单晶ZnO纳米棒的H2O2辅助水热法制备与表征

以二水醋酸锌和氢氧化钠为起始原料,采用H2O2辅助水热法制备了粒径分布均匀的ZnO纳米棒,用XRD、FTIR、FESEM、HRTEM和SEAD等手段对其进行了表征.结果表明,制备的ZnO纳米棒是单晶体,具有六边形截面并沿[0001]晶体方向生长.光致发光谱(PL)测试结果表明,添加H2O2制得的ZnO纳米棒在390nm...     

参数不确定性广义周期时变系统的鲁棒H_∞控制

研究状态矩阵和控制输入矩阵均具不确定性广义周期时变系统的鲁棒H_∞控制问题.提出参数不确定性广义周期时变系统广义可镇定和广义二次可镇定且具有H_∞性能指标的概念,利用线性矩阵不等式(LMI)方法,得到了参数不确定性广义周期时变系统广义二次可镇定且具有H_∞性能指标γ的充要条件,给出了相应的鲁棒H_∞状态反馈控制律的设计方法.最后,通过数值算例说明了设计方法的有效性.     

Minimal configuration bicyclic graphs

The nullity η(G) of a graph G is the multiplicity of zero as an eigenvalue of the adjacency matrix of G. If η(G)?=?1, then the core of G is the subgraph induced by the vertices associated with the nonzero entries of the kernel eigenvector. The set of vertices which are not in the core is the periphery of G. A graph G with nullity one is minimal configuration if no two vertices in the periphery are adjacent and deletion of any vertex in the periphery increases the nullity. An ∞-graph ∞(p,?l,?q) is a graph obtained by joining two vertex-disjoint cycles C _p and C _q by a path of length l?≥?0. Let ?* be the class of bicyclic graphs with an ∞-graph as an induced subgraph. In this article, we characterize the graphs in ?* which are minimal configurations.     

AREA INTEGRAL FUNCTIONS AND H∞ FUNCTIONAL CALCULUS FOR SECTORIAL OPERATORS ON HILBERT SPACES

Area integral functions are introduced for sectorial operators on Hilbert spaces. We establish the equivalence relationship between the square and area integral functions. This immediately extends McIntosh/Yagi＇s results on H∞ functional calculus of sectorial operators on Hilbert spaces to the case when the square functions are replaced by the area integral functions.     

罗丹明6G缔合微粒共振散射光谱法测定过氧化氢

在0.020mol.L-1HCl-4.0×10-4mol.L-1KI-1.6×10-5mol.L-1Mo(Ⅵ)介质中,罗丹明6G(RhG)在540nm处有1个荧光峰,在540nm处有1个同步荧光峰。当有H2O2存在时,H2O2与过量的I-反应生成I3-,I3-与RhG形成缔合微粒,在320,400,595nm处产生3个共振散射(RS)峰;而在540nm处荧光峰猝灭。H2O2浓度在0.068~34μg.mL-1范围内与400nm波长处的共振散射光强度呈线性关系。据此建立了一个测定水中H2O2的共振散射光谱分析法。光谱研究结果表明,(RhG-I3)n缔合微粒和界面的形成是导致体系RS增强和荧光猝灭的根本原因。     

双氧水分光光度法测定Ni-TiO2纳米复合镀层中TiO2的共析量

在硫酸介质中,Ti~(4 )与H_2O_2生成桔黄色络合物,最佳测定波长为407nm;研究了酸度、显色剂用量、显色时间及共存离子对测定结果的影响。结果表明,钛在0—10.0μg/mL范围内遵守朗伯比耳定律,其表观摩尔吸光系数为1.072×103L·mol~(-1)·cm~(-1)。此方法简便、准确,可用于Ni-TiO_2纳米复合镀层中TiO_2共析量的测定。     

高选择性H2O2电化学发光传感器的研制及分析特性研究

提出了基于鲁米诺和醋酸纤维素修饰碳糊电极构建H2O2电化学发光传感器的新方法。在最佳实验条件下,该传感器具有重现性好,抗干扰能力强和选择性好等优点,H2O2浓度在4.0×10-6～4.0×10-5mol L范围内与相对电化学发光强度呈线性关系。该方法测定H2O2的检出限为1.6×10-6mol L,相对标准偏差为1.4%,相关系数为0.9978。     

A simple and efficient synthesis of 2-substituted benzothiazoles catalyzed by H_2O_2/HCl

A simple and efficient procedure for the synthesis of substituted benzothiazoles through condensation of 2-aminothiophenol with aromatic aldehydes in the presence of H_2O_2/HCl system in ethanol at room temperature is described.The target compounds have been characterized by ~1H NMR,~(13)C NMR,IR and MS.Short reaction time,easy and quick isolation of the products,and excellent yields are the main advantages of this procedure.     

Oxidation of NO over cobalt oxide supported on esoporous silica

Cobalt oxide catalysts supported on mesoporous silica (Co3O4/MPS) were prepared, characterized and applied for catalytic oxidation of NO. Effects of catalyst supports, calcination temperatures, H2O and SO2 on NO conversion were investigated. The samples were also characterized by BET, XRD, FTIR and TG/DTG. The results suggested that Co3O4/MPS catalyst calcined at 573 K had the smallest crystal particles and the best surface dispersion. This catalyst had the highest activity and yielded 82% NO conversion at 573 K, at a space velocity of 12000 h−1. Although the conversion of NO decreased with the introduction of H2O, it could be restored completely after removing residual H2O from Co3O4/MPS catalyst by heating at 573 K. In the presence of SO2, the oxidation activity decreased and CoSO4 was detected on the catalyst. The NO conversion decreased to 30.2% in the presence of SO2 and H2O. It could not be restored completely after cutting off H2O and SO2. The deactivation of the catalyst in the presence of SO2 and H2O was attributed to the formation of cobalt sulfate species.     

奇异脉冲系统的奇异H_∞控制

主要研究奇异脉冲系统的奇异H∞控制问题.当系统不满足正则条件时,给出奇异脉冲系统的奇异H∞控制问题可解的充分条件,控制律使得闭环系统在保证内稳定的条件下达到干扰衰减.