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排序方式: 共有21条查询结果,搜索用时 15 毫秒
1.
贵金属纳米粒子由于对激发光的偏振类型和波长的有效响应,成为了全息存储介质的优选材料,但目前还未找到有效的方法抑制紫外光对等离子体存储信息的擦除影响,进而其在抗干扰全息存储器件的应用上受到了很大限制.本文从等离子体诱导电荷分离基本原理出发,利用受主中心俘获载流子转移的方法,在传统Ag/TiO2纳米复合薄膜上,实现了存储信息从可擦除到不可擦除的调控.研究表明:多金属氧酸盐基团能有效调控贵金属/半导体系统内部的电荷转移,实现抗紫外线和射线擦除的高性能全息数据存储.  相似文献   
2.
纳米微晶的制备及其性质研究   总被引:2,自引:0,他引:2  
有机纳米微晶在纳米电子器件等方面具有应用前景, 已成为当前纳米科学的研究热点之一[1]. Nakanishi等[2,3]用再沉淀法制备出了有机纳米微晶, 但并未研究其生长机制和各种制备条件对生长过程的影响. 本文制备了不同粒径的纳米微晶, 研究了晶体结构和光谱性质的变化规律, 讨论了影响粒径大小和生长速率的因素, 为建立可行的有机微晶制备方法提供依据.  相似文献   
3.
TiO2纳米粒子膜表面性质的研究   总被引:14,自引:0,他引:14  
TiO_2纳米粒子膜在光催化降解大气和水中的污染物[1]、光电转换[2]、光致变色[3]等方面有广阔的应用前景,近年来受到了科学界的高度重视.研究表明,膜的表面性质对如上应用有着重要影响.本文采用等离子体化学气相沉积法(PECVD法)[4]制备了TiO2的纳米粒子膜,分别采用TiCl4等离子体或O2等离子体处理膜表面,获得两种不同表面性质的TiO2纳米粒子膜;并利用表面光电压谱(SPS)和电场诱导表面光电压谱(EFISPS)技术对膜的表面性质进行具体分析,探讨了其在光催化领域的可能应用.1实验部…  相似文献   
4.
量子尺寸氧化锌颗粒的表现光电压谱研究   总被引:2,自引:0,他引:2  
  相似文献   
5.
银纳米粒子在云母表面的二维组装及其表面增强拉曼效应   总被引:3,自引:0,他引:3  
随着纳米技术的迅速发展 ,利用共价或非共价键作用将金属纳米粒子组装到固体基片上 ,因其方法简单、重复性好而成为研究热点 .目前 ,人们已经成功地利用带有— SH[1,2 ] ,—CN,— NH2 [3 ] 等基团的单层或多层膜作为偶联剂将 Au和 Ag等金属纳米粒子固定在玻璃、石英、硅、金等固体基片上 .但在许多情况下 ,偶联剂却成为一种干扰物质 .云母是一种重要的电子工业材料 ,并具有廉价、较易获得新鲜表面等特点 ,研究金属纳米粒子在云母表面的组装和排列无疑具有重要意义 .但是 ,迄今为止 ,在表面没有偶联剂修饰的条件下 ,以云母为基底的金属纳…  相似文献   
6.
Depleted bulk heterojunction(DBH)PbS quantum dot solar cells(QDSCs),appearing with boosted short-circuit current density(J_(sc)),represent the great potential of solar radiation utilization,but suffer from the problem of increased interfacial charge recombination and reduced open-circuit voltage(V_(oc)).Herein,we report that an insertion of ultrathin Al_2O_3 layer(ca.1.2 A thickness)at the interface of ZnO nanowires(NWs)and Pb S quantum dots(QDs)could remarkably improve the performance of DBH-QDSCs fabricated from them,i.e.,an increase of V_(oc) from 449 mV to 572 mV,Jsc from21.90 mA/cm~2 to 23.98 mA/cm~2,and power conversion efficiency(PCE)from 4.29% to 6.11%.Such an improvement of device performance is ascribed to the significant reduction of the interfacial charge recombination rate,as evidenced by the light intensity dependence on Jsc and Voc,the prolonged electron lifetime,the lowered trap density,and the enlarged recombination activation energy.The present research therefore provides an effective interfacial engineering means to improving the overall performance of DBH-QDSCs,which might also be effective to other types of optoelectronic devices with large interface area.  相似文献   
7.
