烯丙基-β-环糊精基手性毛细管电色谱整体柱的一步法制备及其性能

以烯丙基-β-环糊精、甲基丙烯酸缩水甘油酯和乙二醇二甲基丙烯酸酯为功能单体,一步键合制备了环糊精聚合物毛细管整体柱.在电色谱模式下18种氨基酸对映体得到成功分离.研究发现,将修饰的环糊精衍生物作为功能单体制备出的毛细管整体柱对疏水性,含氨基和苯环的手性化合物具有良好的保留行为,并具有良好的稳定性和重现性.新型电色谱柱也被应用于手性药物的分离.     

电沉积法制备介孔TiO_2/CdS薄膜光电极

采用阴极恒电位沉积法,在介孔TiO2薄膜上制备了介孔TiO2/CdS薄膜光电极,用XRD,SEM,Raman,SPS和UV-Vis等多种手段对薄膜电极进行了表征.结果表明,CdS成功沉积到介孔TiO2的表面和孔道内,形成了异质结结构.通过光电流作用谱考察了该复合体薄膜电极的光电性能,结果表明,与单纯的介孔TiO2薄膜相比,其光电转换效率显著提高,这是由于CdS具有吸收可见光的特性以及CdS与介孔TiO2形成异质结从而使得光生载流子更容易分离的结果.     

m-Ferrocenylbenzoate-bridged lanthanide coordination polymers: Syntheses, structures, electrochemical and magnetic properties

A series of m-ferrocenylbenzoate [m-ferrocenylbenzoate = m-NaOOCH₄C₆Fc, Fc = (η⁵-C₅H₅)Fe(η⁵-C₅H₄)] lanthanide coordination polymers, namely [Ln(μ₂-OOCH₄C₆Fc)(η²-OOCH₄C₆Fc)(μ₂-η²-OOCH₄C₆Fc)(CH₃OH)₂]_n [Ln = La (1), Pr (2), Nd (3), Sm (4) and Gd (5)], have been synthesized by reactions of m-ferrocenylbenzoate with Ln(NO₃)₃·nH₂O. X-ray crystallographic analyses reveal that 1, 2 and 5 are essentially isostructural with unique one-dimensional linear chain structure. Three types of coordination modes for m-ferrocenylbenzoate are observed in the unit structure which consists of the eight-membered metallacycle Ln₂(COO)₂ and the rhomboid Ln₂O₂. Electrochemical studies indicate that 1-5 exhibit a reversible redox wave of Fe^II/Fe^III and the half-wave potentials of 1-5 are slightly more positive than that of m-ferrocenylbenzoic acid. Magnetic investigations show that an antiferromagnetic interaction between Gd(III) ions exists in 5.     

Non-local theory solution of two collinear mode-I cracks in piezoelectric materials

In this paper, the basic solution of two collinear cracks in a piezoelectric material plane subjected to a uniform tension loading is investigated by means of the non-local theory. Through the Fourier transform, the problem is solved with the help of two pairs of integral equations, in which the unknown variables are the jumps of displacements across the crack surfaces. To solve the integral equations, the jumps of displacements across the crack surfaces are directly expanded in a series of Jacobi polynomials. Numerical examples are provided to show the effects of the interaction of two cracks, the materials constants and the lattice parameter on the stress field and the electric displacement field near crack tips. Unlike the classical elasticity solution, it is found that no stress and electric displacement singularities are present at crack tips. The non-local elastic solutions yield a finite hoop stress at the crack tip, thus allowing us to using the maximum stress as a fracture criterion in piezoelectric materials.     

Application of SPE Using Multi-Walled Carbon Nanotubes as Adsorbent and Rapid Resolution LC-MS-MS for the Simultaneous Determination of 11 Triazine Herbicides Residues in River Water

A method for the simultaneous determination of 11 triazine herbicides residues in river water has been developed. It involves solid-phase extraction (SPE) pretreatment step and rapid resolution liquid chromatography-tandem mass spectrometry (RRLC-MS-MS). In the SPE pretreatment step, the adsorptive performance of MWCNTs material as SPE adsorbent and the elution capability of five kinds of solvents were investigated; in the LC separation step, a rapid resolution high throughput LC column, was used and the gradient elution mode adopted. The linear correlation coefficients (r ²) of the method for 11 target analytes varied between 0.9930 and 0.9980, the mean recoveries were in the range of 73.0 and 98.0% with relative standard deviations (RSD) 2.6 ~ 4.2%, the method detection limits (MDL) were all below 0.1 ng L^?1. An expanded uncertainty of not more than 20% was estimated for each analyte at the spiked concentration of 4.0 μg L^?1. The proposed method was applied to the determination of the residue concentrations of 11 pollutants in Songhuajiang River water.     

