Photoluminescence study of the annihilation process of donor-bound excitons in ZnO： observation of quantum mechanical interference

We report a photoluminescence observation of the coupling of donor-bound excitons and longitudinal optical phonons in high-quality ZnO crystals at 5 K. The first-order phonon Stockes line of donor-bound excitons exhibits a distinct asymmetric line shape with a clear dip at its higher energy side, suggesting that quantum mechanical interference occurs during the annihilation of donor-bound excitons. The donor binding energy is determined to be 49.3 meV from spectral featural.     

BCI代数的闭Ω犹豫模糊理想

在集合Ω中,把犹豫模糊集、Ω模糊集相结合来研究BCI-代数.首先在BCI代数中引入闭Ω犹豫模糊理想的概念,讨论它的一些性质和等价刻画;其次,在闭犹豫模糊理想概念的基础上研究了如何构造闭Ω犹豫模糊理想,讨论了闭Ω犹豫模糊理想的同态像与同态原像的性质;最后,给出了闭Ω犹豫模糊理想与乘积型BCI代数的闭Ω犹豫模糊理想的关系.     

DNA分子结构的多态性研究：（Ⅱ）吖啶橙凝聚体变化诱导的质粒DNA？…

利用吸收光谱和荧光光谱方法，研究了吖啶橙（ＡＯ）与质粒ＤＮＡ水溶液，以及含胶束介抽的吖啶橙与质粒ＤＮＡ溶液体系的相互结合作用及减色效应。结果表明：吖啶橙时质粒ＤＮＡ的吸收光谱有减色效应；含十二烷基硫酸钠（ＳＤＳ）的ＡＯ水溶液体中，随着ＳＤＳ浓度的增加，其光谱结果表明由凝聚态向单体的转化。而在含十二烷基硫酸钠（ＤＳ）的ＡＯ与质粒ＤＮＡ溶液体系中，吖啶橙凝聚态随ＳＤＳ浓度的增加，对ＡＯ与质粒ＤＮＡ相互     

氰基二苯乙烯基超分子聚合物的构筑与光响应行为

通过在氰基二苯乙烯基元上引入氢键识别位点，驱使单体分子之间产生氢键与π-π堆积作用力的高效加合，构建了具有“成核-链增长”机制的超分子聚合物。通过获取组装热力学参数，揭示了酰胺及脲等不同氢键结构对于超分子聚合行为的影响规律。进一步利用超分子聚合态对于氰基二苯乙烯基元的限域效应，光照条件下特异性获得[2+2]环加成产物。与之相比，单体态时氰基二苯乙烯基元倾向于发生Z/E光异构化反应。这一研究结果可为多路径光化学反应的高效调控提供新的思路。     

一维固-液掺杂声子晶体缺陷模的机理研究

建立了一维固-液掺杂声子晶体的谐振腔模型,利用谐振腔的共振条件推导出了缺陷模频率满足的解析公式,从理论上解释了产生一维固-液掺杂声子晶体缺陷模的物理机理.利用频率的解析公式研究了缺陷模的频率随入射角、杂质厚度、杂质波速的变化规律.结果表明:缺陷模的频率随入射角和杂质波速的增加而增加,缺陷模的频率随杂质厚度的增加而减少,圆满地解释了一维固-液掺杂声子晶体缺陷模的变化规律.在此基础上并与转移矩阵法的计算结果进行了比较,其结果吻合.     

Rate effect and coupled evolution of atomic motions and potential landscapes

Since rate effect of materials plays a key role in impact engineering, the microscopic mechanism of rate effect is investigated at molecular level in this paper. The results show that rate effect on the strength of atomic system is closely related to the coupled evolution of atomic motions and potential landscapes. Accordingly, it becomes possible to develop a new algorithm of molecular simulation, which could properly and efficiently demonstrate strain rate effect under a wide range of loading rates and unveil the mecha- nisms underlying the strain rate effects.     

约束修正失效评定曲线及内压管道失效分析

用A2参数描述裂纹尖端约束效应,考虑裂纹尖端约束水平对断裂阻力的影响,对R6失效评定曲线进行修正。以X80钢为例,根据不同约束水平试件测试得到的JR–△a曲线,给出了与裂纹尖端约束相关的失效评定曲线。在使用有限元对带裂纹内压管道进行弹塑性分析的基础上,利用失效评定曲线对失效载荷进行预测;与试验结果比较表明:采用约束修正失效评定曲线,在对存在缺陷的构件进行安全性评定、寿命评估、失效概率计算时,考虑约束效应对断裂韧度的影响可以更充分地发挥构件的强度潜力。     

Ultrasonic guided wave inspection with array sensors

Ultrasonic guided wave becomes one of promising tool for monitoring various types of structures such as large steel plates, vessels, and pipes in oil, chemical or nuclear industry, because guided waves have ability to travel wide range of the target structure in a single position. However, analysis of guided wave signals acquired from structure is difficult on account of low S/N ratio and its dispersive nature. To improve S/N ratio and overcome dispersion effect, focusing techniques for guided waves are needed. Thus, in this study, focusing techniques for guided waves were developed in order to improve long range inspection ability, and performance of the developed techniques was verified by experiments.     

纳米微晶的制备及其性质研究

有机纳米微晶在纳米电子器件等方面具有应用前景, 已成为当前纳米科学的研究热点之一[1]. Nakanishi等[2,3]用再沉淀法制备出了有机纳米微晶, 但并未研究其生长机制和各种制备条件对生长过程的影响. 本文制备了不同粒径的纳米微晶, 研究了晶体结构和光谱性质的变化规律, 讨论了影响粒径大小和生长速率的因素, 为建立可行的有机微晶制备方法提供依据.     

光量子纠缠态的制备和测量实验

以量子纠缠源为实验对象,以光量子纠缠态的制备、传输和纠缠性质的测量为内容设计实验,有利于学生学习量子通讯的基本原理及偏振纠缠、自发参量下转换产生双光子态量子理论.