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81.
The relationship between the selectivity of six drug ion-selective electrodes with anionic species of hetero-poly acid as exchange site and the structural and thermodynamical parameters of the metal ion has been investigated experimentally and theoretically. The electrode selectivity is controlled mainly by the extractibility or hydrophobicity of the metal ion, but not by the ion-association-complex formation process. Linear relationship exists between the pK_(ij) value and the structural parameter z~2/(r + 0.85) and the thermodynamic parameter of hydration (△G_h) of the metal ion. Better correlation is obtained for the pK_(ij)vs. (z~2/r)~(-k) relationship. 相似文献
82.
氟锆酸盐玻璃光纤的研制 总被引:1,自引:0,他引:1
本文介绍聚全氟乙丙烯包皮的氟锆酸盐(ZrF_4-BaF_2-LaF_3-AlF_3-NaF)玻璃光纤的制备方法.研究了各种工艺因素对氟锆酸盐玻璃和光纤散射损耗的影响.结果表明,选择适当的熔化温度和均化时间,玻璃熔化和光纤拉制时环境中低的水含量是制得的损耗氟锆酸盐玻璃光纤的关键;配合料中引入适量NH_4HF_2,选用温度结构合理的拉丝炉及拉丝工艺也有助于降低光纤的损耗.在此工作基础上,获得了波长2.32μm处损耗为0.24dB/m的氟锆酸盐玻璃光纤. 相似文献
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本文由半经典理论推得了原子电离率随脉冲空间传输出现周期性起伏这一新的相干作用结果,这点与速率方程的预计相差甚远.文中定量说明了利用速率方程对同位素分离过程进行分析时产生的系统误差,为实验分析工作提供了依据. 相似文献
85.
本文从理论上通过对钕玻璃中Nd~(3+)离子光吸收特性的分析,阐明了其光吸收对温度依从性的原因.在实验中,试制了几种不同类型的钕玻璃光纤温度传感探头.对Nd~(3+)离子光吸收的温度特性进行了验证,其结果和理论分析相一致,实验表明钕玻璃是一种性能良好的光纤温敏传感材料. 相似文献
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The dynamic properties of the assistant sounders in the black cicada are given and the twitching properties of Contraction in the sounding muscle are revealed in this paper.For the operculum, tymbal cover and joint membrane, each of their vibration periods consists of three subgroup vibrations (SGV_(a,b,c)) corresponding to amplitude-modulation pulse trains (AMPT_(1,2,3)) in every syllable of synchro song. In comparison with the vibration at dorsum, the SGV_(a-c) have a subband with the function of regulating the tone. During calling song continuously, the pressure change inside the resonant cavity and the airspeed through the spiracles on both sides are about 7. 94—15.88 Paand 0.59—0.84 cm~3/s respectively, and they increase by about 7 and 2.6 times as the abdomen is moved. When the contraction motion of the sounding muscle comes up to the critical Sounding state, it further produces the twitching process, and drives the sounding membrane and the toning plate-membrane to produce AMPT_(1-3) and SGV_(a 相似文献
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高重复率XeCl准分子激光器的放电特性 总被引:1,自引:0,他引:1
本文报道紫外预电离放电泵浦的高重复率XeCl准分子激光器的放电特性,分析了放电参数的改变对放电过程的影响.最佳转换效率达2.2%. 相似文献
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