H3PMo12O40 catalyzed three-component one-pot synthesis of 4,6-diarylpyrimidin-2(1H)-ones under solvent-free conditions

<正>4,6-Diarylpyrimidin-2(1H)-one derivatives have been synthesized from three-component one-pot condensation of acetophe-none derivatives,aldehydes and urea in the presence of trimethylsilyl chloride and a catalytic amount of H_3PMo_(12)O_(40)under solvent-free conditions.     

Robust H_∞ control for uncertain systems with heterogeneous time-varying delays via static output feedback

This paper is concerned with the problem of robust H∞ control for a novel class of uncertain linear continuous-time systems with heterogeneous time-varying state/input delays and norm-bounded parameter uncertainties.The objective is to design a static output feedback controller such that the closed-loop system is asymptotically stable while satisfying a prescribed H∞ performance level for all admissible uncertainties.By constructing an appropriate Lyapunov-Krasvskii functional,a delay-dependent stability criterion of the closed-loop system is presented with the help of the Jensen integral inequality.From the derived criterion,the solutions to the problem are formulated in terms of linear matrix inequalities and hence are tractable numerically.A simulation example is given to illustrate the effectiveness of the proposed design method.     

On the Structure of ∞-Harmonic Maps

Let H ∈ C ²(? ^N×n ), H ≥ 0. The PDE system arises as the Euler-Lagrange PDE of vectorial variational problems for the functional E _∞(u, Ω) = ‖H(Du)‖ _{L ^∞(Ω)} defined on maps u: Ω ? ? ⁿ  → ? ^N . (1) first appeared in the author's recent work. The scalar case though has a long history initiated by Aronsson. Herein we study the solutions of (1) with emphasis on the case of n = 2 ≤ N with H the Euclidean norm on ? ^N×n , which we call the “∞-Laplacian”. By establishing a rigidity theorem for rank-one maps of independent interest, we analyse a phenomenon of separation of the solutions to phases with qualitatively different behaviour. As a corollary, we extend to N ≥ 2 the Aronsson-Evans-Yu theorem regarding non existence of zeros of |Du| and prove a maximum principle. We further characterise all H for which (1) is elliptic and also study the initial value problem for the ODE system arising for n = 1 but with H(·, u, u′) depending on all the arguments.     

CO2加H2合成甲醇Cu－Zn－O催化剂表面化学态研究

应用XRD、ESR、URDS、XPS及XAES等手段研究了CO₂加H₂合成甲醇Cu-Zn-O催化剂在还原后和反应状态下的表面化学状态,结果表明,在还原及反应状态下,催化剂表面仅能检测到Cu⁰,而未发现稳定的Cu²⁺和Cu⁺存在;ZnO被部分还原产生低价锌Zn^2-δ(0<δ<2).关联活性测试结果认为,Cu⁰/Zn^(2-δ)+O构成CO₂加H₂合成甲醇反应的活性中心。     

C2H5C60H的加成产物的结构和光谱性质的量子化学研究

用INDO系列方法对C₂H₅C₆₀H的1,2-加成和1,4-加成两种产物异构体的结构进行了理论研究,结果表明1,2-C₂H₅C₆₀H具有Cs对称性,1,4-C₂H₅C₆₀H没有任何对称性,1,2-C₂H₅C₆₀H的总能量比1,4-C₂H₅C₆₀H的低。以此优化构型为基础,计算了两种产物异构体的电子吸收光谱,讨论了其光谱红移的原因,同时对产物的NMR谱进行了探讨。     

在负载铼催化剂上由CO2/H2合成甲醇的研究

CO加H₂合成甲醇的工作已应用于工业化生产,其中多采用锌、铬、铜基催化剂。而CO₂加H₂合成甲醇研究工作尚不很多,其催化剂多数是在CO/H₂制甲醇催化剂基础上发展而来。     

H2,CO和H2/CO在ZrO2催化剂上吸附行为研究

用insituFTIR法研究了H₂、CO及CO/H₂在ZrO₂表面的吸附行为.结果表明,H₂在ZrO₂表面吸附存在两种形态的羟基(即ZrOH和ZrOHZr),吸附温度增加,羟基数量增加.CO在200℃易与ZrO₂表面羟基作用形成甲酸盐物种,吸附温度升高时,该物种逐渐分解生成CO和ZrOH.当CO和H₂共存时,表面甲酸盐的量明显增加,并随温度增加,逐渐加氢形成甲氧基,最后生成甲烷.甲氧基的加氢过程较慢,所需反应温度也较高,被认为是CO加氢合成醇的速控步骤.     

MODAL SYNTHESIS METHOD FOR NORM COMPUTATION OF H ∞ DECENTRALIZED CONTROL SYSTEMS ( Ⅰ )

When using H ∞ techniques to design decentralized controllers for large systems,the whole system is divided into subsystems, which are analysed using H ∞ control theory before being recombined. An analogy was established with substructural analysis in structural mechanics, in which H∞ decentralized control theory corresponds to substructural modal synthesis theory so that the optimal H∞ norm of the whole system corresponds to the fundamental vibration frequency of the whole structure. Hence, modal synthesis methodology and the extended Wittrick-Williams algorithm were transplanted from structural mechanics to compute the optimal H ∞ norm of the control system. The orthogonality and the expansion theorem of eigenfunctions of the subsystems H∞ control are presented in part ( Ⅰ ) of the paper. The modal synthesis method for computation of the optimal H∞ norm of decentralized control systems and numerical examples are presented in part ( Ⅱ ).     

聚硫堇/过氧化氢光致电化学敏感界面的构建及其对葡萄糖氧化酶催化活性的测定

将具有光电活性的硫堇电聚合在光透电极的表面,制备了聚硫堇膜光电极,利用该电极同时具有光敏和电子受体的性能,使其与葡萄糖氧化酶对葡萄糖催化反应产生的电子供体(过氧化氢)发生光致电化学反应,通过检测由此产生的光电流实现对蛋白质催化活性的检测.本文探讨了聚硫堇/过氧化氢光致电化学敏感界面的响应机理,讨论了偏压、电解质溶液pH和底物浓度对光致电化学反应和测定葡萄糖氧化酶催化活性的影响.通过测定商品葡萄糖氧化酶的催化活性,验证了方法的可行性.应用该敏感界面检测蛋白质的催化活性不需要过氧化物酶,比光度法经济、简便和快速.     

时间分辨红外发射光谱研究C2H3+NO反应体系

C2H3是一个不饱和自由基及烃类化合物燃烧过程中的重要中间体,它的基元反应是影响燃烧过程速率和最终产物的重要反应.已有人在实验和理论方面研究了C2H3和O2,H2等体系[1－12]的基元反应,但迄今为止,我们还没有看到对于C2H3＋NO体系的研究报导.本文报导了用时间分辨傅立叶变换红外发射光谱（TR-FTIR）研究C2H3＋NO基元反应的结果.1实验　　C2H3自由基是在248nm（KrF激光,Lambda,Physik,LPX305i,单脉冲能量约为110mJ）光解C2H3Br产生的.时间分辨傅立叶变换红外发射光谱（FTIR）方法在我们以前的文章中已有介绍[13].实验…