液氮浸泡式高性能ReBCO超导带材失超传播特性研究

高性能高温超导带材在大型超导磁体装置上的应用已成为一种趋势,由于存在失超传播速度缓慢、失超检测信号微弱等不足,对失超保护设计提出很大挑战。本文基于液氮浸泡式双保护层的高性能ReBCO带材失超传播特性,采用一维热平衡方程建立失超传播速度的数学模型,通过增加失超源,检测热点温度与电压信号,探究液氮浴环境下的ReBCO带材在传输电流等不同参数下失超传播速度和最小失超能量的变化规律。结果显示:相同条件下,高温超导带材的失超传播速度与传输电流成正相关,最小失超能量与传输电流成负相关,且相比无保护层的普通高温超导带材,具有双保护层的高性能ReBCO临界电流和触发裕度均有提升。     

Multilayered Activatable Nanoprobe for Ultra‐Bright Tumor Imaging

The development of tumor targeted probes with strong signal and high contrast is always challenging in cancer imaging. Here, a unique multilayered activatable nanoprobe (MAN) is prepared to fulfill this long‐standing goal. MAN adopts a versatile layer‐by‐layer fabrication technique that sequentially assembles multifunctional polyelectrolytes onto nanoparticles via charge‐charge interaction. Unlike the common one‐probe‐one‐fluorochrome construct, MAN offers a dramatic fluorescence enhancement by transporting a large quantity of quenched fluorochromes for maximal signal and contrast. Excellent signal amplification and retention with negligible cytotoxicity is observed in cell study. Upon systemic injection into mice, MAN quickly accumulates in tumor and its fluorescent signal is turned on by proteases overexpressed in tumors, resulting in >700% tumor‐to‐normal‐tissue contrast. This multilayered fabrication provides a simple and powerful universal platform to design sensitive tumor imaging probes.     

绿色荧光粉KNaCa2（PO4）2:Tb3+的制备及发光性能研究

采用高温固相法成功制备了KNaCa2(PO4)2:Tb3+绿色荧光粉,并研究了其发光性质。测量了其激发和发射光谱,样品发射峰位于418,440,492,545,586,622 nm,分别对应Tb3+的5 D3→7 F5,5 D3→7 F4,5 D4→7 F6,5 D4→7 F5,5 D4→7 F4,5 D4→7 F3能级跃迁,主发射峰位于545 nm。主激发峰位于350～390 nm之间,属于4f→4f电子跃迁吸收,与InGaN管芯匹配。确定了在KNaCa2(PO4)2基质中Tb3+浓度对其发光强度的影响及其自身浓度猝灭机制。研究了不同电荷补偿剂对KNaCa2(PO4)2:Tb3+材料发光的影响,其中Li+离子改善其发光强度最为明显。     

C掺杂MgB2超导线材的失超特性研究

研究了不同芯数(单芯、6芯和12芯)的C掺杂MgB2超导线材的失超特性.在制冷机环境(20K)下测量了C掺杂MgB2超导线材样品在自场下的最小触发能及失超传播速度.实验结果表明,失超传播速度随着工作电流的增大而线性增加.失超传播速度的大小跟测量位置有关,离触发区越近的传播速度越大.单芯样品的最小触发能最小,6芯和12芯线的最小触发能相差不大.最小触发能随工作电流的增加成指数形式衰减.     

Design of a superconducting magnet for CADS

This paper describes a superconducting magnet system for the China Accelerator Driven System (CADS). The magnetic field is provided by one main, two bucking and four racetrack coils. The main coil produces a central field of up to 7 T and the effective length is more than 140 mm, the two bucking coils can shield most of the fringe field, and the four racetrack superconducting coils produce the steering magnetic field. Its leakage field in the cavity zone is about 5× 10^-5 T when the shielding material Niobium and cryogenic permalloy are used as the Meissner shielding and passive shielding respectively. The quench calculations and protection system are also discussed.     

自旋1/2铁磁模型的相互作用淬火

本文设想了一个相互作用淬火后在 时刻开启的海森堡反铁磁模型,并对其进行了解析分析.在低温近似下,通过求解海森堡方程给出该系统随时间演化的自旋算符的解析形式.主要推算并讨论了自旋传播子,通过对传播子的讨论发现这个新体系的自旋波谱发生了变化.文末对此现象进行了讨论.     

Blow-up,quenching, aggregation and collapse in a chemotaxis model with reproduction term

In this paper,we consider the following chemotaxis model with ratio-dependent logistic reaction term u/t=D▽(▽u-u▽ω/ω)+u(α-bu/ω),(x,t)∈QT,ω/t=βu-δω,(x,t)∈QT,u▽㏑(u/w)·=0,x ∈Ω,0tT,u(x,0)=u0(x)0,x ∈,w(x,0)=w0(x)0,x ∈,It is shown that the solution to the problem exists globally if b+β≥0 and will blow up or quench if b+β0 by means of function transformation and comparison method.Various asymptotic behavior related to different coefficients and initial data is also discussed.     

Fluorine‐substituted azobenzene destabilizes polar form of optically switchable fulgimide unit in copolymer system

Fulgimide and various size and electronic nature of substituents on the terminal position of azobenzene in the pendant homo/copolymethacrylates were synthesized. Differential scanning calorimetry analysis indicates the homopolymer possessing C‐form fulgimide unit exhibited higher T_m than that of E‐form of the homopolymer and revealed C‐form is highly ordered. Thermal stability suggests azobenzene homopolymers with electron donating substituents have high thermal stability than electron withdrawing substituents. Polarized optical microscopy observation disclosed homopolymers viz., NI, CY, FL, ME , and T‐ME exhibited liquid crystalline mesophases between their T_m and T_i. Optical properties of homo/copolymers were investigated by UV–vis and fluorescence spectroscopy. UV–vis spectroscopy displayed C‐form fulgimide absorption in F‐co‐FL around 482 nm which is around 40 nm lesser than C‐form of substituted azobenzene copolymers. Similarly, fluorescence pattern of F‐co‐FL by UV irradiation exhibited emission intensity slowly increased to certain level then decreases with two new emissions at 430 and 480 nm attributed to terminal position of fluorine atom on azobenzene destabilizes polar form (C‐form) fulgimide unit in the copolymer. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 1565–1578, 2010     

基于四环素荧光熄灭测定碘的研究

基于碘对荧光试剂四环素的荧光熄灭,建立了测定微量碘的荧光分析方法。在pH10的碱性介质中,最大激发/发射波长分别为400.0nm/509.0nm,四环素的荧光强度与碘浓度的对数呈良好的线性关系,测定碘浓度的线性范围为3.20×10^-7～1.00×10^-4mol/L,检出限为1.30×10^-8mol/L,常见的共存离子不干扰测定。该方法适用于食盐中微量碘含量的测定。     

Super-FRS超导磁体失超瞬态热应力分析

国际反质子与离子大科学工程(FAIR)项目是一个大型的国际合作项目,其中Super-FRS超导二极磁体由中国科学院近代物理研究所研制。利用ADINA有限元程序对项目中的超导Super-FRS磁体线圈的失超过程进行了模拟分析。利用C程序对ADINA程序进行二次开发以便对有限元求解器的调用和载荷的控制。分析结果显示:在失超过程中产生的最大热应力为26 MPa,可能产生的声波频率在35 Hz左右。