On-line capillary electrophoresis FTIR detection for the separation and characterization of proteins

Capillary electrophoresis (CE) with on-line FTIR spectroscopic detection was used to separate a mixture of three model proteins and to provide information on the dominant secondary structures of the separated proteins. On-line FTIR transmission measurements were achieved using a micro-machined flow cell made out of CaF₂ and SU-8 polymer which was attached to the fused silica capillaries using commercial O-rings. The IR beam was focused on the detection window using an off-axis parabolic mirror attached to an external optical port of the spectrometer. As the absorption of water heavily overlaps the so-called amide I band of the proteins the separations were carried out in heavy water (D₂O). The model proteins studied were myoglobin, α-lactalbumin and β-lactoglobulin having different secondary structures. It could be shown that the performance of the separation was comparable to conventional UV–vis detection and that the IR-peak positions of the proteins studied were the same as obtained in reference measurements using the ATR technique.     

聚酰亚胺薄膜的电致发光和光致发光

测量了氙灯辐照后聚酰亚胺(PI)薄膜的光致发光(PL)强度、PL谱和氙灯辐照后直流高电场下PI薄膜的电致发光(EL)强度、EL谱、XRD谱和吸收光谱,研究了其EL、PL特性与微观结构的关系.结果表明:PI薄膜的PL强度随测量时间呈指数衰减,EL强度随场强呈指数增长;辐照39 h后,PI的预击穿场强为2.56MV/cm,...     

Optical characterization of antimony-based bismuth-doped thin films with different annealing temperatures

Antimony-based bismuth-doped thin film,a new kind of super-resolution mask layer,is prepared by magnetron sputtering.The structures and optical constants of the thin films before and after annealing are examined in detail.The as-deposited film is mainly in an amorphous state.After annealing at 170-370℃,it is converted to the rhombohedral-type of structure.The extent of crystallization increased with the annealing temperature.When the thin film is annealed,its refractive index decreased in the most visible region,whereas the extinction coefficient and reflectivity are markedly increased.The results indicate that the optical parameters of the film strongly depend on its microstructure and the bonding of the atoms.     

Laser-induced quadrupoleben quadrupole collisional energy transfer in Xe-Kr

By considering the relative velocity distribution function and multipole expansion interaction Hamiltonian, a three-state model for calculating the cross section of laser-induced quadrupole-quadrupole collisional energy transfer is presented. Calculated results in Xe-Kr system show that in the present system, the laser-induced collision process occurs for ~4 ps, which is much shorter than the dipole-dipole laser-induced collisional energy transfer (LICET) process. The spectrum of laser-induced quadrupole-quadrupole collisional energy transfer in Xe-Kr system has wider tunable range in an order of magnitude than the dipole-dipole LICET spectra. The peak cross section decreases and moves to the quasi-static wing with increasing temperature and the full width at half peak of the profile becomes larger as the system temperature increases.     

基于SBS光限幅和金属酞菁光限幅相结合的复合型光限幅器的研究

为了使受激布里渊散射(SBS)光限幅器的输出能量更"平",提出了一种基于SBS光限幅和金属酞菁光限幅相结合的复合型光限幅器的方案,即SBS光限幅后边放置金属酞菁光限幅,在两种光限幅器的共同限幅作用下,使复合型光限幅器的输出光能量更"平". 数值模拟了该复合型光限幅器的输出光能量随入射光强度的变化曲线,并在Countinuum's Nd: YAG种子注入式激光器中进行了实验验证. 理论和实验结果均表明,复合型光限幅器的输出光能量比单独SBS光限幅器更"平". 关键词： 复合型光限幅器 SBS光限幅 金属酞菁限幅