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71.
有机溶剂对镧和钇ICP光谱信号的增敏机理研究 总被引:2,自引:0,他引:2
本文考察了有机溶剂(乙酸丁酯)及有机试剂(PMBP)引入ICP-AES对稀土元素镧和钇光谱信号的影响。实验结果表明,有机溶剂的引入明显增大了待测物的传质效率,从而导致分析灵敏度的改善。与水相相比,有机相的引入对ICP激发温度未产生明显影响,但使线对强度比(LogI^ /I)增强,有利于待测物的电离。 相似文献
72.
Carlos Vázquez-Vázquez M. Arturo López-Quintela 《Journal of solid state chemistry》2006,179(10):3229-3237
The synthesis of La1−xAxMnO3 (A=Ca, Sr, Ba) nanoparticles in nonaqueous solvents has been studied. For this solvothermal procedure benzyl alcohol and acetophenone were chosen as reaction media. After this treatment in mild conditions a precipitate was obtained, which, however, can be annealed to the crystalline perovskite structure. Our results show that acetophenone is more suited to obtain the clean pervoskite phase than benzyl alcohol. 相似文献
73.
74.
75.
LaB6-ZrB2共晶复合材料的组织特征及控制 总被引:2,自引:0,他引:2
用电弧炉和电子束悬浮区熔炉法制备了LaB6ZrB2共晶复合材料,并用SEM和TEM方法对其显微组织进行了研究。结果表明,LaB6ZrB2形成纤维状共晶组织,控制凝固条件可得到定向排列的组织,LaB6基体上均匀分布着直径为02~12μm的ZrB2纤维,纤维长度可达100μm以上。对于固液界面为平面生长的试样,其结晶学取向关系为[001]LaB6∥[001]ZrB2,(110)LaB6∥(010)ZrB2。 相似文献
76.
研究了四元体系CsCl-LaCl3-HCl-H2O(25℃、「HCl」=13%(wt),23%(wt)和CsCl-LaCl3-HAc-H2O(30℃,「HAc」=42%(wt))的平衡态的溶度数据,并给出制了相应的溶度图,共得到了CsCl.LaCl3.4H2O、2CsCl.LaCl3.2H2O和3CsCl.LaCl3.3H2O3种化合物。对得到的新相进行了热分析,X射线粉末衍射及偏光性质的测定,依 相似文献
77.
78.
Transition metal oxide doped lanthanum gallates, La0.9Sr0.1Ga0.8M0.2O3 (where M=Co, Mn, Cr, Fe, or V), are studied as mixed ionic-electronic conductors (MIECs) for electrode applications. The
electrochemical properties of these materials in air and in H2 are characterized using impedance spectroscopy, open cell voltage measurement, and gas permeation measurement. Three single
cells based on La0.9Sr0.1Ga0.8 Mg0.2O3 (LSGM) electrolyte (1.13 to 1.65 mm thick) but with different electrode materials are studied under identical conditions
to characterize the effectiveness of the lanthanum gallate-based MIECs for electrode applications. At 800 °C, a single cell
using La0.9Sr0.1- Ga0.8Co0.2O3 as the cathode and La0.9Sr0.1Ga0.8Mn0.2O3 as the anode shows a maximum power density of 88 mW/cm2, which is better than that of a cell using Pt as both electrodes (20 mW/cm2) and that of a cell using La0.6Sr0.4CoO3 (LSC) as the cathode and CeO2-Ni as the anode (61 mW/cm2) under identical conditions. The performance of LSGM-based fuel cells with MIEC electrodes may be further improved by reducing
the electrolyte thickness and by optimizing the microstructures of the electrodes through processing.
Received: 9 January 1998 / Accepted: 1 May 1998 相似文献
79.
One-dimensional alternative chains of two lanthanum complexes: [La(L1)3(CH3OH)(H2O)2]·5H2O (L1=anion of α-cyano-4-hydroxycinnamic acid ) 1 and [La(L2)3(H2O)2]·3H2O (L2=anion of trans-3-(4-methyl-benzoyl)-acrylic acid) 2 were synthesized and structurally characterized by single-crystal X-ray diffraction, element analysis, IR and thermogravimetric analysis. The crystal structure data are as follows for 1: C31H36LaN3O17, triclinic, P-1, , , , α=72.7960(10)°, β=83.3820(10)°, γ=67.1650(10)º, Z=2, R1=0.0377, wR2=0.0746; for 2: C33H37LaO14, triclinic, P-1, , , , α=81.145(2)°, β=87.591(2)°, γ=67.345(5)°, Z=2, R1=0.0869, wR2=0.220. 1 is a rare example of the alternative chain constructed by syn-syn and anti-syn coordination mode of carboxylato ligand arranged along the chain alternatively. La(III) ions in 2 are linked by two η3-O bridges and four bridges (two η2-O and two η3-O) alternatively. Both of the linear coordination polymers grow into two- and three-dimensional networks by packing through extending hydrogen-bond network directed by ligands. 相似文献
80.
Ooms KJ Feindel KW Willans MJ Wasylishen RE Hanna JV Pike KJ Smith ME 《Solid state nuclear magnetic resonance》2005,28(2-4):125-134
Results from a solid-state 139La NMR spectroscopic investigation of the anhydrous lanthanum(III) halides (LaX3; X=F, Cl, Br, I) at applied magnetic fields of 7.0, 9.4, 11.7, 14.1, and 17.6 T are presented and highlight the advantages of working at high applied magnetic field strengths. The 139La quadrupolar coupling constants are found to range from 15.55 to 24.0 MHz for LaCl3 and LaI3, respectively. The lanthanum isotropic chemical shifts exhibit an inverse halogen dependence with values ranging from −135 ppm for LaF3 to 700 ppm for LaI3, which represents nearly half of the total lanthanum chemical shift range. The spans of the magnetic shielding tensors also vary widely, from 35 to 650 ppm for the solid LaF3 through LaI3. DFT calculations of the 139La electric field gradient and magnetic shielding tensors have been performed and provide a qualitative interpretation of the trends observed experimentally. 相似文献