求解对流扩散方程的低耗散中心迎风格式

以四阶CWENO重构为基础,通过将对流项采用低耗散中心迎风格式离散,扩散项采用四阶中心差分格式离散,对得到的半离散格式采用四阶龙格库塔方法在时间方向上推进,得到一种求解对流扩散方程的高阶有限差分格式.数值结果验证了该格式的四阶精度和基本无振荡特性.     

一种基于新型斜率限制器的理想磁流体方程的高分辨率熵相容格式

针对磁流体动力学方程, 通过分析数据重建所需的条件, 构造一种基于MUSCL(Monotone Upstream-Centred Scheme for Conservation Laws)型重建方法的斜率限制器, 获得了一种求解理想磁流体动力学方程的高分辨率熵相容格式。该格式在解的光滑区域具有高精度; 在解的间断区域可以合理地控制耗散, 可有效避免非物理现象的产生。采用熵稳定格式、熵相容格式和新的高分辨率熵相容格式对一维、二维理想磁流体动力学方程进行数值模拟。结果表明: 新格式能准确地捕捉解的结构, 且具有无振荡、高分辨、鲁棒等特性。     

丙烯聚合负载型Ziegler-Natta催化剂的ESR研究

用ESR方法对MgCl₂负载的钛系Ziegier-Natta催化剂进行了研究,获得了分辩率较好的谱图,并结合前人的工作将信号的归属同钛原子在MgCl₂上的负载情况对应起来.同时考察了内外给电子化合物对ESR谱图的影响,探讨了它们可能的作用机理.     

On the Correlation between the Blue Shift of Hydrogen Bonding and the Proton Donor-Proton Acceptor Distance

It is demonstrated that in all types of hydrogen bonds (X—H…Y) there is a balance between the long-range attractive orbital interactions and short-range Pauli/nucleus repulsions. When the proton acceptor approaches the proton donor from distance, the hydrogen bonding energy becomes more negative at relatively large distance, goes through a minimum, and then starts to become less negative when the short-range repulsive forces come into effect.Meanwhile, the X--H bond length increases at relatively large distances, goes through a maximum and starts to shorten when the short-range repulsive forces come into effect. Whether the hydrogen bond is red or blue shifted is dictated by the energy minimum position. If at the energy minimum position the X—H bond length is shorter than that for the free monomer, the hydrogen bond is blue shifted and vice versa. Further studies demonstrate that the recent report about the correlation of C—H bond lengths with proton donor-acceptor distance in F3C—H…OH2 and F3C—H…Cl^- is not fully correct because the authors conducted an inappropriate comparison. Furthermore, it is shown for the first time that the Pauli/nucleus repulsion theory is applicable to the blue-shifted hydrogen bonds in the X—H…π complexes and the blue-shifted lithium bonds in the X—Li…Y complexes.     

MATHEMATICAL MODEL OF A JUNCTION BETWEEN LINEAR ELASTOMER AND THIN PLATE

（聂玉峰）（聂铁军）（封建湖）ＭＡＴＨＥＭＡＴＩＣＡＬＭＯＤＥＬＯＦＡＪＵＮＣＴＩＯＮＢＥＴＷＥＥＮＬＩＮＥＡＲＥＬＡＳＴＯＭＥＲＡＮＤＴＨＩＮＰＬＡＴＥ￥ＮｉｅＹｕｆｅｎｇ；ＮｉｅＴｉｅｊｉｕｎ；ＦｅｎｇＪｉａｎｈｕ（ＤｅｐａｒｔｍｅｎｔｏｆＡｐｐ...     

光弹塑性等倾线角度的判读一法

本文提出并证明了一套测定光弹塑性模型中任一点的等倾线角度的方法     

Specific Heat Properties of Proton Transfer in Hydrogen Bonded Systems

The thermodynamic properties of proton transport along hydrogen-bonded systems at finite temperatures have been studied by our model. We first derive the dynamic equations of the proton transport and find the solutions and the free energy of the systems. Finally, we obtain the specific heats of the hydrogen bonded systems, resulting from the motion of the soliton, by using transfer integral way. The theoretical value is basically consistent with the experimental data.     

新型无机离子交换剂的研究：Ⅴ.偏磷酸铈的离子交换色谱法应用

新型无机离子交换剂的研究Ⅴ．偏磷酸铈的离子交换色谱法应用苏政权（广东药学院预防医学系卫生化学教研室广州５１０２２４）封惠侠（河南信阳教育学院化学系河南４６４０００）张秀莲（广东教育学院化学系广州５１０３０３关键词离子色谱偏磷酸铈分离中图分类号Ｏ６５７...     

Fabrication and Characterization of ZnO-Based Film Bulk Acoustic Resonator with a High Working Frequency

We report on the fabrication and characterization of a ZnO-based film-bulk acoustic-resonance device utilized as biosensor. The device has a multilayer structure which consists of piezoelectric element (Au/ZnO/Pt) and a Bragg-reflection-layer acoustic isolation consisting of multilayers of ZnO/Pt. Dielectric measurements have revealed that the device has a very high working frequency (up to -3.1 GHz), meaning that the device may have a higher sensitivity than the devices reported in the literature.     

以2，2，6，6－四甲基哌啶酮氮氧自由基为自旋探针研究烯烃聚合物的链段运动

用混合型Ｚｉｅｇｌｅｒ－Ｎａｔｔａ催化剂，合成了多种用作原油减阻剂的烯烃聚合物，研究发现Ａｌ（ｉＢｕ）＿３／ＡｌＥｔ＿２Ｃｌ的摩尔比在２－３／７－８，反应时间约为１ｈ左右，能得分子量较大的聚合物，用２，２，６；６－四甲基哌啶酮氮氧自由基为自旋探针，研究了烯烃聚合物的链段运动，发现减阻效率和链段的柔顺性有密切关系。