Ning Li 《中国物理 B》2022,31(3):36101-036101
Noble-metal/metal-oxide-semiconductor nanostructures as an important material platform have been applied in massive data storage. ZnO exhibits excellent optical modulation ability. However, plasmon induced charge separation effect in Ag/ZnO systems is very weak due to the low chemical activity on surface of the oxide. Herein, we prepare ZnO nanowire arrays via the hydrothermal method, and measure their absorption spectra, photoluminescence spectra and electron paramagnetic resonance, proving the existence of oxygen defects in ZnO. Accordingly, an idea of "electron reverse transfer" is proposed such that blue-ray (403.4 nm) induces reduction of Ag+ ions through the excitation of ZnO. Rod-like and spherical silver nanoparticles emerge on the surface and in the gap of ZnO nanowire arrays, respectively, after the visible light stimulus. It is found that nanowire density, oxygen defects and surface roughness are dependent on hydrothermal time. The optimized diffraction efficiency of 0.08% is obtained for reconstructing hologram in the nanocomposite film. This work provides a bright way for construction of ZnO-based optoelectronic integrated devices.  相似文献   
8.
为实现伴随粒子中子管研究中的小靶点表征,设计了一种基于YAG∶Ce材料的模块化荧光靶体,给出了一种靶点实时监视与测量的方法。利用该方法实现了伴随粒子中子管最小4 mm直径靶点的实验工作。研究中在可更换的荧光靶面上经过激光雕刻阵列化后,能够分辨毫米级甚至亚毫米级的靶点大小。经过长时间高能离子束轰击后的YAG∶Ce材料靶面能够持续发光,未见性能下降,证明YAG∶Ce材料具有良好的耐辐照性能。  相似文献   
9.
不同形态SnO2纳米晶的制备   总被引:2,自引:0,他引:2  
In this paper, we report our research on morphologically selective synthesis of nanocrystalline SnO2 by the combination of hydrothermal preparation and calcinated process. We firstly prepared SnO2 nanocrystals by the hydrothermal method at 140 ℃ for 3 h, using SnCI4 as the reactant. With the initial pH of 1.8 or 1.34, we prepared uniform and well-dispersed SnO2(tetragonal) nanocrystals, with similar size of about 3 nm, as determined by TEM. However, after being calcinated at 500 ℃ for 2 h, specimen 1 prepared at pH=1.8 showed the rod-like shape with an average size of 5 nm×20 nm, while the other one(specimen 2)prepaed at pH=1.34 showed a granular shape with an average size of 10 nm. XRD experiments showed that specimen 1 had a new diffraction peak after calcination, which was contributed by the (023) face of orthorhombic SnO2. The experiment results indicated that the morpholgy of SnO2 nanocrystals after calcination was closely related to the initial acidity of the reaction solution, possibly due to the difference in surface properties, e.g. the difference in crystalline faces exposed to the surface of particals, under different hydrothermal conditions.  相似文献   
10.
利用乙二胺阳离子为模板,采用温和的反应条件制备出一种新的光致变色化合物NH3CH2CH2NH3Mo3O10·4.4H2O,经过元素分析、热重以及光谱测定,证明该化合物的无机骨架为(Mo3O10)∞^2-无穷长链。乙二胺阳离子通过氢键等超分子作用与无机骨架相连。实验发现该化合物具有良好的光致变色性能,与真空蒸镀MoO3不同的是,经紫外光照后,此化合物由白色变为红棕色,EXAFS(扩展X射线精细结构)研究结果表明紫外光照后,质子从乙二铵阳离子转移到Mo-O^-为其可能的机理。  相似文献   
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