溶剂尺寸对ABA两亲性三嵌段共聚物在选择性溶剂中自组装行为影响的Monte Carlo模拟

采用Monte Carlo模拟方法研究了溶剂尺寸对ABA两亲性三嵌段共聚物在选择性溶剂中自组装行为的影响。模拟结果表明,溶剂尺寸是决定共聚物聚集形态的重要因素之一。随着溶剂尺寸的增大,嵌段共聚物自组装所形成的胶束可以发生从球状到棒状再到囊泡状的转变。通过对各组分的相互作用对数随溶剂尺寸变化曲线的分析发现,增大溶剂尺寸会使溶剂的溶解性变差,由此引发体系中的一系列形态转变。此外,通过对体系自组装形貌结构相图的分析发现,增大溶剂尺寸或增加疏水作用同减小亲水作用对于自组装形态的改变具有同等效果。     

单目多视点立体图像提取及应用

设计并实现了一种基于广角相机和平面镜的单目多视点立体图像摄像系统,给出了硬件装置的设计指标和优化方法;同时,在研究了硬件系统的标定方法基础上,实现了其在三维测距方面的应用。多枚平面镜构成的对称斗型腔体被放置在广角相机前面,物体光线经过不同平面镜反射后,投影到相机图像平面的不同区域,在相机投影平面上生成物体多个影像,形成单目多视点投影图像。该类图像等价于视点不同的多幅图像,可以使用多视点立体视觉算法实现三维测量。     

非均匀材料样品的霍尔系数的计算

将不均匀材料网络化用等效电源的方法根据基尔霍尔定律得到了不均匀材料样品的霍尔系数的较为一般的表达式,应用该结果可以谇地计算不均匀材料样品的霍尔系数,而双层模型和三层模型是此表达式的特例。     

The aerosol penetration through an electret fibrous filter

The aim of this paper is to present a theoretical study of the aerosol penetration through an electret fibrous filter, using a numerical approach. The aerosol sizes considered in this study were in the submicron range, and in the numerical model, the conventional mechanical mechanisms (impaction, interception, diffusion and gravitationally settling) were taken into consideration along with the electrostatic mechanisms, including the Coulombic and dielectrophoretic effects. The aerosol penetration through an electret fibrous filter is heavily dependent on the aerosol penetration of a single fibre. The aerosol penetration through a single electret fibre under various filtration conditions was calculated. The effects of aerosol diameter, aerosol and fibre charge state, face velocity, packing density and aerosol dielectric constant on the aerosol penetration were investigated.     

HPLC法拆分粉唑醇对映体

HPLC法拆分粉唑醇对映体;粉唑醇;对映体;分离;手性固定相     

自旋s=1双层铁磁-反铁磁的零温磁矩

采用线性自旋波理论,利用数值计算的方法计算自旋s=1的零温磁矩 。     

冰排与斜面结构作用时的破断长度分析

研究了冰排与斜面结构的相互作用过程．文中将冰排分为在斜面附近脱离水面部分和较远处漂浮于水面部分两个区域,建立了冰排因弯曲而发生破断的数学模型,根据弯矩分布分析了冰排可能的破断位置,从而得到冰排与斜面结构相互作用时的破断长度解析表达式．结果表明,冰排破断长度既不是冰厚的固定倍数,也不与冰排特征长度直接相关．计算结果与前人实验结果吻合较好,可以为近海冰区抗冰结构的设计提供参考．     

角度非均匀材料平面V形切口应力奇性分析

提出了一种确定角度非均匀材料平面V形切口尖端应力奇性指数的有效方法。首先,在弹性力学基本方程中引入V形切口尖端位移场的级数渐近展开,建立以位移为特征函数的变系数和非线性微分方程组。然后,采用微分求积法(DQM)求解微分方程组,可得到多阶应力奇性指数及其相对应的特征函数,该法具有公式简单、编程方便、计算量少和精度高等优点,可处理任意开口角度和任意材料组合的V形切口。典型算例验证了微分求积法的有效性和精确性。     

COMPUTER SIMULATION OF MISCIBILITY AND SELF-ASSEMBLY STRUCTURE FOR POLYMER-CONTAINING SYSTEMS WITH SPECIAL INTERACTIONS

The miscibility and structure of A-B copolymer/C homopolymer blends with special interactions were studied by aMonte Carlo simulation in two dimensions. The interaction between segment A and segment C was repulsive, whereas it wasattractive between segment B and segment C. In order to study the effect of copolymer chain structure on the morphologyand structure of A-B copolymer/C homopolymer blends, the alternating, random and block A-B copolymers were introducedinto the blends, respectively. The simulation results indicated that the miscibility of A-B block copolymer/C homopolymerblends depended on the chain structure of the A-B copolymer. Compared with alternating or random copolymer, the blockcopolymer, especially the diblock copolymer, could lead to a poor miscibility of A-B copolymer/C homopolymer blends.Moreover, for diblock A-B copolymer/C homopolymer blends, obvious self-organized core-shell smicture was observed inthe segment B composition region from 20% to 60%. However if diblock copolymer composition in the blends is less than40%, obvious self-organized core-shell structure could be formed in the B-segment component region from 10 to 90%.Furthermore, computer statistical analysis for the simulation results showed that the core sizes tended to increasecontinuously and their distribution became wider with decreasing B-segment component.     

N,N′-联苄基-2-苯基四氢咪唑的合成

以苯甲醛和乙二胺为原料,经缩合、催化加氢两步法合成标题产物,产物通过质谱、红外光谱、核磁共振氢谱及元素分析,对其结构进行确证.与传统的方法相比产率有所提高,而且反应条件温和,缩短了时间,简化了操作步骤.