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991.
研究了5种α,α‘-二氧代烯酮环二硫代缩酮类化合物的碳基、碳碳双键、碳硫等一些特征红外光谱,尤其着重研究了共轭体系下的各种特征谱带随化学结构而变化的规律。 相似文献
992.
The wave equation of light beam propagation was written in the form of an axial-coordinate-dependent Schrdinger equation, and the expectation value of a dynamical variable, the trial function of variational approach and the ABCD law were discussed by use of quantum mechanics approach. In view of the evolution equations of expectation values of dynamical variables in the framework of quantum mechanics, the definition of a potential function representing the beam propagation stability and its universal formula with the quality factor, the universal formula of beam width and curvature radius for a paraxial beam and cylindrically symmetric non-paraxial beam, the general formula of second derivative of beam width with respect to the axial coordinate of beam for a paraxial beam, and the general criteria of the conservation of beam quality factor and the existence of a potential well of a potential function for a paraxial beam, were given or derived, respectively. Starting with the same trial function, the comparative research of our formulation with variational approach was done, which gave some further insight into the physical nature of a beam propagation parameters. The ABCD law of non-paraxial beam was discussed in terms of the definition of the non-paraxial expectation value of a dynamical variable for the first time. The applications to the media of constant second derivative of beam width with respect to the axial coordinate of a beam, square law media and the media of constant refractive index in the momentum representation were discussed, respectively. 相似文献
993.
Analytical chemistry often involves a large amount of experimental data, and the reliability and accuracy of the experimental results are related to whether the original data can be properly recorded and calculated. In this paper, starting from the importance of significant figures, analyzing the frequently encountered problems related to the significant figures in teaching process, and giving some solutions, we try to help students to learn and master the concept of significant figures, rounding off numerical values, rule of operation and data processing. 相似文献
994.
HU Fang ZHANG Chun-hua ZHANG Song MING Xing CHEN Gang WEI Ying-jin WANG Chun-zhong . School of Materials Science Engineering Shenyang University of Technology Shenyang P. R. China . College of Physics State Key Laboratory of Superhard Materials Jilin University Changchun . College of Physical Science Technology Huanggang Normal University Huanggang 《高等学校化学研究》2011,(3):528-530
1 Introduction Low-dimensional nanostructures, such as nanorods, nanowires, and nanotubes, have received much attention for their superior optical, electrical, catalytic and magnetic properties. 相似文献
995.
水溶性Rh-BISBIS配合物对阿维菌素催化加氢的研究 总被引:1,自引:0,他引:1
The hydrogenation of avermectin catalyzed by [RhCl(COD)]_2-BISBIS[COD:1,5-cyclooctadiene,BISBIS:sulfonated 1,1'-bis(diphenylphosphino Methyl-2,2'-biphenyl)] in situ in aquenous/organic two-phase system was studied.The influence of various parameters,such as the surfactant concentration,the molar ratio of rhodium to phosphine,the reaction temperature and pressure on this hydrogenation were investigated.The results showed that the hydrogenation activities of diphosphine was higher that of monophosphine. 相似文献
996.
利用非离子表面活性剂Triton X-114在温度高于其浊点时形成相分离行为,建立了浊点萃取富集痕量Ni(Ⅱ)的新方法.在pH9.5的Na2B4O7-NaOH缓冲溶液中,Ni(Ⅱ)与1-(4-硝基苯基)-3-(5,6-二甲基-1,2,4三氮唑)-三氮烯(NPDMTT)反应生成稳定的络合物,在475 nm处出现正吸收峰,... 相似文献
997.
Microsolvation of glycine in methanol clusters is explored by the use of DFT calculation method. The lowest energy conformations within 16.72 kJ·mol-1 of the glycine clustering with one to six methanol molecules, which are obtained at the B3LYP/6-31+G(d) level of theory, are reoptimized at PBE1PBE/6-311+G(d,p). The calculated results agree with our previous results with B3LYP (Chin. J. Chem. Phys. 22 (2009) 577) that the clusters of two forms (Z-and N-form) tend to be isoenergetic when the number of the solvate molecules reaches six. Furthermore, this result is in good agreement with the experiment of the tryptophan-methanol clusters, implying that the present treatments are reasonable and reliable. The results also indicate that nine methanol molecules are not enough to fully solvate a glycine molecule, and a tentative estimation is obtained that ten methanol molecules may fully solvate a glycine molecule, which consists with the experiment results. 相似文献
998.
999.
研究了温度、酶浓度、反应时间、几种有机溶剂等因素对PstⅠ星号活力的影响,并在有利于星号活力的反应条件下测定了星号活力及原活力的Km 分别为1.46×10- 7 m ol/L和1.02×10- 8 m ol/L,Vm ax 分别为2.86×10- 16 m ol/s和3.06×10- 15 m ol/s. 相似文献
1000.
本文以反射式高能电子衍射(RHEED)和其强度振荡为监测手段,在半绝缘GaAs衬底上成功地生长GaSb/AlSb/GaAs应变层结构,RHEED图样表明,GaSb正常生长时为Sb稳定的C(2×6)结构,AlSb为稳定的(1×3)结构,作者观察并记录GaSb,AlSb生长时的RHEED强度振荡,并利用它成功地生长10个周期的GaSb/AlSb超晶格,透射电子显微镜照片显示界面平整、清晰,采用较厚的AlSb过渡层及适当的生长条件,可在半绝缘GaAs衬底上生长出质量好的GaSb外延层,其X射线双晶衍射半峰宽小于
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