同步辐射X射线光刻技术

同步辐射X射线光刻（SRXL）是本世纪超大规模集成电路（VLSI）发展中最有希望的深亚微米图形加工技术,本文综述了SRXL技术研究的现状及存在的问题,并对其今后的发展进行展望。     

氧化黑液木素-Mn2+(Cu2+、Zn2+)螯合物稳定性的研究

随着造纸工业的发展 ,造纸黑液的污染愈来愈受到人们的重视。目前 ,人们已采用多种方法来试图消除或降低黑液的污染。其中一重要方法是 :通过酸析法等从造纸黑液中分离出木素 (亦称木质素 ) [1] 。据估计 ,我国造纸厂每年可提取数百万吨的干木素。因此 ,有效地开拓造纸黑液木素的应用途径 ,不仅可以解决造纸厂的后顾之忧 ,更重要的是可为社会提供大量的物质财富 ,成为当今重要的研究课题。最近 ,我们通过氧化黑液木素与无机盐作用制得木素螯合微肥。试验结果表明 :与无机盐相比 ,木素螯合微肥表现出较强的肥效作用 ,这种作用可能与氧化木素…     

骑行波的非线性演化方程

从能量的角度出发,采用Ｈａｍｉｌｔｏｎ描述交结合变分原理和摄动分析,并借助于符号运算导出了骑行在大波上的小波的Ｈａｍｉｔｏｎ密度函数和非线性动力学方程。这里的大流和小波是对波高而言的。在Ｈａｍｉｌｔｏｎ描述中,正则变量取为波高和速度势。本文导出了描述小波演化的二阶方程,在一阶近下的方程与Ｈｅｎｙｅｙ等人（１９８８）的结果一致。     

关于Makowski-Schinzel问题

对于正整数ｎ,设σ（ｎ）,ψ（ｎ）分别是ｎ的约数和函数和Ｅｕｌｅｒ函数,本文证明了：如果ｐ是ｎ的素因数,则必有σ（ψ（ｎｐ））／ｎｐ〉σ（ψ（ｎ））／ｎ。     

实二次域Q(P(1/2))(p≡3(mod 4))类数的上界

设p是适合p≡3（Pod4）的奇素数,h,ε分别是实二次域Q的类数和基本单位．本文运用初等方法证明了：εh＜（p a 2)a 2/4(a 2)!,其中     

酰胺类喹唑啉酮衍生物的合成及抗菌活性

本文设计并合成了23个含酰胺结构单元的新型喹唑啉酮类化合物,经1 H NMR、13 C NMR和HRMS确证结构.在100μg·mL-1和50μg·mL-1浓度下,评价了它们对水稻白叶枯病菌、猕猴桃溃疡病菌和柑橘溃疡病菌的抑菌活性.结果表明,化合物对柑橘溃疡病菌有较强的抑制活性,并测定了6个化合物对柑橘溃疡病菌的EC5...     

Phase Diagram for Ashkin-Teller Model on Bethe Lattice

Using the recursion method, we study the phase transitions of the Ashkin-Teller model on the Bethe lattice, restricting ourselves to the case of ferromagnetic interactions. The isotropic Ashkin-Teller model and the anisotropic one are respectively investigated, and exact expressions for the free energy and the magnetization are obtained. It can be found that each of the three varieties of phase diagrams, for the anisotropic Ashkin-Teller model, consists of four phases, i.e., the fully disordered paramagnetic phase Para, the fully ordered ferromagnetic phase Ferro, and two partially ordered ferromagnetic phases 〈σ〉and 〈σs〉, while the phase diagram, for the isotropic Ashkin-Teller model, contains three phases, i.e., the fully disordered paramagnetic phase Para, the fully ordered ferromagnetic phase Baxter Phase, and the partially ordered ferromagnetic phase 〈σs〉.     

HZSM-5沸石孔口改性及其择形分离性能

采用Si(OCH~3)~4化学气相沉积方法精细调变HZSM-5孔径,焙烧后在沸石外表面上沉积一薄层氧化硅,使沸石孔口有控制地被缩小。制备了一系列氧化硅沉积量不同的SiHZSM-5沸石,并用红外光谱,NH~3-TPD和吸附方法对其进行表征,结果表明沸石骨架结构,内孔孔容和内表面性质基本不变。测定了SiHZSM-5沸石对于二甲苯和甲酚异构体的择形吸附性能,发现在沉积量适当的SiHZSM-5沸石上能够成功地实现对二甲苯和对甲酚的择形选择吸附分离,因为复合孔口缩小后将大的间位异构体排除在外,而沸石总吸附容量仍保持较高水平。     

Solid state NMR study of intercalate complexes of poly(ethylene oxide) and small molecules

From solid state NMR spectra, a lower shielding of poly(ethylene oxide) (PEO) protons, in contrast to higher shielding of PEO carbons, has been found for PEO/hydroxybenzene and PEO/LiCF₃SO₃ complexes in comparison with neat PEO. The same PEO chemical shifts were found both for crystalline and amorphous phase of PEO/LiCF₃SO₃ polymer electrolyte, confirming the same interaction in both phases. Measurements of 2D ¹H CRAMPS exchange NMR spectra have been used to characterize proton distances in complexes of PEO and benzene derivatives. A close contact (∼ 0.3 nm) between aromatic and PEO protons was detected in some cases. From the measurements of the cross polarization ¹H → ¹³C, using Lee-Goldburg irradiation of ¹H nuclei, the distance between LiCF₃SO₃ carbon and the nearest PEO protons in the PEO/LiCF₃SO₃ complex was determined.     

NMR and vibrational spectroscopic study of the order and mobility in polycarbonate and polycarbonate — poly(ethylene oxide) blends

Time dependence of the gel formation in toluene solutions of polycarbonate (PC) was investigated by two-dimensional Fourier-transform infrared (2D FT-IR) correlation spectroscopy. The 2D correlation approach reveals that there are at least three bands in the C=O stretching region. The intensity increase of the band at 1771 cm⁻¹ occurs later compared with the onset of the intensity changes of the bands at 1778 and 1765 cm⁻¹ corresponding to amorphous and crystalline-like domains, respectively. The band at 1771 cm⁻¹ is assigned to the chain conformations occurring in the partial-order regions accompanying crystalline-like domains. Splitting of the signals of aromatic carbons in the solid-state ¹³C CP/MAS NMR spectra of semicrystalline PC and PC-PEO blends indicates restricted mobility resulting from the fixed ordering due to partial crystallinity of PC itself and from blending of PC with PEO. The decreasing mobility of PC with the increasing content of highly mobile PEO in the blends was proved by the dipolar dephasing rates obtained in the ¹H-¹H CRAMPS (combined rotation and multi-pulse spectroscopy) NMR experiments.