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11.
High resolution photoemission measurements are carried out on non-superconducting SmOFeAs paxent compound and superconducting SmFeAs(O1-xFx) (x = 0.12, and 0.15) compounds. The momentum-integrated spectra exhibit a clear Fermi cutoff that shows little leading-edge shift in the superconducting state. A robust feature at 13 meV is identified in all these samples. Spectral weight suppression near IF, F with decreasing temperature is observed in both undoped and doped samples that points to a possible existence of a pseudogap in these Fe-based compounds.  相似文献   
12.
抗坏血酸在2-氨基吡啶修饰电极上的电催化氧化及其应用   总被引:10,自引:0,他引:10  
研究了 2 -氨基吡啶聚合膜修饰玻碳电极的制备及其电化学性质 ,修饰电极对抗坏血酸 ( AA)的氧化有明显的催化作用 ,其氧化电位负移 2 72 m V。在 p H5 .7的B.R.缓冲溶液中 ,以 1 5 0 m V为工作电位 ,AA在修饰电极上的响应电流与 AA的浓度在 4× 1 0 - 6~ 1 0 - 3 mol/ L范围内呈良好的线性关系 ,检出限为 1 .3× 1 0 - 6mol/ L。在此条件下 ,多巴胺 ( DA)对 AA无干扰 ,电极重现性良好 ,可用于实际样品中 AA的测定  相似文献   
13.
2-氨基吡啶修饰电极的电化学性质及对抗坏血酸的测定   总被引:17,自引:0,他引:17  
吴婧  刘国东  黄杉生  俞汝勤 《分析化学》2001,29(10):1140-1143
研究了2-氨基吡啶聚合膜修饰玻碳电极的制备及其电化学性质,并用于抗坏血酸(AA)的测定。在pH5.7BR缓冲溶液中,AA在 2-氨基吡啶修饰电极上产生一灵敏的氧化峰,峰电流与AA浓度在4 × 10-6~10-3mol/L范围内呈良好的线性关系,检测下限为 1.3 × 10-6mol/L。该电极对 AA有增敏作用,对多巴胺(DA)有排斥作用,重现性良好,可用于AA的测定。  相似文献   
14.
Hongtao Yan 《中国物理 B》2022,31(8):87401-087401
The pseudogap state is one of the most enigmatic characteristics in the anomalous normal state properties of the high temperature cuprate superconductors. A central issue is to reveal whether there is a symmetry breaking and which symmetries are broken across the pseudogap transition. By performing high resolution laser-based angle-resolved photoemission measurements on the optimally-doped Bi2Sr1.6La0.4CuO6+δ superconductor, we report the observations of the particle-hole symmetry conservation in both the superconducting state and the pseudogap state along the entire Fermi surface. These results provide key insights in understanding the nature of the pseudogap and its relation with high temperature superconductivity.  相似文献   
15.
We carry out detailed momentum-dependent and temperature-dependent measurements on Bi_2Sr_2CaCu_2O_(8+δ)(Bi2212) superconductor in the superconducting and pseudogap states by super-high resolution laser-based angleresolved photoemission spectroscopy. The precise determination of the superconducting gap for the nearly optimally doped Bi2212(T_c= 91 K) at low temperature indicates that the momentum-dependence of the superconducting gap deviates from the standard d-wave form(cos(2Φ)). It can be alternatively fitted by including a high-order term(cos(6Φ)) in which the next nearest-neighbor interaction is considered. We find that the band structure near the antinodal region smoothly evolves across the pseudogap temperature without a signature of band reorganization which is distinct from that found in Bi_2Sr_2CuO_(6+δ) superconductors. This indicates that the band reorganization across the pseudogap temperature is not a universal behavior in cuprate superconductors.These results provide new insights in understanding the nature of the superconducting gap and pseudogap in high-temperature cuprate superconductors.  相似文献   
16.
