衬底对Cu(In,Ga)Se2薄膜织构的影响

分别在苏打石灰玻璃、Mo箔、无择优取向的Mo薄膜以及(110)择优取向的Mo薄膜四种不同衬底上，采用共蒸发工艺沉积约2 μm厚的Cu(In,Ga)Se₂薄膜，用X射线衍射仪测量薄膜的织构，研究衬底对Cu(In,Ga)Se₂薄膜织构的影响.在以上四种衬底上沉积的Cu(In,Ga)Se₂薄膜的(112)衍射峰强度依次逐渐减弱，(220/204)衍射峰从无到有且强度逐渐增强.在苏打石灰玻璃和Mo箔衬底上的Cu(In,Ga)Se_{2关键词： 择优取向 Cu(In 2}薄膜')" href="#">Ga)Se₂薄膜 太阳电池     

光纤模式混合器在差分吸收光谱系统中的应用研究

差分吸收光谱技术(DOAS)已经发展为监测对流层痕量气体的重要技术，一般采用光电倍增管(PMT)作为探测器.由于光电二极管阵列(PDA)在多道探测及像元灵敏性方面的优势，采用PDA代替扫描探测装置将能改善系统剩余噪声，提高系统性能.但实际应用中由于使用收发一体Cassegrain望远镜造成灯谱与大气谱结构不统一，在消除PDA像元间差异的过程中给系统带来误差，从而导致剩余噪声的标准偏差达到1.4×10^-3.根据光纤扰模原理在系统中加入自制光纤模式混合器很好的解决了上述难题，在实际应用中起到良好的作用，系统剩余噪声的标准偏差为3.4×10^-4. 关键词： 差分吸收光谱 扰模 模式混合器 剩余噪声     

Effective generation of red-green-blue laser in a two-dimensional decagonal photonic superlattice

We demonstrate the effective generation of red, green and blue (RGB) light in a two-dimensional decagonal quasiperiodic LiNbO₃ nonlinear crystal. Owing to the unique abundance in reciprocal vectors (RVs), the RGB signals were generated directly by frequency doublings. Thus the conversion efficiencies of the RGB light were much higher than previously recorded. In addition, the same results were obtained when the crystal was rotated by integral multiples of π/5. This result will aid in the effective generation of RGB in multiple directions and may have important applications in laser-based projection displays. PACS 42.65.Ky; 42.72.Bj; 42.79.Nv     

La2O3对Yb:Y2O3透明陶瓷光谱性能的影响

研究了La2O3对Yb:Y2O3透明陶瓷光谱性能的影响,添加适量La2O3以后,Yb:Y2O3透明陶瓷的吸收峰和发射峰的位置不变,但由于La3+的离子半径大于Y3+的离子半径,在Y2O3中引入La3+离子后,导致Y2O3晶格常数变大,晶场强度变弱,同时降低了Y2O3晶体的有序度,致使发射峰强度有所下降,发射截面变小.过量的La2O3(x=0.16)造成Yb3+激活离子发射强度明显下降;其荧光寿命在添加La2O3后总体增大45%-60%.     

Effect of calcium malonate on the formation of β crystalline form in isotactic poly(propylene)

Calcium malonate (Camt) is used to induce the β crystalline form in isotactic polypropylene (iPP) for the first time. The relative content of the β crystalline form (K value) increases markedly with the addition of Camt and attains the maximum value of 73.48% at 0.40% Camt. The amounts of bright and colorful β spherulites increase and the spherulitic sizes decrease with the increase in Camt contents. The tensile strength and the Izod notched impact strength of the nucleated iPP samples increase with the addition of Camt; in particular, the latter almost doubles at 0.40% Camt compared to that of the blank iPP sample. The β nucleation mechanism of Camt is analyzed by the dimensional lattice match criterion. Copyright © 2008 John Wiley & Sons, Ltd.     

Effect of β-Nucleating Agent on the Crystallization,Mechanical Properties,and Heat Resistance of Injection-Molded Isotactic Polypropylene

Injection-molded β-isotactic polypropylene (β-iPP) was prepared with a commercial β-nucleating agent (NT-A). The effect of NT-A on the crystallization, mechanical properties, and heat resistance of β-iPP was investigated by differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), polarized light microscopy (PLM), and mechanical and heat deflection tests. DSC and WAXD analysis showed that the content of β-crystals in the nucleated iPP was higher than that of pure iPP, and the content of β-crystals of the core was higher than that of the skin. PLM observations showed that injection-molded iPP had an obvious skin-core structure. NT-A induced abundant β-crystals and resulted in small spherulites which improved the Izod notched impact strength. When the content of NT-A was 0.075wt%, the Izod notched impact strength reached a maximum, 2.6 times more than that of pure iPP. The heat distortion temperature was also improved by NT-A.