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| 对固体圆二色光谱测试方法的再认识——兼谈“浓度效应” | |
| 引用本文： | 章慧,颜建新,吴舒婷,李丹,万仕刚,丁雷,林丽榕.对固体圆二色光谱测试方法的再认识——兼谈“浓度效应”[J].物理化学学报,1985,29(12):2481-2497. |
| 作者姓名： | 章慧 颜建新 吴舒婷 李丹 万仕刚 丁雷 林丽榕 |
| 作者单位： | 1 厦门大学化学化工学院化学系, 福建厦门 361005; 2 福州大学化学化工学院化学系, 福州 350108; 3 中国科学院福建物质结构研究所, 结构化学国家重点实验室, 福州 350002 |
| 基金项目： | 国家自然科学基金(21273175, 21271150, 21001026)和中国科学院福建物质结构研究所结构化学国家重点实验室基金(20110006, 20130008)资助项目 |
| 摘 要： | 对近期发展的固体圆二色(CD)光谱测试方法进行了概述、评价和比较, 着重探讨了“浓度效应”的存在使固体CD光谱失真的原因. 通过对本课题组和其他作者已报道的四种化合物的固体CD谱再测试的反思, 强调了依手性化合物的手性光谱学性质不同, 根据浓度梯度实验选择其合适测试浓度的必要性. 对固有手性的阻转异构化合物(S)-1,1'-联二萘酚(S-BINOL)进行了成膜法固体CD谱浓度梯度测试, 发现所得固体薄膜CD谱中也存在着“浓度效应” |
| 关 键 词： | 固体手性光谱 圆二色 测试方法 浓度效应 阻转异构 镜面对称性破缺 |
| 收稿时间： | 2013-07-19 |
| 修稿时间： | 2013-10-15 |
Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects |
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| ZHANG Hui,YAN Jian-Xin,WU Shu-Ting,LI Dan,WAN Shi-Gang,DING Lei,LIN Li-Rong.Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects[J].Acta Physico-Chimica Sinica,1985,29(12):2481-2497. | |
| Authors: | ZHANG Hui YAN Jian-Xin WU Shu-Ting LI Dan WAN Shi-Gang DING Lei LIN Li-Rong |
| Institution: | 1 Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China; 2 Department of Chemistry, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108, P. R. China; 3 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Struture of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China |
| Abstract: | In this paper, the recent developments in measurement methods of solid-state circular dichroism (CD) spectroscopy were summarized and discussed, especially the effects of concentration on solid-state CD spectral distortions. By reinspection and introspection of the solid-state CD spectra of four reported compounds, concentration gradient measurements were proved to be necessary for appropriate concentrations, which are greatly related to the chiroptical properties. The thin film solid-state CD measurements of the inherently chiral atropisomer (S)-1,1'-bi-2-naphthol (S-BINOL) were carried out with concentration gradient measurements. Using this film-state technique for the first time, the results show some subtle correlations between the CD curves and the special concentrations. |
| Keywords: | Solid-state chiroptical spectroscopy Circular dichroism Method of measurement Concentration effect Atropisomerism Mirror symmetry breaking |
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