HPLC-APCI-MS法分析测定白刺籽油中游离脂肪酸

利用荧光衍生试剂1,2-苯并-3,4-二氢咔唑-9-乙基对甲苯磺酸酯(BDETS)作为脂肪酸柱前衍生化试剂,采用梯度洗脱在Eclipse XDB-C8色谱柱上对游离脂肪酸(FFA)(油酸、亚油酸、软脂酸和硬脂酸)衍生物进行分离.利用柱后在线的串联质谱以大气压化学电离源(APCI)正离子模式实现了各组分的质谱定性.荧光检测的激发和发射波长分别为λex=333 nm,λem=390 nm.脂肪酸的线性回归系数大于0.9990,检出限为3.38～6.59 nmol/L.建立的方法具有良好的重现性.利用此方法对超临界CO2提取的唐古特白刺籽油中几种游离脂肪酸进行了分析.结果表明白刺籽油中含有大量的游离不饱和脂肪酸.     

General constructions of biquandles and their symmetries

Biquandles are algebraic objects with two binary operations whose axioms encode the generalized Reidemeister moves for virtual knots and links. These objects also provide set theoretic solutions of the well-known Yang-Baxter equation. The first half of this paper proposes some natural constructions of biquandles from groups and from their simpler counterparts, namely, quandles. We completely determine all words in the free group on two generators that give rise to (bi)quandle structures on all groups. We give some novel constructions of biquandles on unions and products of quandles, including what we refer as the holomorph biquandle of a quandle. These constructions give a wealth of solutions of the Yang-Baxter equation. We also show that for nice quandle coverings a biquandle structure on the base can be lifted to a biquandle structure on the covering. In the second half of the paper, we determine automorphism groups of these biquandles in terms of associated quandles showing elegant relationships between the symmetries of the underlying structures.     

Analyzing Multiple Phenotypes Based on Principal Component Analysis

Acta Mathematicae Applicatae Sinica, English Series - Joint analysis of multiple phenotypes can have better interpretation of complex diseases and increase statistical power to detect more...     

几乎各向同性的高维空间分数阶扩散方程的分块快速正则Hermite分裂预处理方法

一类空间分数阶扩散方程经过有限差分离散后所得到的离散线性方程组的系数矩阵是两个对角矩阵与Toeplitz型矩阵的乘积之和.在本文中,对于几乎各向同性的二维或三维空间分数阶扩散方程的离散线性方程组,采用预处理Krylov子空间迭代方法,我们利用其系数矩阵的特殊结构和具体性质构造了一类分块快速正则Hermite分裂预处理子.通过理论分析,我们证明了所对应的预处理矩阵的特征值大部分都聚集于1的附近.数值实验也表明,这类分块快速正则Hermite分裂预处理子可以明显地加快广义极小残量(GMRES)方法和稳定化的双共轭梯度(BiCGSTAB)方法等Krylov子空间迭代方法的收敛速度.     

绿色产品零售企业与市场消费者策略选择演化分析

线上线下结合营销模式有效缓解了流通渠道不畅和营销方式单一的问题,进而促进绿色产品消费。在相关假设的基础上,通过构建绿色产品零售企业和市场消费者的演化博弈模型,重现博弈主体的动态演进过程。研究结果表明,在线上线下结合营销模式中,绿色产品零售企业与消费者演化博弈系统存在两个可能的均衡状态,分别是O{维持传统营销策略,使用传统渠道购买产品}、C{建立线上营销策略,使用线上渠道购买产品}。演化博弈系统的演进受到9个相关因素的干扰,这些因素通过影响博弈主体的收益、成本及潜在的风险损失等发生作用。在理论推导的基础上,以被调研的A绿色产品零售企业为样本进行数值模拟,验证理论推导的正确性,给出上述影响因素的作用强度。     

Event-triggered sliding mode control for switched genetic regulatory networks with persistent dwell time

This paper focus on the event-triggered sliding mode controller design for discrete-time switched genetic regulatory networks (GRNs) with persistent dwell time (PDT) switching. Firstly, the observation error dynamics of switched GRNs with PDT is constructed in the light of event-triggered sliding mode control (SMC) scheme. Next, sufficient conditions are derived to ensure the exponential stability of the augmented plant. Moreover, an event-triggered SMC law is synthesized to impel the system trajectories onto the sliding surface in a finite time. Finally, a verification example is provided to illustrate the effectiveness and potential of the proposed method.     

