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971.
972.
Ana Paula F. Albers Thomaz A. G. Restivo Luciano Pagano Joo B. Baldo 《Thermochimica Acta》2001,370(1-2):111-118
Several experimental techniques either under steady state or transient heat transfer conditions, have been developed to evaluate thermal conductivity and thermal diffusivity of materials. However, testing difficulties resulting from specimen size, extended testing time and heat losses, have somewhat impaired the applicability of many of them. In this respect, the use of the laser flash technique for thermal diffusivity measurements, is a very convenient alternative, considering its basic modeling equation is independent of the temperature gradient as well as the heat flow, and in addition the heat losses can be analytically treated. Another important advantage of the technique is its rapid experimental execution. In this work, it is presented as an investigation concerning how the testing conditions such as specimen coating, laser power and pulse duration, base line adoption, heat losses correction methods, and specimen thickness, may affect the thermal diffusivity measurements of some ceramic materials using the laser flash technique. 相似文献
973.
974.
John F. Smalley Marshall D. Newton Stephen W. Feldberg 《Electrochemistry communications》2000,2(12):832-838
Theoretical relationships are developed to describe the open-circuit responses associated with the indirect laser-induced temperature-jump (ILIT) method, a method for measuring fast electron-transfer rate constants of surface-attached redox species. The analysis is also applicable to data obtained using the coulostatic charge-injection method. The unique relationship between km, the relaxation rate constant for the ILIT (or coulostatic) response, and Ei, the potential at which the system is initially poised, exhibits a surprising sensitivity to the values of k0, Ei0′ (the standard rate constant and formal potential for the redox couple), α (the transfer coefficient in the Butler–Volmer equation) and γ (a dimensionless parameter which is directly proportional to the total surface concentration of the redox moiety). ILIT data for several examples of surface-attached ferrocene moieties confirm the theoretically predicted km vs Ei behavior. Values of Ei0′ and γ extracted from the ILIT data agree well with the values obtained from cyclic voltammetric data thereby confirming that the ILIT and cyclic voltammogram (CV) experiments are sampling the same ferrocene population. 相似文献
975.
C. Goutaudier F. S. Ermeneux M. T. Cohen-Adad R. Moncorge 《Journal of Crystal Growth》2000,210(4):693-698
High-quality and crack-free Y2O3 single crystals containing low concentrations of Tm3+, Tb3+ and Yb3+ were obtained. The crystals were grown in the form of monocrystalline fibers by using a floating zone method with laser heating (laser-heated pedestal growth). 相似文献
976.
杂多化合物的性质对激光促进甲烷部分氧化反应性能的影响 总被引:3,自引:2,他引:1
合成了PW12、PMo12和NaPMo123种固体表面材料。采用IR、TPR、PTD和激光促进表面反应技术等手段,考察了固体表面材料的表面构造、晶格氧的活泼性和甲烷在固体表面的化学吸附以及部分氧化反应的规律。分别以980和960cm^-1的激光光子激发固体表面的W=O和Mo=O键,甲烷的部分氧化反应在100℃以上和常压下顺利进行。CH4在固体表面的吸附位、固体表面材料的晶格氧活性、激光频率和反应温 相似文献
977.
催化激光热透镜光谱法测定铜 总被引:5,自引:0,他引:5
基于铜催化邻苯二胺氧化反应,以激光热透镜光谱法测定微量铜,讨论了测定条件的影响。结果表明,该方法测定灵敏度高,在0.2-1.2μg/L铜(Ⅱ)浓度范围内呈线性关系,重现性及回收率实验均取得满意的结果。 相似文献
978.
激光诱导荧光光谱方法测量气溶胶颗粒研究 总被引:5,自引:4,他引:1
采用激光诱导荧光光谱方法测量大气中气溶胶颗粒物的散射荧光特性,同时用飞行时间方法测量颗粒物的动力学直径大小。给出了实验系统设计、测量方法、颗粒粒径分布图及散射荧光强度分布谱图的对比,并对多组实验数据进行分析。同时讨论了利用颗粒物散射荧光百分比分析方法判别生物粒子和非生物粒子的可行性。 相似文献
979.
激光诱导沉积银膜制备新型光纤SERS传感器 总被引:1,自引:1,他引:0
利用激光诱导沉积的方法直接在光纤端面沉积了银纳米膜,并用SERS光谱监测了这一沉积过程,在光纤端面上生成的银膜出现了“年轮”状宏观形貌,这种形貌与激光在光纤中的干涉与衍射条纹分布相一致,证明了这种现象是由激光诱导反应引发的. 结合实验结果进一步讨论了银纳米膜的形成机理. 在光纤上沉积的银纳米膜作为光纤SERS传感器的基底与其它制备基底的方法比较也具有实验操作简便,耗时短,重现性好,SERS增强效果强等诸多优点,是一种非常好的制备光纤SERS传感器基底的方法. 相似文献
980.
An analysis is made of the effect of Doppler broadening on gain
without inversion (GWI) from different aspects in a closed
lambda-type three-level system with an incoherent pump. It is shown
that, regardless of the driving field being on resonance or not, for
the counter- or co-propagating of the probe and driving fields (PDF),
GWI does not monotonically decrease or increase with increasing
Doppler width. Except for the case of counter-propagating PDF with
off-resonance driving field, at a suitable Doppler width one can
obtain a gain maximum value much larger than that without Doppler
broadening; especially in the situation of the resonant driving
field, the co-propagating geometry leads to a larger GWI. In
addition, for the counter-propagating geometry, when Doppler width is
larger enough, GWI oscillation occurs, and the oscillation amplitude
and region increase with increasing Doppler width. These conclusions
are very different from that obtained in previous investigation
(Lukin {\it et al}, {\it Laser Phys.} {\bf 6} 436 (1996)). 相似文献