对“原子钟、原子弹哪个更重要”一文的一点看法

 这里全文刊登侯明东先生对于本刊2003年第3期“原子钟、原子弹哪个更重要”一文的看法。虽然本刊发表的每一篇文章都只代表作者本人的看法,但是,对于一些重大的科技进步和发明创造,本刊应该注意把关。以上文为例,原子弹的研发,对于加强我国国防、提高国际地位,做出了重大贡献,与原子钟“两者无法比较”。在此,我们衷心感谢侯先生对本刊的关爱,并为我们工作上的疏忽向读者致歉!衷心欢迎读者对本刊提出批评、建议。     

4He+辐照非晶态合金引起的表面形貌变化

室温~4He~+辐照Fet_(11)B_(?)Si_3,Cr_2和Ni_(?)B_(?)Si_5非晶态合金,利用扫描电子显微镜(SEM)观测表面形貌随辐照参数的变化,同时给出表面形变,即发泡或层离的临界剂量范围,以及发泡直径分布算实验结果. 关键词：     

THE MULTIPLE IONIZATION OF ARGON INDUCED BY PARTIALLY STRIPPED CARBON IONS

The cross section ratios of the double, triple and quadruplicate ionization to the single ionization of argon by 1.5-7.5 MeV partially stripped carbon ions are measured by using time-of-flight technique. The Auger transition and the charge exchange process in the multiple ionization of argon are studied. The ratios of cross sections of the direct multiple ionization to those of the direct single ionization are obtained by subtracting the parts of the Auger transition and the charge exchange process from the measured data. It is found that the cross section ratios of the direct multiple ionization to those of the direct single ionization are in good agreement with the predicted mniti-step (ν/q_eff)^-2n+2 law.     

桥梁桩基防护用玄武岩复合纤维套筒的抗冲磨试验研究

介绍了用于解决桥梁水下桩基腐蚀及冲刷问题的玄武岩复合纤维套筒防护技术。为检验玄武岩复合纤维护筒的抗冲磨效果,重点开展了基于水下钢球法的玄武岩复合纤维板材的抗冲磨试验研究。试验结果表明,冲磨试验前后以及不同冲磨周期下试件板材的颜色均存在明显差异;与裸露混凝土试件相比,采用玄武岩复合纤维板防护试件的平均抗冲磨强度增加,同时平均磨损系数显著降低;随着冲磨周期的增加,材料抗冲磨强度逐渐增大,而磨损系数趋于稳定。本文试验验证了玄武岩复合纤维套筒具有较好的抗冲磨能力和长期抗冲磨稳定性,可用于桥梁水下桩基的工程防护。     

22 MeV/u的Fe离子在PET 膜中引起的辐照效应研究

用能量为22 MeV/u的 Fe离子在室温和真空条件下辐照了多层堆叠的半晶质聚酯膜, 采用傅里叶转换红外吸收光谱、 紫外/可见吸收光谱 和X射线衍射技术分析测量了辐照后聚酯膜的微观结构所发生的变化, 详细研究了分子结构的变化和非晶化转变与离子剂量、 离子在样品中的平均电子能损以及吸收剂量的依赖关系． 分析结果表明: 辐照导致化学键的断裂、 新化学键的形成和非晶化转变． 非晶化效应和化学键的断裂随离子剂量和电子能损的增加而增大, 但变化的总量仅依赖于总的吸收剂量, 表明在所涉及的能损范围里, 辐照产生的变化与辐照离子的种类和能量没有直接的关系, 而只决定于材料对辐照离子能量的吸收程度． Semicrystalline polyethylene terephthalate (PET) film stacks were irradiated with 22 MeV/u Fe ions at room temperature under vacuum. Ion beam induced microscopic structural modifications and amorphous transformation were investigated by means of Fourier transform infrared spectrosocopy (FTIR), ultraviolet visible absorption spectrosocopy (UV/Vis) and X ray diffractometer (XRD). It was found that irradiation induces bond breaking, formation of new free radiculs and amorphous transformation. These effects were found to depend on ion fluence , the electronic energy loss and aborbed dose. The creation of alkyne groups was found only at the aborbed dose higher than 5.0 MGy.     

高剂量Ar离子辐照Si缺陷产生及其退火行为EPR研究

112MeVAr离子在50K以下的低温辐照Si到8×10¹⁴/cm²剂量,室温下采用电子顺磁共振技术分析了由辐照引起的缺陷产生及其退火行为,结果表明:Ar离子辐照在Si中引起了中性四空位(Si-P3心)､带正电荷的〈100〉劈裂的双间隙子(Si-P6心)以及连续的非晶层3种缺陷的形成. 在200℃的退火温度,Si-P3心和Si-P6心消失,这时带负电荷的五空位(Si-P1心)开始生长,Si-P1心可以保持到550℃左右的退火温度. 在350℃时,可以明显地观测到另一个含有更多空位的顺磁缺陷心(Si-A11心).连续非晶层的再结晶需要600℃以上的温度,并且在整个退火过程中,非晶顺磁共振线的线型和线宽保持不变. 定性地讨论了结果.     

离子径迹模板法制备纳米线

重离子辐照的高分子有机膜,经过适当的处理,可以作为模板制备金属和可溶性盐纳米线,此方法称为离子径迹模板法。介绍了用电化学沉积方法和过饱和溶液法制备金属纳米线和可溶性盐纳米线的基本原理和制各实例,同时还展望了离子径迹模板法制备纳米线的一些可能的应用。The polymer foils irradiated by heavy ions can be used as temptates to prepai nanowires and some inorganic salt nanowires. It is called ＂ion-track template method＂. Compared to other templates, such as AAO template and porous silicon, etched ion-track template is more convenient and flexible. The density of the pores can be easily controlled by changing the ion fluences and the diameter of the pores can be altered through changing the etching condition. The pores of the etched ion-track template are well aligned. We present some examples of preparing metallic nanowires and inorganic salt wires by electrochemical deposition and by supersaturation solution method, respectively. We also introduce some applications of nanowires prepared with ion-track template method.     

Fluorinated <Emphasis Type="Italic">p</Emphasis>-<Emphasis Type="Italic">n</Emphasis> type copolyfluorene as polymer electret for stable nonvolatile organic transistor memory device

In this study, a kind of fluorinated copolyfluorene, named poly[(4-(octyloxy)-9,9-diphenylfluorene-2,7-diyl)-alt-(2,3,5,6-tetrafluoro-1,4-phenylene)] (PODPF-TFP), is synthesized by facile palladium-based direct aromatization. Compared to the non-fluorinated counterpart, poly[(4-(octyloxy)-9,9-diphenylfluorene-2,7-diyl)-alt-(p-phenylene)] (PODPF-P), deeper HOMO/LUMO energy level combined with steric hindrance effect endow PODPF-TFP with excellent spectra and morphology stability. Finally, organic field-effect transistor (OFET) memory devices are fabricated with PODPF-P/PODPFTFP as the dielectric layers, and they both exhibit flash type storage characteristic. Owing to the electronegativity of fluorine atom, the device based on PODPF-TFP exhibits larger memory window and more stable I _on/I _off ratio during a retention time of 10⁴ s as well as a better aging stability. The present study suggests that fluorinated p-n copolyfluorene electrets could enhance the capabilities of charge trapping and storage, which are promising for OFET memory devices.