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排序方式: 共有1134条查询结果,搜索用时 31 毫秒
31.
You Liang ZHAO Chuan Fu CHEN Fu XI* State Key Laboratory of Polymer Physics Chemistry Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2002,13(5):420-421
Much effort has been dedicated to the molecular design and synthesis of model proteins to define protein folding interactions and to develop protein-based materials. Among them, the ring-opening polymerization of -amino acid-N-carboxyanhy- drides (NCAs) has drawn much attention because the resulting artificial polypeptides have wide applications in biotechnology, biomineralization and diagnostics1, 2. It is well known that dendrimers are hyperbranched macromolecules possessing a very high co… 相似文献
32.
Nan Yan FU Mei Li PANG Yao Feng YUAN Ji Tao WANG* Department of Chemistry National Key Laboratory of Elemento-organic Chemistry Nankai University Tianjin 《中国化学快报》2002,13(10)
A highly efficient catalyst indium (III) tribromide is used to synthesize 5-alkoxy- carbonyl-4-hydrocarbyl-3,4-dihydropyrimidin-2(1H)-ones by a three-component coupling of β-keto ester, aldehydes and urea through improved Biginelli reaction. 相似文献
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Jue Xiao CAI Zheng Hong ZHOU Kang Ying LI Chi Hung YEUNG Chu Chi TANG* State Key Laboratory of Elemento-Organic Chemistry Institute of Elemento-Organic Chemistry Nankai University Tianjin Open Laboratory of Chirotechnology D 《中国化学快报》2002,13(7)
Optically active 1,1-binaphthalene-2, 2-diol has become a quite important chiral source in different fields of chirotechnology, especially in asymmetric synthesis1. Its synthesis and resolution has been extensively studied and various resolution methods have been reported2. Among the reported resolution methods, the following three, namely, via the formation of phosphoric acid derivatives3, boric acid derivatives4 and inclusion complexes5, are the most important. OHOH+_( )-1(-)-(S)-1(+)-(R)… 相似文献
35.
Yi Xin ZHAO Shu Guang WANG* School of Chemistry Chemical Technology Shanghai Jiaotong University Shanghai 《中国化学快报》2005,(11)
The increasing demand to produce enantio-pure pharmaceuticals, flavors, and other fine chemicals has advanced the field of asymmetry catalytic technologies. Among all asymmetry catalytic methods, catalytic enantioselective hydrogenation of unsaturated bonds such as olefins, ketones, and imines, which employs dihydrogen and small amounts of transition-metal complexes modified intrinsically by chiral ligands, is now recognized as being the most promising strategy for the synthesis of large amount… 相似文献
36.
Qing LI Hui LI Bin SU Xiang Bao MENG Meng Shen CAI Zhong Jun LI* Department of Chemical Biology School of Pharmaceutical Sciences National Research Laboratory of Natural Biomimetic Drugs Peking University Beijing 《中国化学快报》2002,13(4):303-305
Our previous paper1,2reported the results of selective synthesis of mannose type glycosides and their dimers in our attempt to synthesize derivatives of N-acetyllacto- samine, which could have potential activity of anti-metastasis3. Further studies on the glycosylation of the accepters exploiting glycosyl nitrate instead of the acetate as donor showed interesting chemoselectivity between the two kinds of donor, namely, the glucose type and the mannose type. The reactivity difference of the t… 相似文献
37.
在有关核磁共振技术的大学教材和专著中,给出了以下几种不同形式的化学位移(δ)定义式: δ=v_(样品)-v_(标准)/v_(标准)×10~6(1) δ=H_(样品)-H_(标准)/H_(标准)×10~6(2) δ=H_(标准)-H_(样品)/H_(样品)×10~6(3) δ=(1)式=(3)式(4) δ=(v_(样品)-v_(TMS))Hz/核磁共振仪所用频率MHz核磁共振仪所用频率MHz(5) 几种不同形式定义式的出现,对教学和自学造成了一定的困难.因为存在以下三个问题需要理解: 第一:以磁场强度(H)出发的定义式(2)和(3),为什么分子中相应各项的下标是相反的? 第二:以磁场强度(H)出发的定义式(3)和以频率(v)出发的定义式(1),分子中相应各项的下标也是相反的,为什么这两个式子是相等的(即(4)式)? 第三:若(4)式成立,为什么实际工作 相似文献
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邻硝基苯丙酮酸乙酯烯醇钾的合成和乙醇钾的制备新方法研究张本才,李宝林,李安祥(陕西师范大学化学系,西安710062)邻硝基苯丙酮酸乙酯烯醇钾用作合成邻硝基苯甲醛(一种难于合成的重要化工原料,主要用来生产硝苯吡啶等药物)的关键中间体早有报道 ̄[1,2]... 相似文献
40.
Yun Yan GAO Chang Jiang YOU Jin Ping CHEN Yong Yong LIU Bao Wen ZHANG Yi LI* Technical Institute of Physics Chemistry Chinese Academy of Sciences Beijing 《中国化学快报》2002,13(12)
The photochemistry of the vitamin D family and their precursors has been the subject of extensive studies for many years1-4. Most of the studies focus on the photoisomer- ization of 7-dehydrocholesterol and that of tachysterol to previtamin D3, which is of commercial importance in the synthesis of vitamin D34, 5. Recently the cis/trans isomerization of vitamin D analogs (Scheme 1) draws attention because of its importance in the synthesis of hydroxylated vitamin D metabolites6. However, o… 相似文献