Sol-Gel Nanosized Semiconducting Titania-Based Powders for Thick-Film Gas Sensors

Pure, 5 at%, and 10 at% Ta- or Nb-doped TiO₂ nanosized powders were prepared by the sol-gel method. The powders heated to 400°C have the crystalline anatase structure. While the pure TiO₂ powder heated to 850°C has the rutile structure, the addition of Ta and Nb inhibited the anatase-to-rutile phase transformation at this temperature. Ta was soluble in the titania lattice up to the concentration of 10 at%, while the solubility of Nb was 5 at%. Thick films were fabricated with these powders by screen printing technology and then fired at 650°C and 850°C for 1 h. SEM observations showed that the anatase-to-rutile phase transformation induces a grain growth of about one order of magnitude for pure TiO₂. The addition of Ta and Nb is effective to keep the TiO₂ grain size at the nanometric level even at 850°C. Conductance measurements showed that a good gas response is observed only for the nanostructured titania-based films. The CO response of these materials is only slightly affected by humidity.     

Mixing of a passive scalar across a thin shearless layer: concentration of intermittency on the sides of the turbulent interface

The advection of a passive scalar through an initial flat interface separating two different isotropic decaying turbulent fields is investigated in two and three dimensions. Simulations have been performed for a range of Taylor’s microscale Reynolds numbers from 45 to 250 and for a Schmidt number equal to 1. Different to the case where the transport involves the momentum and kinetic energy only and one intermittency layer is formed in the low-turbulent energy side of the system, in the passive scalar concentration field two intermittent layers are observed to develop at the sides of the interface. The layers move normally to the interface in opposite directions. The dimensionality produces different time scaling of the passive scalar diffusion, which is much faster in the two-dimensional case. In two dimensions, the propagation of the intermittent layers exhibits a significant asymmetry with respect to the initial position of the interface and is deeper for the layer which moves towards the high kinetic energy side of the system. In three dimensions, the two intermittent layers propagate nearly symmetrically with respect the centre of the mixing region. During the temporal decay, inside the mixing, which is both inhomogeneous and anisotropic but devoid of a mean velocity shear, the passive scalar spectra are computed. In three dimensions, the exponent in the scaling range gets in time a value close to that of the kinetic energy spectrum of isotropic turbulence (?5/3). In two dimensions, instead the exponent settles down to a value that is about one-half of the corresponding isotropic case. By means of an analysis based on simple wavy perturbations of the interface we show that the formation of the double layer of intermittency is a dynamic general feature not specific to the turbulent transport. These results of our numerical study are discussed in the context of experimental results and numerical simulations.