Surface plasmon resonance and electrochemistry for detection of small molecules using catalyzed deposition of metal ions on gold substrate

Small molecules are difficult to detect by conventional surface plasmon resonance (SPR) spectroscopy due to the fact that the changes in the refractive index resulted from the binding process of small biomolecules are quite small. Here, we report a simple and effective method to detect small biomolecule using SPR spectroscopy and electrochemistry by catalyzed deposition of metal ions on SPR gold film. As an example, the ascorbic acid-mediated deposition of Ag on gold film was monitored by in situ SPR spectrum. The deposition of Ag atom on gold film resulted in an obvious decrease of depth in SPR angular scan curves of reflectance intensity and minimum reflectivity angle. The depth change of the SPR reflectance intensity and minimum reflectivity angle curves mainly relied on the amount of Ag atom deposited on gold film that can be controlled by the concentration of ascorbic acid. By monitoring the deposition of Ag atom on gold film, ascorbic acid was detected in the concentration range of 2 × 10⁻⁵ M to 1 ×  10⁻³ M. After each of detections, the SPR sensor surface was completely regenerated by a potential step that stripped off the Ag atom. Furthermore, the regeneration process of the sensor surface provides the feasibility for detecting the concentration of ascorbic acid by electrochemical method.     

Fluoro-substituted DPP-bisthiophene conjugated polymer with azides in the side chains as ambipolar semiconductor and photoresist

Photoresists are essential for the fabrication of flexible electronics through all-photolithographic processes. Single component semiconducting photoresist exhibits both semiconducting and photo-patterning properties, and as a result, the device fabrication process can be simplified. However, the design of semiconducting polymeric photoresist with ambipolar semiconducting property remains challenging. In this paper, we report a single component semiconducting photoresist (PFDPPF4T-N₃) by incorporating azide groups and noncovalent conformation locks into the side alkyl chains and conjugated backbones of a diketopyrrolopyrrole-based conjugated polymer, respectively. The results reveal that PFDPP4FT-N₃ exhibits ambipolar semiconducting property with hole and electron mobilities up to 1.12 and 1.17 cm² V^?1 s^?1, respectively. Moreover, field effect transistors with the individual photo-patterned thin films of PFDPPF4T-N₃ also show ambipolar semiconducting behavior with hole and electron mobilities up to 0.66 and 0.80 cm² V^?1 s^?1, respectively. These results offer a simple yet effective design strategy for high-performance single component semiconducting photoresists, which hold great potential for flexible electronics processed by all photolithography.

     

Diastereoselective rhodium-catalyzed nitrene transfer starting from chiral sulfonimidamide-derived iminoiodanes

The dirhodium-catalyzed aziridination of olefins with chiral sulfonimidamides as iminoiodane precursors has been investigated under stoichiometric conditions. Diastereoisomeric excesses of up to 82% have been achieved using [Rh₂{(S)-nttl}₄] as catalyst. Matching and mismatching effects were observed upon use of chiral rhodium(II) carboxylate catalysts.     

碳酸二甲酯法合成1，5-二氨基甲酸甲酯的反应机理

应用红外光谱技术研究了在乙酸锌催化作用下1，5-萘二胺与碳酸二甲酯甲氧基羰基化反应机理．结果表明，二水合乙酸锌只有失去两个结晶水变成无水乙酸锌后才能产生催化活性．无水乙酸锌与1，5-萘二胺形成一个新的配位络合物，该配位络合物是一个适宜的亲核试剂，能与碳酸二甲酯进行亲核反应，生成1，5-萘二胺的甲氧基羰基化产物．在无水乙酸锌与1，5-萘二胺形成配位络合物的过程中，无水乙酸锌的结构从双齿型转变成单齿型．