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991.
ZONG Chenglong ZENG Runsheng ZOU Jianping 《高等学校化学研究》2014,30(4):632-638
A direct and efficient approach to synthesize imidazo[1,2-α]pyridines through three-component one-pot reaction of 2-aminopyridine,aldehyde and terminal alkyne catalyzed by Cu-nanoparticles under solvent-free conditions has been developed.This method provides a rapid access to substituted imidazo[1,2-α]pyridines with good yields(up to 85%). 相似文献
992.
A novel periodic boundary condition (PBC), that is the constant transverse wavenumber (CTW) method, is introduced to solve the time delay in the transverse plane with oblique incidence. Based on the novel PBC, the FDTD/PBC algorithm is proposed to study periodic structure consisting of plasma and vacuum. Then the reflection coefficient for the plasma slab from the FDTD/PBC algorithm is compared with the analytic results to show the validity of our technique. Finally, the reflection coefficients for the plasma photonic crystals are calculated using the FDTD/PBC algorithm to study the variation of bandgap characteristics with the incident angle and the plasma parameters. Thus it has provided the guiding sense for the actual manufacturing plasma photonic crystal. 相似文献
993.
Deep submicron n-channel metal-oxide-semiconductor field-effect transistors (NMOSFETs) with shallow trench isolation (STI) are exposed to ionizing dose radiation under different bias conditions.The total ionizing dose radiation induced subthreshold leakage current increase and the hump effect under four different irradiation bias conditions including the worst case (ON bias) for the transistors are discussed.The high electric fields at the corners are partly responsible for the subthreshold hump effect.Charge trapped in the isolation oxide,particularly at the Si/SiO 2 interface along the sidewalls of the trench oxide creates a leakage path,which becomes a dominant contributor to the offstate drain-to-source leakage current in the NMOSFET.Non-uniform charge distribution is introduced into a threedimensional (3D) simulation.Good agreement between experimental and simulation results is demonstrated.We find that the electric field distribution along with the STI sidewall is important for the radiation effect under different bias conditions. 相似文献
994.
995.
An unsteady magnetohydrodynamic (MHD) boundary layer flow over a shrinking permeable sheet embedded in a moving viscous electrically conducting fluid is investigated both analytically and numerically. The velocity slip at the solid surface is taken into account in the boundary conditions. A novel analytical method named DTMBF is proposed and used to get the approximate analytical solutions to the nonlinear governing equation along with the boundary conditions at infinity. All analytical results are compared with those obtained by a numerical method. The comparison shows good agreement, which validates the accuracy of the DTM-BF method. Moreover, the existence ranges of the dual solutions and the unique solution for various parameters are obtained. The effects of the velocity slip parameter, the unsteadiness parameter, the magnetic parameter, the suction/injection parameter, and the velocity ratio parameter on the skin friction, the unique velocity, and the dual velocity profiles are explored, respectively. 相似文献
996.
Influence of ignition condition on the growth of silicon thin films using plasma enhanced chemical vapour deposition 下载免费PDF全文
The influences of the plasma ignition condition in plasma enhanced chemical vapour deposition (PECVD) on the interfaces and the microstructures of hydrogenated microcrystalline Si (μc-Si:H) thin films are investigated. The plasma ignition condition is modified by varying the ratio of SiH4 to H2 (RH). For plasma ignited with a constant gas ratio, the time-resolved optical emission spectroscopy presents a low value of the emission intensity ratio of Hα to SiH* (IHα/ISiH*) at the initial stage, which leads to a thick amorphous incubation layer. For the ignition condition with a profiling RH, the higher IHα/ISiH* values are realized. By optimizing the RH modulation, a uniform crystallinity along the growth direction and a denser μ c-Si:H film can be obtained. However, an excessively high IHα/ISiH* may damage the interface properties, which is indicated by capacitance-voltage (C-V) measurements. Well controlling the ignition condition is critically important for the applications of Si thin films. 相似文献
997.
Suvabrata Das Author VitaeKwok Fai CheungAuthor Vitae 《Wave Motion》2012,49(1):181-197
The steady forward motion of a marine vessel modifies the incident and scattered waves as well as its dynamic characteristics in a seaway. Small amplitude assumptions of the surface waves and vessel dynamic responses lead to linearization of the potential flow problem and its solution in the frequency domain. The mathematical formulation adopts a translating coordinate system at the vessel forward speed. The free surface boundary condition accounts for the modification of the uniform current around the vessel and a new radiation condition takes into account the Doppler shift of the scattered waves. A boundary element model, based on the Rankine source distribution, describes the steady and oscillatory flows around the vessel. Stokes’ theorem allows evaluation of the surface integrals involving the so-called m-terms due to oscillation of the vessel in a current. Through a numerical experiment with a Wigley hull form, we establish the convergence of the numerical model, verify the radiation condition, and examine the scattered wave patterns for a full range of forward speeds. Previous laboratory data provides validation of the computed hydrodynamic coefficients and dynamic response as well as the potential flow model for general seakeeping applications. 相似文献
998.
金属材料脆性断裂机理的实验研究 总被引:1,自引:0,他引:1
材料的脆性断裂有许多准则和模型,但对脆断机理和变化规律缺乏合理的描述,给工程应用带来不便。本文对典型脆性材料球墨铸铁、灰铸铁分别进行了拉扭双轴断裂实验和常规拉伸、扭转破坏实验;对韧性金属材料合金钢进行了单轴拉伸颈缩破坏实验。通过上述实验分析了脆性材料和韧性材料发生脆性断裂的机理特征并选择应力三维度作为应力状态参数描述危险点的应力状态,同时考察了脆性材料和韧性材料发生脆性断裂的主导因素。结果表明:韧性材料45#钢和14CrNiMoV合金钢在颈缩断面心部应力三维度值较大时发生脆性拉断,而在颈缩断面边缘处应力三维度值较小时发生剪断;脆性材料球墨铸铁在应力三维度值为0.0~0.33之间变化时均发生脆性断裂;灰铸铁在应力三维度值大于0.0时发生脆性拉断,而在应力三维度值小于0.0时发生剪断。因此可以认为,材料的细观组织结构和危险点应力状态是影响断裂机理及变化规律的主要因素。对于同种材料,随着应力三维度代数值从小向大变化材料的断裂机制由塑性剪切断裂逐渐转变为脆性断裂。本文通过对几种材料的脆性断裂危险点和断裂方向的研究给出了脆断宏观破坏条件。 相似文献
999.
圆柱壳的塑性膨胀和变形 总被引:1,自引:0,他引:1
根据材料不可压缩假设,适当选取材料塑性本构关系,将圆柱壳塑性膨胀运动简化为以圆柱壳内 半径为因变量的常微分方程初值问题。对3种初始内外半径比纯铜厚壁圆柱壳膨胀过程的计算表明,应变率 硬化阻碍圆柱壳的塑性膨胀运动,应变硬化和温度效应的影响可以忽略,而与圆柱壳的厚度无关。 相似文献
1000.
采用改装的霍普金森压杆装置结合数值模拟对伪弹性TiNi合金固支梁的结构动态响应特性进行了研究。结果表明,在子弹冲击下,撞击点和固定端附近首先发生相变,并随着载荷增加,进一步产生相变铰,梁演变为二杆铰接机构。由于轴力作用,此处相变铰为拉伸侧的单边铰。与传统塑性铰不同,卸载后相变铰完全消失,梁回复原状没有残余变形。此外,对固支边界条件的实现及其对实验结果的影响进行了专门研究。 相似文献