用修正的RELIEF方法测量高速空气流瞬时速度的理论研究

修正了拉曼激发激光感应电子荧光（ＲａｍａｎＥｘｃｉａｔｉｏｎｐｕｌｓｅＬａｓｅｒ－ｉｎｄｕｃｅｄＥｌｅｃｔｒｏｎｉｃＦｌｕｏｒｅｓｃｅｎｃｅ简称ＲＥＬＩＥＦ）方法，以实现对亚音速和超音速空气流多点时速度的测量，测量精度优于２％。     

Sol-Gel Nanosized Semiconducting Titania-Based Powders for Thick-Film Gas Sensors

Pure, 5 at%, and 10 at% Ta- or Nb-doped TiO₂ nanosized powders were prepared by the sol-gel method. The powders heated to 400°C have the crystalline anatase structure. While the pure TiO₂ powder heated to 850°C has the rutile structure, the addition of Ta and Nb inhibited the anatase-to-rutile phase transformation at this temperature. Ta was soluble in the titania lattice up to the concentration of 10 at%, while the solubility of Nb was 5 at%. Thick films were fabricated with these powders by screen printing technology and then fired at 650°C and 850°C for 1 h. SEM observations showed that the anatase-to-rutile phase transformation induces a grain growth of about one order of magnitude for pure TiO₂. The addition of Ta and Nb is effective to keep the TiO₂ grain size at the nanometric level even at 850°C. Conductance measurements showed that a good gas response is observed only for the nanostructured titania-based films. The CO response of these materials is only slightly affected by humidity.     

一种新型的空气扰动探测方法

基于光折变材料的二波耦合特性提出了一种新型的空气扰动探测方法。空气中的微扰导致入射到光折变材料中两束光的光程差发生改变，干涉条纹随之发生变化。由于光折变体相位栅建立时间比较长，体相位栅不能及时跟随干涉条纹发生变化，导致干涉条纹与体相位栅间的相移将随空气扰动信息的变化而变化。相移角的改变将导致瞬态能量转移，输出两束光的能量在瞬态能量转移作用下将实现对空气扰动信息的光调制，并且这种调制过程是一种差分调制方式。在接收端采用电差分检测方法便可解调出空气扰动信息。这种利用光折变体相位栅的差分探测方法在未来的探测领域将有广泛的应用前景。     

球形钨合金破片空气阻力系数实验研究

 实验研究了理想球形钨合金破片和经历爆轰驱动的球形钨合金破片长距离飞行时的速度衰减规律。实验结果表明：（1）对于理想球形钨合金破片，在同一初始速度条件下，衰减系数为常数，空气阻力系数与初始速度有关，两者成线性关系；（2）对于经历爆轰驱动的球形钨合金破片，由于有轻微的质量损失和变形，速度衰减规律与理想球形钨合金破片有明显的区别，空气阻力系数与飞行速度有关，两者成线性关系。     

二次风率对分级进风燃烧室内湍流燃烧与NOx生成的影响

本文在分级进风燃烧室的热态实验装置上,测量了燃烧室内湍流燃烧的温度场和组分浓度场,研究了分级进风的流量比率即二次风率对燃烧及NOx生成的影响.得到了四组不同二次风率下燃烧室内气体温度和O2、CO2、CO与NO浓度的分布.     

Continuous flame oxidation in supercritical water

Abstract

Continuous flames have been observed in Supercritical water oxidation (scWO) of isopropyl alcohol (IPA), using a vertical continuous reactor with sapphire windows and a mixing nozzle. Two types of continuous flame were confirmed: the one was long pale blue colored and the other was red short cone shaped, changing blue to red at around air ratio 2.0. The flame was strongly influenced by IPA concentration, air ratio and design of the mixing nozzle. Results for decomposition of PA are presented for IPA concentrations ranging from 600 up to 28260 ppm as TOC and initial reactor temperatures, were mostly around 490°C, at 25 MPa. Decomposition rate at steady state was over 99.9%. Experimentally measured CO₂ and O₂ concentrations at the flue gas were in good agreement with theoretically calculated values. Even for low air ratio as 1.1, high decomposition rate without CO, NO, NO₂ was achieved.     

Chemical Kinetics Database and Predictive Schemes for Humid Air Plasma Chemistry. Part I: Positive Ion–Molecule Reactions

Reliable kinetic and thermodynamic data are required to model the evolution of electric discharge or electron-beam decomposition chemistry of gases in humid air streams. In this first segment of a continuing series, we provide a core database describing the initially dominant ion-neutral molecule reactions in humid air plasmas. Recommended reaction rate data and extrapolation tools are presented in a manner to facilitate prediction of reactivities and reaction channels as a function of temperature, pressure, and applied electric field.     

A Stochastic Model for Transport of Particulate Matter in Air: An Asymptotic Analysis

A branching particle system with changes of size is considered as a model for transport of particulate matter in air. This type of model is motivated by problems arising in the context of air pollution. High-density fluctuation limits for the process recording the positions and sizes of the particles through time are presented. These results allow to compute approximate probabilities for the temporal and spatial concentrations of particles of given sizes (in particular the small-sized pollutant particles which pose a health hazard).     

喷水室典型空气处理过程中空气流速的实验研究

针对纺织厂空调系统的核心-喷水室,研究喷水室内处理空气的冷却减湿和等焓加湿两个典型热湿交换过程。提出Re准数对传热传质有显著作用,而Re数的大小取决于流体速度。通过实验研究当空气流速从3m/s提高到5m/s时对喷水室热湿交换性能的影响,从而确定空气流动速度因素对两个热湿交换效率的影响趋势。根据拟合的数学曲线,总结出当空气的流动速度提高后,热湿交换效率相应提高。从而推动高速喷水室在实际工程中的应用。     

Research into conditions of quantitivity in the determination of carboniles in complex air matrices by adsorptive solid phase microextraction

This study focuses on certain aspects of the quantitivity of adsorptive solid phase microextraction when applied in the form of on-fibre derivatisation with O-(2,3,4,5,6)-pentafluorobenzyl-hydroxylamine hydrochloride (PFBHA) for the determination of carboniles in air samples of relevance in the atmosphere. The study was performed in the high-volume outdoor atmospheric simulation chambers (EUPHORE) located in Valencia (Spain). At short sampling times, the adsorption profiles obtained when only benzaldehyde was inserted in the chamber coincided with those obtained when other carbonylic compounds were also introduced at the same concentration, and this was also the case when the concentration of all the gaseous mixture components was increased considerably from one experiment to another. In a number of experiments applying different conditions, it was proven that all the extraction profiles belonged to the same regression when the fibre responses were plotted against the concentration-time product. A number of calibrations were obtained for benzaldehyde introduced in the chamber alone and in a mixture with three other carboniles at similar concentration values. A statistical test is applied to confirm that they all belonged to the same regression since they shared homogeneous variances. After these tests, the method of SPME on-fibre derivatisation for the determination of carboniles was considered to be safely applicable to quantification. Moreover, the concentration levels at which certain unwanted effects, i.e., displacement, saturation and competition, were observed are a few orders of magnitude higher than their occurrence levels in atmospheric processes.