全文获取类型
收费全文 | 3562篇 |
免费 | 255篇 |
国内免费 | 713篇 |
专业分类
化学 | 3229篇 |
晶体学 | 89篇 |
力学 | 58篇 |
综合类 | 9篇 |
数学 | 347篇 |
物理学 | 798篇 |
出版年
2024年 | 4篇 |
2023年 | 115篇 |
2022年 | 75篇 |
2021年 | 145篇 |
2020年 | 137篇 |
2019年 | 37篇 |
2018年 | 39篇 |
2017年 | 45篇 |
2016年 | 69篇 |
2015年 | 102篇 |
2014年 | 184篇 |
2013年 | 198篇 |
2012年 | 308篇 |
2011年 | 305篇 |
2010年 | 225篇 |
2009年 | 281篇 |
2008年 | 321篇 |
2007年 | 328篇 |
2006年 | 339篇 |
2005年 | 253篇 |
2004年 | 200篇 |
2003年 | 125篇 |
2002年 | 101篇 |
2001年 | 86篇 |
2000年 | 131篇 |
1999年 | 63篇 |
1998年 | 48篇 |
1997年 | 39篇 |
1996年 | 47篇 |
1995年 | 24篇 |
1994年 | 35篇 |
1993年 | 41篇 |
1992年 | 32篇 |
1991年 | 23篇 |
1990年 | 9篇 |
1989年 | 5篇 |
1988年 | 6篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1976年 | 1篇 |
1936年 | 1篇 |
排序方式: 共有4530条查询结果,搜索用时 15 毫秒
31.
33.
HOU Xiao-Mina b CHEN Ming-Huanga② XIE Jie-Mingc YE Xiao-Minga ZHAO Geng-Xianga b YANG Fenga b CHEN Li-Qingd HUANG Ming-Donga a 《结构化学》2006,25(9):1035-1038
1 INTRODUCTION The ribosome-inactivating proteins (RIPs) are RNA N-glycosidases[1, 2] which inactivate ribosomes by cleaving a single N–C glycosidic bond between adenine and ribose at A4324 in the 28s rRNA of rat. Because of the removal of one adenine from rRNA, elongation factorⅡ(EF-2) can not bind to the 60S subunit, so RIPs can arrest protein synthesis. RIPs can be classified into three types based on the struc- tures of genes and mature proteins[3]. Type 1 RIPs with molec… 相似文献
34.
35.
Suyun Jie Tianzhu Zhang Jiutong Chen Dongbing Liu Wei Chen 《Journal of organometallic chemistry》2005,690(7):1739-1749
A series of bridged bis(pyridinylimino) ligands were efficiently synthesized through the condensation reaction of 4,4′-methylene-bis(2,6-disubstituted aniline) with 2-pyridinecarboxaldehyde or 2-benzoylpyridine. They reacted with (DME)NiBr2 to form dinuclear Ni(II) complexes. All resultant compounds were characterized by elemental analysis, IR spectra as well as the single-crystal X-ray diffraction to confirm the structures of ligands and complexes. Activated with methylaluminoxane (MAO), these nickel complexes showed considerably good activities for ethylene oligomerization and polymerization. Their catalytic activities and the properties of PEs obtained were depended on the arched environment of ligand and reaction conditions. 相似文献
36.
A new nickel(Ⅱ)-dicyanamide compound, [Ni(dca)2(en)]n (1) (dca=dicyanamide anion, [N(CN)2]-); en=ethylene diamine), has been synthesized and its structure has been determined by single crystal X-ray diffraction analysis. The crystal is monoclinic, space group P21/n with unit cell dimensions: a=0.694 3(1) nm, b=1.041 5(2) nm, c=1.4132(2) nm, and β=90.381°, Z=4, V=1.011 0(3) nm3. In this compound, the adjacent nickel atoms are connected by dca all in μ1,5-bridging mode to form ladder-like units, which are linked with double dca bridges to generate a regular infinite stair-like structure. Temperature-dependent magnetic susceptibility was also characterized for this compound. CCDC: 208276. 相似文献
37.
38.
对近期发展的固体圆二色(CD)光谱测试方法进行了概述、评价和比较, 着重探讨了“浓度效应”的存在使固体CD光谱失真的原因. 通过对本课题组和其他作者已报道的四种化合物的固体CD谱再测试的反思, 强调了依手性化合物的手性光谱学性质不同, 根据浓度梯度实验选择其合适测试浓度的必要性. 对固有手性的阻转异构化合物(S)-1,1'-联二萘酚(S-BINOL)进行了成膜法固体CD谱浓度梯度测试, 发现所得固体薄膜CD谱中也存在着“浓度效应” 相似文献
39.
Characterization of the Nanoscale Microstructure of an Immersion Silver on Sputtered Copper 总被引:1,自引:0,他引:1
TANG Dian WEI Zhe-Liang SHAO Yan-Qun YOU Shao-Xin O‘KEEFE Mathew O‘ KEEFE Thomas 《结构化学》2005,24(8):935-939
1 INTRODUCTION Silver and its compounds have received much attention due to their current and potential applica- tions in many areas[1, 2]. As a metal with the highest electrical and thermal conductivities, silver was one of the most important noble metals used in electrical industries in the last century. Several decades ago, however, the development of silver application in electronic area seemed not so quick. The fear for some undesirable phenomena involving silver, like “electrochemi… 相似文献
40.
XIANG Sheng-Chang SHENG Tian-Lu FU Rui-Biao HU Sheng-Min WU Xin-Tao ② 《结构化学》2006,25(5):631-635
1 INTRODUCTION Amino acids (AA) are some of the most important biological ligands, and metal ions are known to par- ticipate in a variety of biological reactions, therefore, research on the coordination behavior of metal-ami- no acid complexes is one of the most essential ele- ments of chemical biology[1, 2]. For over three deca- des their structures have been of considerable inte- rest and importance in coordination chemistry[2, 3]. Studies of these relatively simple complexes may en- ha… 相似文献