混配配合物[Co(cpida)(C7H5N2)2]·C7H5N2·5H2O

在溶液中用N-(邻苯甲酸基)-亚氨基二乙酸、苯并咪唑和Co(Ac)2·4H2O进行自组装合成了标题三元金属混配配合物.用元素分析、红外光谱、单晶衍射对配合物的组成和结构进行了表征,确定配体N-(邻苯甲酸基)-亚氨基二乙酸中的3个羧基为单齿形式与中心金属钴离子配位.     

混杂配体金属簇合物的分子振动光谱与结构

由于原子簇化合物在催化，生物活性，功能材料等方面所呈现的重要性，使其成为无机和物理化学最重要的研究领域之一。文章中和谱学方法对一些具有混配体的过渡金属簇合物的结构及其两者之间的关系进行.     

0.351μm激光辐照Au盘靶吸收、散射规律的实验研究

在“星光Ⅱ”激光装置上，利用80只分立式探测器研究了约0.8ns，0.351μm激光辐照Au盘靶的吸收、散射．结果表明，强度约为5×10¹⁴W/cm²的激光以10°角入射，吸收可达90%以上；但是，以45°角入射，吸收仅为75%左右，散射高达25%．散射主要来自未被等离子体充分吸收的激光在弯曲临界面上的反射，同时伴随少量受激布里渊散射．吸收的理论计算与实验结果进行了比较，两者符合较好． 关键词：     

Heterolytic and Homolytic N-NO Bond Dissociation Energies of N-Nitroso-benzenesulfonylmethylamines in Acetonitrile

Great interests have been accumulated in recent years in the chemistry and biochemistry of nitric oxide (NO) since the remarkable discoveries of its key roles in a wide range of human physiological processes. To elucidate the mechanistic details of NO migration from its donor to its acceptor, it is necessary to determine the Y-NO bind energy that registers the thermodynamic driving force for NO release and capture. In this paper the heterolytic and homolytic N-NO bond dissociation energies [ i. e., △Hhet(N-NO) and △Hhomo(N-NO)] for ten N-nitroso-p-substituted-benzensulfonyl methylamines in acetonitrile are offered, which were obtained from titration calorimetry and thermodynamic cycles, respectively (Scheme 1).     

Low-threshold interband cascade lasers operating above room temperature

Mid-IR type-II interband cascade lasers were demonstrated in pulsed mode at temperatures up to 325 K and in continuous mode up to 200 K. At 80 K, the threshold current density was 8.9 A/cm² and a continuous wave output power of 140 mW/facet was obtained.     

GI／G／1单重休假随机服务系统的马氏骨架方法

文献[1]引入一类具有广泛应用前景的随机过程-Markov骨架过程。借助Markov骨架过程的方法研究GI/G/1单重休假服务系统队长，及t时刻到达顾客等待时间的瞬时概率分布。     

Experimental 511 W Composite Nd：YAG Ceramic Laser

We demonstrate a 511 W laser diode pumped composite Nd：YAG ceramic laser. The optical pumping system is consisted of five laser diode stacked arrays arranged in a pentagonal shape around the ceramic rod whose size is φ6.35×144mm. When the pumping power is 1600 W, the cw laser output up to 511 W at 1064nm can be obtained with a linear piano-piano cavity, and the optical-to-optical efficiency is 31.9%. To our knowledge, this is the highest value of laser output by using a newly invented composite Nd：YAG ceramic rod as the gain medium.     

物理实验教学与中学生辩证逻辑思维能力的培养

阐述了如何在辩证逻辑基本规律——对立统一规律指导下，通过挖掘物理实验中蕴涵的辩证逻辑思维素材，在物理实验教学中有意识地培养学生的辩证逻辑思维能力。     

An approach based on simplified KLT and wavelet transform for enhancing speech degraded by non-stationary wideband noise

It is well known that the non-stationary wideband noise is the most difficult to be removed in speech enhancement. In this paper a novel speech enhancement algorithm based on the dyadic wavelet transform and the simplified Karhunen-Loeve transform (KLT) is proposed to suppress the non-stationary wideband noise. The noisy speech is decomposed into components by the wavelet space and KLT-based vector space, and the components are processed and reconstructed, respectively, by distinguishing between voiced speech and unvoiced speech. There are no requirements of noise whitening and SNR pre-calculating. In order to evaluate the performance of this algorithm in more detail, a three-dimensional spectral distortion measure is introduced. Experiments and comparison between different speech enhancement systems by means of the distortion measure show that the proposed method has no drawbacks existing in the previous methods and performs better shaping and suppressing of the non-stationary wideband noise for speech enhancement.     

An enantioselective Michael addition of malonate to nitroalkenes catalyzed by low loading demethylquinine salts in water

An enantioselective Michael addition of malonate to nitroalkenes is efficiently catalyzed by low loading demethylquinine salts in water; the yield range from 49% to 93% and the ee up to 90%.