负载型CO3[Fe（CN）6]2及CN^—加氢反应的研究

双金属催化剂是一类重要的多相催化剂。其中d电子在催化活性方面起着重要的作用.本文在Co_3[Fe(CN)_6]_2的工作基础上,进一步研究了该配合物在硅胶、氧化铝、以及氧化镁上的热性质,同时考察了CN~-在Co-Fe体系双端基配位的活化加氢,探讨了载体的影响.     

Study on the Reaction of Benzimidazolium Salt with Amine Compounds

The addition-hydrolysis reaction of benzimidazolium salt with some mono- and bifunctional amine nucleophiles is reported,and a novel method of biomimetic synthesis for formamides and heterocycle compounds is provided.     

Effects of External Electric Field on Ferroelectric Superlattice with Two Alternating Layers

The effects of the external electric field on the ferroelectric superlattice with two alternating layers have been studied using the transverse Ising model based on the effective-field theory with the differential technique. The hysteresis loops and susceptibility of the system have been given. The stronger the external electric field, the smaller the susceptibility, reflecting that the polarization is weaker.     

The Isoelectric Point and the Points of Zero Charge of Fe-Al-Mg Hydrotalcite-like Compounds

The relation of the isoelectric point (IEP) and the point of zero net charge (PZNC) of the hydrotalcite-like compounds was discussed. It was found that the IEP does not equal to the PZNC and the IEP is higher than the PZNC. The structural positive charges existing in the HTlc,which cause the difference between the IEP and the PZNC. The effects of the structural positive charges of the HTlc on its IEP and PZNC are the same as the specific adsorption of metal cations.     

Magnetic and Crystalline Microstructures of Fe-Pt-B Nanocomposite Ribbons

We investigate magnetic and crystalline microstructures of melt-spun (Fe0.675Pt0.325)100-xBx (x=12, 14, 16, 18,20) nanocomposite ribbons after optimal thermal treatment using a magnetic force microscope. The magnetic microstructures are characterized by darker spots adjacent to brighter ones in a sub-micro scale and in random distribution. It is found that the strength of the exchange coupling interaction between the crystals in the 10-100 nm scale, implied by the maximum value (δM)max of the Henkel plot, could be roughly described by the ratio of the average width of the magnetic spots w^- to the average crystal size D^- for the ribbons. Moreover, we find that the intrinsic coercivity jHc of the ribbons is sensitive to their crystal sizes, and the smaller D^-, the higher jHc. Finally, by using roughness analysis, the curve of the root mean square values (δФ)rms of the phase shift of the magnetic force images versus the boron content x is obtained, which is qualitatively consistent with that of the magnetization σ12 kOe of the ribbons versus x.     

乌洛托品法测定钢铁热浸镀锌量

钢铁热浸镀锌量的测定在GB及世界各国标准里均采用三氯化锑法。因其产生SbH_3有毒气体而被甲醛或乌洛托品代替锑剂。ZBH11001-88采用甲醛,GB/T13825-92及ISO1460-1992(E)均采用乌洛托品。本文对乌洛托品方法进行试验并与三氯化锑法、ZBH11001-88法加以研究比较。 1 试验部分 1.1 主要试剂 乌洛托品(六次甲基四胺,分析纯,含甲醛97％以上) 乌洛托品盐酸退镀溶液,称取乌洛托品3.5g溶于盐酸(1+1)1L中。 1.2 测定步骤 将热浸镀锌钢铁试样制备成可测面积的样品,以无水乙醇及乙醚清除表面油污,烘干冷至室温于万分之一天平上称准至毫克。置于盛有乌洛托品退镀溶液的器皿中,保持样品每平方厘米表面上有10ml以上的     

金属有机化学气相沉积法制备钛酸铅铁电薄膜

利用低压ＭＯＣＶＤ工艺分别在（００１）取向的ＬａＡｌＯ_３，ＳｒＴｉＯ_３和重掺杂硅单晶衬底上制备ＰｂＴｉＯ_３铁电薄膜，并通过Ｘ射线衍射谱对薄膜的微结构进行分析．Ｘ射线θ－２θ扫描显示硅衬底上得到了ＰｂＴｉＯ_３多晶薄膜，另两种衬底上得到了择优取向的ＰｂＴｉＯ_３薄膜．ＬａＡｌＯ_３衬底上的ＰｂＴｉＯ_３薄膜有ａ和ｃ两个取向，也就是薄膜中存在着９０°畴结构，而生长在ＳｒＴｉＯ_３衬底上的ＰｂＴｉＯ_３薄膜中只存在ｃ方向的择优取向．由于薄膜的尺度效应，发现ｃ轴晶格常数与块材相比均缩短．Ｘ射线的φ扫描验证了后两类薄膜的外延特性，利用同步辐射的高强度和高能量分辨率用摇摆曲线方法研究了这两种外延薄膜的品质，进一步证明了ＳｒＴｉＯ_３衬底上的ＰｂＴｉＯ_３薄膜的单畴特性．利用重掺杂的硅衬底作底电极，测量显示直接生长于硅衬底上的ＰｂＴｉＯ_３多晶薄膜具有良好的铁电性能 关键词：     

Theoretical Design of High-spin Organic Molecules with —^＊N—S— as a Spin-containing Fragment and Heterocycle as End Groups

IntroductionDesigns and syntheses of organic molecules withvery high-spin ground states have been a topic of greatinterest[1—8].One of the rational approaches to desig-ning high-spin molecules,which has been proposedand studied by several groups[9,10],in…     

Exact Solution of an Extended Hubbard Model with Electron—Lattice Interaction for an Organic Ferromagnetic Polymer

Using an exact diagonalization method,we study an extended Hubbard model with an electron-lattice interaction for an organic ferromagnetic chain with radical coupling.The result shows that the ferromagnetic ground state originates from the antiferromagnetic correlation between adjoining sites,which is enhanced by the on-site e-e repulsion.The intersite e-e repulsion induces the inhomogeneous distribution of the charge density.The dimerization is decreased by the e-e interaction and the radical coupling.The electron-lattice interaction and the radical coupling can transfer the spin density and charge density between the main chain and the radicals.     

Studies on the Model Synthesis of the Brassinolide and Dolicholide‘s Side Chains

A highly stereoselective synthesis of the side Chain enantiomers of brassinolide and dolicholide through an aldol reaction of 2-(4-methoxy benzyloxyl) proplonylaldehyde (5) with the anion of 1- ( tert -butyldimethylsiloxy )-3-methyl-2-butanone ( 6 ) is described.