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31.
利用还原偶联方法合成出新化合物四(4,4′,4",4′″-N,N-二乙氨基)四苯乙烯(TDEFE).通过测定该化合物在溶液、掺杂聚合物中及晶体粉末的稳态-瞬态荧光光谱、荧光量子产率和辐射衰变速率常数等,讨论了分子的构象效应等因素对TDETE光致发光行为的影响.在一定浓度下TDETE溶液存在着三个发光带,分别为全扭曲构象分子(位于345 nm附近的发光Ⅰ带)、半扭曲构象分子(位于430 nm附近的发光Ⅱ带)和激基缔合物(530 nm发光Ⅲ带)的辐射衰变所致.在聚合物(PMMA)中,一方面由于分子单键的自由旋转扭曲受到遏制,表现为Ⅱ带的辐射衰变速率常数(kf值)增大、同时非辐射衰变速率常数(knf值)减小;另一方面,TDETE分子之间相互作用得到加强而有利于缔合物形成,结果,使发光Ⅱ带和Ⅲ带合二为一出现了强而宽的发射峰,荧光量子产率从溶液中的0.055提高到0.855.此外,在PMMA介质中观测到TDETE分子聚集体在626 nm处的发光带(Ⅳ),粉末态中聚集体Ⅳ带的强度骤增,峰值波长红移至650 nm. 相似文献
32.
33.
The potential energy surfaces for the butoxy radical dissociation into R·+O on the six low-lying electronic states have been determined with the combined CASSCF and MR-CI methods. The isomerization reactions between the different conformers of 1- and 2-butoxy radicals at the X and B states have been also investigated with the MP2, B3LYP, and CASSCF methods. The non-radiative decay mechanisms of butoxy radicals at the B state have been characterized with the computed potential energy surfaces and intersections. Supported by recent LIF experimental results, it was predicted that the t-butoxy radical would predissociate via the B/C intersection. As to 1- and 2-butoxy radicals, the relative energies of the transition states for the isomerization reactions between conformers at the B state are much lower than those of the B/C intersections, resulting in the predominance of the isomerization in the decay of the B state for 1- and 2-butoxy radicals. 相似文献
34.
We present the comaprative study of semileptonic and leptonic decays of Ds, D±and D0meson(D →M l+-αl-β, D → l+αlβ, D → l+αvα;α,β=e,μ) within the framework of R-parity violating the( Rp) Minimal Supersymmetric Standard Model(MSSM). The comparison shows that combination and product couplings,(λβiα λ* ij qor λβqkλ*αj k)contribution to the branching fractions of the said processes(under consideration) is consistent with or comparable to the experimental measurements in most of the cases. However, some cases exist where these contributions are highly suppressed. We identify such cases in our analysis and single out the important ones suitable for exploring in the future and current experiments. 相似文献
35.
36.
We analyze the φ meson production in e^+e^- →ωπ^0 as a probe for studying the isospin violation mechanisms. By clarifying the dynamic sources causing the isospin violation, we succeed in quantifying those mechanisms with the help of the recent KLOE data. Hence, the φ→ωπ^0 branching ratio is extracted. We find that apart from the electromagnetic (EM) transitions, the strong transition via intermediate kaon loops plays an important role in understanding the cross section and its lineshape. 相似文献
37.
In a recent XUV photoabsorption spectrum of Cs Ⅲ ions by Cummings and O'Sullivan [2001 J. Phys. B 34 199], rather large linewidths were found for the 4d^95s^25p^6 - 4d^105s^25p^5 transition which are quite in disagreement with corresponding quasi-relativistic multiconfiguration Hartree Fock (MCHF) calculation. In the present work, a detailed multiconfiguration Dirac-Fock study has been carried out to explore this discrepancy. Owing to the detailed consideration of electron correlation effects, some ‘forbidden' Auger decay channels, such as 4d^105s^25p^35d and 4d^105s^05p^6, would become ‘open'. As a result, remarkable improvement of the linewidths has been obtained in our calculation. Furthermore, the theoretical Auger spectrum of the 4d^ 95s^25p^6 core-excited states of Cs Ⅲ ions is Riven in the present work. 相似文献
38.
The photo-excitation and Auger decay processes of inner-shell double vacancy states 1s2s2p^6(1,3^S)3s3p of neutral neon atoms have been studied theoretically. Multi-configuration Dirac-Fock (MCDF) calculations have been carried out, with electron correlation effects taken into consideration. The relaxation of core and excited orbitals and configuration interaction are found to be crucial to creating the double vacancy states by single photo-absorption. The predominant decay paths for the double vacancy states turn out to be of the LLM Auger decay to 1s 2s^22p^53s(3p), KLL Auger decay to 1s^22s2p^43s3p, and KLM Auger decay to 1s^22p^63s(3p). They lead to further Auger decay, creating the neon ions of multiple charge states. For both double and single vacancy states the spectator type of Auger process is dominated in all the Auger decay processes. Theoretical Anger electron spectra are presented for further investigations, experimental and theoretical. 相似文献
39.
Coliins低能诱导6179Hfm^m2辐射衰变“正”面实验结果受到质疑的原因之一是未能确定出诱导实验的中间激发态。^178Hf核能级结构的实验数据表明:距同质异能态^178Hf^m2(2.446Mev)最近的一条能级是2.573MeV(K^π=14^+)。因此,详细计算^178Hf核2.44-2.6MeV范围内高自旋、高激发核能级结构,对寻找低能诱导^178Hf^m辐射衰变中间激发态,分析低能诱发辐射实验可行性非常必要。 相似文献
40.
265Bh(Z=107)同位素的首次观测 总被引:1,自引:0,他引:1
在兰州的重离子加速器上用26Mg离子束轰击243Am靶,产生了新同位素265Bh.通过观测新同位素265Bh和它的已知子核261Db和257Lr之间的α衰变的关联,实现了对新核素的鉴别.实验中使用了一套新建立的具有数个探测器对的转轮收集探测系统.将该系统用于特殊的母–子核搜索模式,从而大大减少了本底.共测得了8个265Bh的α衰变关联事件;同时4个已知核264Bh的衰变关联事件也被鉴别出来.实验测得265Bh的α衰变能量为(9.24±0.05)MeV,半衰期为0.94+0.70–0.31s. 相似文献