The parent compounds of the high-temperature cuprate superconductors are Mott insulators.It has been generally agreed that understanding the physics of the doped Mott insulators is essential to understanding the mechanism of high temperature superconductivity.A natural starting point is to elucidate the basic electronic structure of the parent compound.Here we report comprehensive high resolution angle-resolved photoemission measurements on Ca_2CuO_2Cl_2,a Mott insulator and a prototypical parent compound of the cuprates.Multiple underl.ying Fermi surface sheets are revealed for the first time.The high energy waterfall-like band dispersions exhibit different behaviors near the nodal and antinodal regions.Two distinct energy scales are identified:a d-wave-like low energy peak dispersion and a nearly isotropic lower Hubbard band gap.These observations provide new information of the electronic structure of the cuprate parent compound,which is important for understanding the anomalous physical properties and superconductivity mechanism of the high temperature cuprate superconductors.  相似文献   
17.
黄炎  刘国东  张学记 《化学进展》2020,32(9):1241-1251
2019年12月以来席卷全球的新型冠状病毒(COVID-19)肺炎是一种高传染性疾病,给全球社会、经济和生活带来了巨大的负面影响,严重威胁人类的生命安全。由于尚无用于COVID-19的特定药物或疫苗,快速及时的检测和诊断对于控制疫情至关重要。本文介绍了目前检测COVID-19的方法,主要比较了CT检测、核酸检测和抗体检测在检测COVID-19中各自发挥的作用,总结了各种方法的优势和不足之处,综述了各种方法的最新研究进展。病毒分离是检测病毒感染的黄金标准,但是要求严格的条件,这些条件多数实验室和医院无法满足。CT检查可以直接看到症状,但是存在特异性低的局限;核酸检测能提供直接的证据,是当前检测新型冠状病毒的主要方法,但是存在假阳性;抗体检测能提供非直接的证据,适于进行筛查工作,但是其无法用于感染的早期诊断且可能得到假阳性或假阴性结果。本文提出了联合使用和综合判读可以从技术和时间差上互补,并对未来的发展趋势和研究重点进行了展望。  相似文献   
18.
High resolution laser-based angle-resolved photoemission measurements are carried out on an overdoped superconductor Bi_2Sr_2CaCu_2O_(8+)with a_(c )of 75 K.Two Fermi surface sheets caused by bilayer splitting are clearly identified with rather different doping levels:the bonding sheet corresponds to a doping level of 0.14,which is slightly underdoped while the antibonding sheet has a doping of 0.27 that is heavily overdoped,giving an overall doping level of 0.20 for the sample.Different superconducting gap sizes on the two Fermi surface sheets are revealed.The superconducting gap on the antibonding Fermi surface sheet follows a standard d-wave form while it deviates from the standard d-wave form for the bonding Fermi surface sheet.The maximum gap difference between the two Fermi surface sheets near the antinodal region is~2 meV.These observations provide important information for studying the relationship between the Fermi surface topology and superconductivity,and the layer-dependent superconductivity in high temperature cuprate superconductors.  相似文献   
19.
研究了杂多酸阴离子α- P2 W1 7O1 0 -61 修饰电极的制备及其化学性质。α- P2 W1 7O1 0 -61 修饰电极对 Br O-3 具有催化作用。催化电流 ΔIp 与 [Br O-3 ]在 7.0× 1 0 -6~ 1 .0× 1 0 -4mol/ L范围内呈良好线性关系。用此电极测定了天然水中 Br O-3 的含量 ,结果令人满意  相似文献   
20.
超导是一种奇异的宏观量子现象.100多年来,已发现的超导体主要分为两类:以金属或者合金为代表的常规超导体以及以铜氧化物和铁基高温超导体为代表的非常规超导体.常规超导体的超导机理能被BCS超导理论完美解释,但高温超导体的超导机理至今仍未达成共识,已经成为凝聚态物理领域中长期争论且充满挑战的重大科学问题.从实验上揭示非常规超导材料的微观电子结构,是理解其奇异正常态和超导电性机理、建立新理论的前提和基础.角分辨光电子能谱技术,由于可以实现对材料中电子的能量、动量和自旋的直接测量,在高温超导研究中发挥了重要的作用.本文综述了我们利用角分辨光电子能谱技术在铜氧化物和铁基高温超导体电子结构和超导机理研究中取得的一些进展,主要包括母体的电子结构、正常态的非费米液体行为、超导态的能带和超导能隙结构以及多体相互作用等.这些结果为理解铜氧化物和铁基高温超导体的物性及超导机理提供了重要的信息.  相似文献   
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