of Cr2O3 film. The reasons were that the implanted lanthanum reduced the grain size and internal stress of Cr2O3 oxide, increased the high temperature plasticity of oxidized film. Lanthanum mainly existed in the outer surface of Cr2O3 film in the forms of fine La2O3 and LaCrO3 spinel particles. 相似文献
24.
Thermodynamic properties of complex oxides in the La-Ni-O system 总被引:1,自引:0,他引:1
Complex oxides La2NiO4+δ, La3Ni2O7−δ, La4Ni3O10−δ and LaNiO3−δ, the members of Ruddlesden-Popper series Lan+1NinO3n+1, were prepared using citrate precursors. The stability range of LaNiO3−δ in air as well as the oxygen nonstoichiometry of La3Ni2O7−δ and La4Ni3O10−δ as a function of temperature and oxygen partial pressure was determined by means of thermogravimetric technique. Decomposition temperatures of La3Ni2O7−δ, La4Ni3O10−δ and LaNiO3−δ in air were determined by conductivity measurement method. The boundary of stability for La4Ni3O10−δ was determined by EMF measurements of galvanic cell with oxygen conducting solid electrolyte. The isothermal (1400 K) projection of La-Ni-O system phase diagram to the plane “log(PO2)-relative mole fraction of metal components” was suggested. 相似文献
25.
26.
Impedance spectroscopy was used to study the oxygen reaction kinetics of La0.8Sr0.2MnO3 (LSM)-based electrodes on Y2O3-stabilized ZrO2 (YSZ) electrolytes. Three types of electrodes were studied: pure LSM, LSM–YSZ composites, and LSM/LSM–YSZ bilayers. The electrodes were formed by spin coating and sintering on single-crystal YSZ substrates. Measurements were taken at temperatures ranging from 550 to 850°C and oxygen partial pressures from 1×10−3 to 1 atm. An arc whose resistance Rel had a high activation energy, Ea=1.61±0.05 eV, and a weak oxygen partial pressure dependence, (PO2)−1/6, was observed for the LSM electrodes. A similar arc was observed for LSM–YSZ electrodes, where Rel(PO2)−0.29 and the activation energy was 1.49±0.02 eV. The combination of a high activation energy and a weak PO2 dependence was attributed to oxygen dissociation and adsorption rate-limiting steps for both types of electrodes. LSM–YSZ composite cathodes showed substantially lower overall interfacial resistance values than LSM, but exhibited an additional arc attributed to the resistance of YSZ grain boundaries within the LSM–YSZ. At 850°C and low PO2, an additional arc was observed with size varying as (PO2)−0.80 for LSM and (PO2)−0.57 for LSM–YSZ, suggesting that diffusion had become an additional rate limiting step. Bilayer LSM/LSM–YSZ electrodes yielded results intermediate between LSM and LSM–YSZ. The results showed that most of the improvement in electrode performance was achieved for a LSM–YSZ layer only ≈2 μm thick. However, a decrease in the grain-boundary resistance would produce much better performance in thicker LSM–YSZ electrodes. 相似文献
27.
Zhen-Hai Gan 《Analytica chimica acta》2004,511(2):239-247
Chronoamperometry based on the “controlling-diffusion layer” concept of the convective system was used to assay the activity of lactate dehydrogenase (LDH) on a bare glassy carbon (GC) electrode and a GC electrode modified by a single-wall carbon nanotube (SWNT) film. The effects of lanthanum ion, oxalic acid, and nicotine on the LDH activity were monitored. Analysis of the experimental results revealed that the single-wall carbon nanotubes could markedly increase the activity of LDH. The activation and inhibition were characterized by three quantities: the real initial reaction rate (V0) and the maximum reaction rate (Vmax) of the enzyme-catalyzed reaction and the Michaelis-Menten constant (Km). Tapping mode atomic force microscopy (AFM) images and the Raman spectra unambiguously demonstrated that the single-wall carbon nanotubes could interact with the enzyme LDH while the SWNT-modified electrode was under the potential control. In this case, the activation of SWNT was attributed to the interaction of SWNTs with the enzyme. 相似文献
28.
天然水中微量稀土元素镧的流动注射在线预浓集ICP光谱法测定 总被引:1,自引:0,他引:1
本文采用P507萃淋树脂为固定相,应用流动注射(FI)在线预浓集技术,建立了镧的ICP发射光谱分析方法,对天然水中的微量镧进行了测定,获得满意结果。 相似文献
29.
本文以3-甲基苯甲酸为配体,合成了与三价稀土镧离子的固体配合物LaL3.H2O,并对该配合物进行了元素分析,红外光谱,UV光谱,TG-DTA,HNMR等的测试与表征。该配合物属螯合双齿配位。 相似文献
30.