FTIR Spectroscopy in Cultural Heritage Studies:Non-destructive Analysis of Chinese Handmade Papers

Chinese handmade papers have been the carriers of paper-based documents, paintings and calligraphies, which are of great importance for historical and cultural heritage studies. This research developed the attenuated total reflectance-Fourier transform infrared(ATR-FTIR) spectroscopic technique for the analysis of Chinese handmade papers. The test was applied to Chinese handmade papers taken from bark, hemp and bamboo groups, followed by papers from ancient books and arts collected in library and museum. Our study indicated tliat FTIR was an efficient analytical method to identify fiber types of library/museum papers of unknown origin. Moreover, information about degree of crystallinity and state of deterioration of cellulosic fibers was learned from FTIR spectra. This research provides a non-destnictive method to study the molecular structure of cellulosic fibers, and guides tlie selection of appropriate Chinese handmade papers for the restoration of cultural heritage objects.     

中高能质子与核碰撞反应机制的研究

用量子分子动力学模型,在质子能量为200MeV、585MeV和1000MeV的情况下,对P+⁵⁶Fe的碰撞反应机制进行了研究,并计算了核子能谱、碎块质量分布随时间的演化以及中子发射的双微分截面等,得到了合理的结果.     

不同厚度溅射Ag膜的微结构及光学常数研究

用直流溅射法在室温Si基片上制备了4．9nm-189.0nm范围内不同厚度的Ag薄膜，并用X射线衍射及反射式椭偏光谱技术对薄膜的微结构和光学常数进行了测试分析。结构分析表明：制备的Ag膜均呈多晶状态，晶体结构仍为面心立方；随膜厚增加薄膜的平均晶粒心潮6．3nm逐渐增大到14．5nm；薄膜晶格常数均比标准值（0．40862nm)稍小，随膜厚增加，薄膜晶格常数由0．40585nm增大到0.40779nm。250nm-830nm光频范围椭偏光谱测量结果表明：与Johnson的厚Ag膜数据相比，我们制备的Ag薄膜光学折射率n总体上均增大，消光系数k变化复杂；在厚度为4．9nm-83.7nm范围内，实验薄膜的光学常数与Johnson数据差别很大，厚度小于33．3nm的实验薄膜k谱线中出现吸收峰，峰位由460nm红移至690nm处，且其对应的峰宽逐渐宽化；当膜厚达到约189nm时，实验薄膜与Johnson光学常数数据已基本趋于一致。     

具$w_0$-距离度量空间中$p$-逼近$\alpha$-$\eta$-$\beta$-拟压缩的最佳逼近点定理

本文提出了一类称为$p$-逼近$\alpha$-$\eta$-$\beta$-拟压缩的新的非自映射,并引进了关于$\eta$的$\alpha$-逼近可容许映射和关于$\eta$的$(\alpha,d)$正则映射的概念.基于这些新概念,在$w_0$-距离度量空间中研究了此类新压缩最佳逼近点的存在唯一性,并给出了一个新的定理,推广和补充了文[Ayari, M. I. et al. Fixed Point Theory Appl., 2017, 2017: 16]和[Ayari, M. I. et al. Fixed Point Theory Appl., 2019, 2019: 7]中的结果.给出了一个例子来说明主要结果的有效性.进一步地,作为推论得到关于两个映射的最佳逼近点和公共不动点定理.作为其中一个推论的应用,讨论了一类Volterra型积分方程组的求解问题.     

Metal-Organic Frameworks Nanocarriers for Functional Nucleic Acid Delivery in Biomedical Applications

Metal−organic frameworks (MOFs), a distinctive funtionalmaterials which is constructed by various metal ions and organic molecules, have gradually attracted researchers′ attention from they were founded. In the last decade, MOFs emerge as a biomedical material with potential applications due to their unique properties. However, the MOFs performed as nanocarriers for functional nucleic acid delivery in biomedical applications rarely summarized. In this review, we introduce recent developments of MOFs for nucleic acid delivery in various biologically relevant applications, with special emphasis on cancer therapy (including siRNA, ASO, DNAzyme, miRNA and CpG oligodeoxynucleotides), bioimaging, biosensors and separation of biomolecules. We expect the accomplishment of this review could benefit certain researchers in biomedical field to develop novel sophisticated nanocarriers for functional nucleic acid delivery based on the promising material of MOFs.     

Ce∶KNSBN光折变晶体光栅衍射特性研究

研究了Ce∶KNSBN光折变晶体两波耦合作用写入体光栅的衍射效率与写入光偏振态和光强比的关系 ,分析了写入光偏振态造成光栅衍射效率差别的原因 ,并用修正耦合波理论对实验结果进行了拟合。实验结果为Ce∶KNSBN晶体在全息记录和光学信息处理领域的应用提供了依据。     

H2PdCl4和竞争吸附剂在Al2O3上吸附的研究

研究了H₂PdCl₄和乙酸等有机酸在Al₂O₃上的吸附行为,发现H₂PdCl₄和乙酸等六种竞争吸附剂在Al₂O₃上均呈Langmuir型等温吸附,得到了H₂PdCl₄在Al₂O₃上的吸附速度式,注意到溶液的pH值和竞争吸附剂对H₂PdCl₄的吸附动力学曲线均有影响。考察了H₂PdCl₄和竞争吸附剂共存溶液的紫外吸收光谱,对H₂PdCl₄在Al₂O₃上的浸渍过程进行了讨论。     

投影式头盔物镜设计在视空间的性能评价

对一款折衍混合投影式头盔(Head-mounted projective displays,HMPDs)物镜进行了精确的视空间评价,并给出了详细的评价步骤和评价结果。在对调制传递函数(MTF)进行评价时,充分考虑了人眼的焦距和瞳孔对评价结果的影响,给出了调节和像散所造成的分辨力损失的计算公式。评价结果显示:对于3 mm瞳孔,该系统中心视场调制传递函数在0.5 cycles/(′)达到了0.55,达到了人眼的最小分辨角(1′)。当眼睛注视投影像面中心时,轴外点最大需要0.35D的调节量,由此造成的分辨力损失最大为3.5′。由于像散造成的分辨力损失最大只有1.1′。横向色差和二级光谱最大值分别只有0.57′和0.17′,均小于人眼的最小分辨角。这些结果证明此设计满足投影式头盔物镜的使用需要。该方法适用于所有的头盔系统在视空间的性能评价。     

Rapid identification of gallotannins from Chinese galls by matrix‐assisted laser desorption/ionization time‐of‐flight quadrupole ion trap mass spectrometry

Chinese gall, a conventional traditional Chinese medicine, contains high levels of gallotannins. A rapid method for direct analysis of the gallotannins without using any troublesome sample pretreatments was developed using matrix‐assisted laser desorption/ionization time‐of‐flight quadrupole ion trap mass spectrometry (MALDI‐QIT‐TOF MS) to successfully identify the gallotannin components in the crude extract of Chinese galls within several minutes. The high quality of the MS and MS² spectra acquired clearly showed that hydrolysable tannins in Chinese galls were identified as a series of the gallotannins with degrees of polymerization (DP) of 4–11 galloyl units. The MS² data indicated that the identified gallotannins with DP of 4–7 galloyl units had clear fragmentation with loss of 1–5 galloyl units which were further deprived of 1–3 water moieties. This technique may be used for rapid evaluation and screening of hydrolysable tannins in medicinal plants. Copyright © 2009 John Wiley & Sons, Ltd.