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101.
A. Atrashchenko A. Nashchekin M. Mitrofanov V. P. Ulin V. P. Evtikhiev 《固体物理学:研究快报》2014,8(4):325-327
In this Letter, we have presented a new approach for the fabrication of nanowire media (wire metamaterials) by electrochemical methods. AIIIBV porous matrices (a host medium) were prepared by anodic electrochemical etching of industrial substrates. The host medium has been filled via electrochemical deposition with a metal and by means of annealing process. We have shown that this technique can be used to fabricate a nanowire medium with unique parameters (such as aspect ratio, high electric permittivity and strong χ(3) nonlinearity near the fundamental absorption edge of the host media). (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
102.
Deming Huang Shanhong Wan Liping Wang Qunji Xue 《Surface and interface analysis : SIA》2011,43(7):1064-1068
Tungsten trioxide‐incorporated hydrogenated amorphous carbon (WO3/a‐C:H) films have been fabricated on a single‐crystal silicon wafer by liquid phase electrodeposition using methanol as carbon source and tungsten carbonyl as incorporated reagent. The morphology, composition and structure of the films have been investigated by SEM, XPS, Raman scattering spectroscopy, Fourier transform infrared spectroscopy (FTIR) and Transmission electron microscope (TEM), respectively. The effects of WO3 incorporation on the electrical and wetting properties were studied in detail. The characterization results showed that tungsten trioxide nanocrystalline particles with diameters in the range of 10–20 nm were homogenously embedded in the amorphous carbon films. Also, the electrical conductivity and wetting ability of the films were strongly improved due to the contribution of the tungsten trioxide. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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A combined redox-competition and negative-feedback SECM study of self-healing anticorrosive coatings
Y. González-García S.J. García A.E. Hughes J.M.C. Mol 《Electrochemistry communications》2011,13(10):1094-1097
In this paper, the long-term anticorrosive efficiency of a damaged self-healing coating is studied for the first time using scanning electrochemical microscopy (SECM). In the study an epoxy-coating with embedded-capsules containing a silyl-ester is employed. The properties of the silyl-ester as a healing-agent for the protection of AA2024-T3 were evaluated by complementary SECM experiments operating in negative-feedback and redox-competition modes. The experimental approach here presented allowed for monitoring the early-stages of corrosion activity and subsequent healing mechanisms offered by the release of silyl-ester into a relatively large coating defect. This result was observed by detecting the transition of the oxygen reduction response from a redox-competition mode to a negative-feedback behavior. These measurements demonstrated that the silyl-ester is released efficiently after capsules break upon coating damage, covering relatively large areas and gradually healing the damaged-site hindering the corrosion processes and providing an effective protection for at least one month of immersion in chloride solution. 相似文献
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为了改善钛钒基固溶体合金的电化学性能,利用两步电弧熔炼法制备复合储氢合金Ti0.10Zr0.15V0.35Cr0.10Ni0.30+5wt%LaNi5,X-射线衍射(XRD)和场发射扫描电镜-能谱(FESEM-EDS)显示:复合储氢合金的主相是体心立方结构的钒基固溶体相和六方结构的C14 Laves相,复合过程中生成了第二相。电化学测试结果表明:复合合金电极的P-C-T特征、活化性能、最大放电容量、循环稳定性、低温放电性能和动力学特性均较母体合金有显著改善。复合合金电极的活化周期数为5,最大放电容量为353.9 mAh.g-1,233 K时低温放电能力为50.26%。该复合合金电极的最大储氢容量、平台压、电荷转移电阻和交换电流密度均存在协同效应;在任意循环、在高/低温下以及在高倍率放电过程中,该复合合金电极的放电容量均存在协同效应。 相似文献