全文获取类型
收费全文 | 6254篇 |
免费 | 1076篇 |
国内免费 | 784篇 |
专业分类
化学 | 4217篇 |
晶体学 | 55篇 |
力学 | 445篇 |
综合类 | 48篇 |
数学 | 775篇 |
物理学 | 2574篇 |
出版年
2024年 | 8篇 |
2023年 | 127篇 |
2022年 | 115篇 |
2021年 | 172篇 |
2020年 | 222篇 |
2019年 | 239篇 |
2018年 | 179篇 |
2017年 | 193篇 |
2016年 | 279篇 |
2015年 | 309篇 |
2014年 | 307篇 |
2013年 | 370篇 |
2012年 | 547篇 |
2011年 | 609篇 |
2010年 | 413篇 |
2009年 | 330篇 |
2008年 | 447篇 |
2007年 | 398篇 |
2006年 | 366篇 |
2005年 | 352篇 |
2004年 | 292篇 |
2003年 | 206篇 |
2002年 | 180篇 |
2001年 | 150篇 |
2000年 | 113篇 |
1999年 | 150篇 |
1998年 | 107篇 |
1997年 | 118篇 |
1996年 | 127篇 |
1995年 | 116篇 |
1994年 | 82篇 |
1993年 | 67篇 |
1992年 | 58篇 |
1991年 | 65篇 |
1990年 | 67篇 |
1989年 | 53篇 |
1988年 | 42篇 |
1987年 | 27篇 |
1986年 | 34篇 |
1985年 | 27篇 |
1984年 | 14篇 |
1983年 | 9篇 |
1982年 | 11篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1979年 | 1篇 |
1976年 | 2篇 |
1974年 | 1篇 |
1957年 | 3篇 |
排序方式: 共有8114条查询结果,搜索用时 203 毫秒
1.
Tian Xiu-Zhi Yang Rui Ma Jia-Jia Ni Yong-Hao Deng Hai-Bo Dai Lei Tan Jiao-Jun Zhang Mei-Yun Jiang Xue 《高分子科学》2022,40(7):789-798
Chinese Journal of Polymer Science - Antistatic and strength properties are of vital importance for polyurethane rubber used in moving parts of many industrial instruments. Herein, polyurethane was... 相似文献
2.
Hu Duo-Duo Gao Qian Dai Jing-Cheng Cui Ru Li Yuan-Bo Li Yuan-Ming Zhou Xiao-Guo Bian Kang-Jie Wu Bing-Bing Zhang Kai-Fan Wang Xi-Sheng Li Yan 《中国科学:化学(英文版)》2022,65(4):753-761
Science China Chemistry - A light-induced, nickel-catalyzed three-component arylsulfonation of 1,3-enynes in the absence of photocatalyst is reported. This methodology exhibited mild conditions,... 相似文献
3.
采用水热法制备花状Bi2 WO6,并利用超声分散法制备了Cu2 O/TiO2-Bi2 WO6复合光催化剂,通过FESEM、XRD、XPS、FI-IR、UV-vis DRS和PL对光催化剂进行了分析和表征.表征结果证明:花状Bi2 WO6表面负载着碎片状的TiO2和立方体Cu2 O形成Cu2 O/TiO2-Bi2 WO6复合光催化剂;以短链脂肪酸(SCFAs)为牺牲剂,考察复合光催化剂的光催化产生氢气和烷烃的性能.实验结果表明:Cu2 O/TiO2-Bi2 WO6复合光催化剂以乙酸为牺牲剂,主要产氢气和甲烷,降解率高达91.82;;以丙酸为牺牲剂,产物主要是乙烷和丁烷,降解率高达90.70;;以丁酸为牺牲剂,除了氢气,甲烷,乙烷,丙烷,丁烷外,气体产物还含有一定量的戊烷,其降解率高达91.50;.结合反应液中间产物的成分进行检测,由此推断出光催化反应的可能机理. 相似文献
4.
In recent years, spatial self-phase modulation (SSPM) with two-dimensional (2D) materials has attracted the attention of many researchers as an emerging and ubiquitous nonlinear optical effect. In this review, the state of the art of 2D material-based SSPM is summarized. SSPM measures or tunes the nonlinearity of 2D materials, and it is also an effective approach to study the band structure of 2D materials. Several modified forms of SSPM, such as high-order, white-light-excited, vector field excited, and optically nonlinearly enhanced SSPM are also presented. Subsequently, the physical origin of the SSPM formation mechanism is compared and analyzed. Furthermore, the applications of SSPM with 2D materials, including passive photonic devices, generation of Bessel beams, and identifying the mode of the orbital angular momentum, are listed. Finally, several urgent problems of the SSPM with 2D materials, potential applications, and prospects for future development are presented. 相似文献
5.
6.
Cuixia Cui Yong Gao Dr. Jun Li Chao Yang Meng Liu Prof. Dr. Huile Jin Prof. Dr. Zhenhai Xia Prof. Dr. Liming Dai Prof. Dr. Yong Lei Prof. Dr. Jichang Wang Prof. Dr. Shun Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(20):8002-8007
Although tremendous efforts have been devoted to understanding the origin of boosted charge storage on heteroatom-doped carbons, none of the present studies has shown a whole landscape. Herein, by both experimental evidence and theoretical simulation, it is demonstrated that heteroatom doping not only results in a broadened operating voltage, but also successfully promotes the specific capacitance in aqueous supercapacitors. In particular, the electrolyte cations adsorbed on heteroatom-doped carbon can effectively inhibit hydrogen evolution reaction, a key step of water decomposition during the charging process, which broadens the voltage window of aqueous electrolytes even beyond the thermodynamic limit of water (1.23 V). Furthermore, the reduced adsorption energy of heteroatom-doped carbon consequently leads to more stored cations on the heteroatom-doped carbon surface, thus yielding a boosted charge storage performance. 相似文献
7.
8.
9.
Summary. Let be a square matrix dependent on parameters and , of which we choose as the eigenvalue parameter. Many computational problems are equivalent to finding a point such that has a multiple eigenvalue at . An incomplete decomposition of a matrix dependent on several parameters is proposed. Based on the developed theory two new algorithms are
presented for computing multiple eigenvalues of with geometric multiplicity . A third algorithm is designed for the computation of multiple eigenvalues with geometric multiplicity but which also appears to have local quadratic convergence to semi-simple eigenvalues. Convergence analyses of these methods
are given. Several numerical examples are presented which illustrate the behaviour and applications of our methods.
Received December 19, 1994 / Revised version received January 18, 1996 相似文献
10.