基于广义局部频率的Duffing系统频域特征分析

针对传统功率谱在频率概念上的局限性及傅氏变换的固有缺陷, 提出一种新的广义局部频率概念,在自适应峰值分解方法的基础上, 研究周期激励下Duffing系统随阻尼参数r变化的频域动力学特征,发现了频率分岔现象, 并且不同参数r下的混沌时间序列在中心频率附近出现连续频段, 其形状具有相似性.通过厄米解调分析,总结出混沌时间序列具有频率调制特性和频率调制的相似性. 上述研究表明:提出的基于自适应峰值分解的广义局部频率方法, 能够有效提取Duffing系统的频域特征,为观察非线性系统混沌状态下频率连续分布规律提供一种新方法.     

TDNAZ·HNO3和DNAZ·HCl的结构及性能

钝感高能炸药1,3,3-三硝基氮杂环丁烷(TNAZ)可由3,3-二硝基氮杂环丁烷(DNAZ)进行合成. 在合成DNAZ的过程中, 得到了中间产物N-叔丁基-3,3-二硝基氮杂环丁烷硝酸盐(TDNAZ·HNO3)和3,3-二硝基氮杂环丁烷盐酸盐(DNAZ·HCl). 培养了二者的单晶, 并通过X射线单晶结构分析法测定了它们的晶体结构. TDNAZ·HNO3属于正交晶系, Pnma空间群, 晶胞参数a=1.2697(3) nm, b=0.8179(2) nm, c=1.1621(3) nm, V=1.2067 nm3, Z=4. DNAZ·HCl属于正交晶系, Cmc21空间群, 晶胞参数a=0.6681(2) nm, b=1.0441(2) nm, c=0.9971(2) nm, V=0.6955 nm3, Z=4. 用密度泛函理论方法对该二种化合物进行了几何优化和频率计算, 获得分子结构、原子上Hirshfeld电荷、原子间Mayer键级和前沿轨道能量及组成. 基于分子和电子结构信息从理论上解释了相关反应机理, 并对两种化合物的热稳定性进行了比较.     

3,6-二肼基-1,2,4,5-四嗪的热行为、比热容及绝热至爆时间

利用差示扫描量热法(DSC)、热重-微商热重法(TG-DTG)研究了3,6-二肼基-1,2,4,5-四嗪(DHT)的热行为, 其分解过程可分为两个放热的分解过程, 且热分解反应的表观活化能分别为154.8和123.4 kJ·mol-1, 指前因子分别为1016.63和109.48 s-1. DHT热爆炸的临近温度为426.10 K. 同时, 利用微量热法和理论计算方法研究了DHT的比热容, 298.15 K时的标准摩尔比热容为183.61 J·mol-1·K-1. 计算获得了DHT的绝热至爆时间为263.84-297.58 s之间的某一值.     

超构天线:原理、器件与应用

自从电磁波被发现和应用以来,利用各种材料或者结构调节电磁波的辐射行为、构造高性能的电磁辐射器件一直是研究人员的追求目标.经过百余年的发展,电磁辐射器件的方向性提高、带宽拓展等技术逐渐达到瓶颈.受自然材料电磁特性的限制,微带天线、喇叭天线等传统电磁辐射器件存在体积重量大、工作带宽窄、无法快速动态调控等缺陷,难以满足日益发展的通信技术的需求.近年来出现的亚波长结构可在深度亚波长尺度下调控电磁波的传输行为,出现了多种奇异的电磁现象,完善了传统的电磁学理论,在一定程度上突破了传统材料电磁特性的限制,形成全新的电磁辐射技术,有效解决了传统天线存在的口径大、厚度高、带宽窄等难题,促进了电磁学、光子学、材料学等领域的发展.这种基于超构材料的新型天线可以被称为超构天线,具有高方向性、低副瓣、超宽带、可重构等传统天线难以实现的功能.本文主要回顾了近年来基于亚波长超构材料的超构天线技术的发展现状和取得的成果,介绍了超构材料在亚波长尺度下对电磁波振幅、相位、偏振态等的衍射调控机理,以及在此基础上形成的新型辐射器件,例如相控阵天线、高方向性天线、低雷达散射截面天线,基于亚波长结构的多种偏振调控器件及其在天线中的应用等.在衍射极限尺度下,这种亚波长结构的调控行为可有效提升电磁辐射器件的方向性、带宽,并可重构天线的工作频率、偏振态等性能.     

Diffraction of white-light supercontinuum by femtosecond laser-induced transient grating in carbon bisulfide

Experiments on fs laser-induced transient grating (LITG) in carbon bisulfide (CS2 ) are carried out to explore the chirp characteristics of a white-light supercontinuum (SC) generated by a 800-nm, 160-fs laser pulse in a 4-mm thick Al2O3 crystal. Two orders of diffraction signals of SC by fs LITG in CS2 are observed, demonstrating that both the third-order process and the fifth-order process are present simultaneously. The experimental results also imply that the formation of an fs transient refractive-index grating in CS2 is mainly due to the electronic polarization process.     

Kα波段介质加载回旋行波管小信号分析与设计

应用分析回旋行波管绝对不稳定性的Briggs-Bers相碰判据与小信号色散方程,并结合介质加载波导的冷场分析,通过数值计算比较了不同介质加载条件下回旋行波管工作模式的起振电流与寄生模式的起振长度,通过改变加载介质的特性参数从而增加行波损耗可以显著提高工作模式起振电流,并抑制掉寄生模式的返波振荡.结合介质加载波导冷场分析与回旋行波管小信号色散方程,分析了介质加载条件下回旋行波管小信号增益,给出了不同介质加载条件下的回旋行波管的小信号增益带宽曲线.在对介质回旋行波管自激振荡与小信号增益的综合分析基础上,对Kα 关键词： Kα波段介质加载回旋行波管 绝对不稳定性 自激振荡 小信号增益     

Noise Characteristics of Optocouplers on Neutron Radiation

Neutron dose radiation experiment is designed to study the optocoupler's displacement effects and the noise characteristics. The burst noise is introduced in optocouplers on neutron radiation, which is indicated from experiments. With the increasing neutron radiation the displacement defects in space-charge region increase, the scattering enhances and the noise signal mutations increase. All these represent the noise time series mutations, the random pulses and the increasing noise complexity. The burst noise becomes evident, and the power spectrum density, the characteristic frequency and the fractal dimension of time series of noise greatly increase.     

A Three-dimensional Zn~(Ⅱ) Based Coordination Polymer with 2-Fold Interpenetrated Topology Displaying Luminescent Property

A new coordination polymer, [Zn2(m-bix)(p-bdc)2](1), was synthesized under hydrothermal conditions by a reaction of 1,3-bis(imidazol-1-ylmethyl)benzene(m-bix), 1,3-benzenedicarboxylic acid(H2p-bdc) and Zn(NO3)2. The colorless block crystals of complex 1(C30H22N4O8Zn2) belong to the triclinic system, space group P1 with a = 10.213(2), b = 12.052(2), c= 12.392(3) A, α = 82.97(3), β = 76.04(3), γ = 78.02(3)o, V = 1443.8(5) A3, Z = 2, Dc = 1.604 g/cm-3,Mr = 697.26, F(000) = 708, R = 0.0403 and w R = 0.0907 for 4886 observed reflections(I 2σ(I)). In1, the tetrahedral ZnI I cations are linked by [p-bdc]2– anions into 2D sq1 networks, which are further connected by bix ligands forming an interesting 2-fold 4,4-connected mog-type 3D network with a point symbol of {4·64·8}2{42·62·82}. Complex 1 was characterized by elemental, IR spectroscopy,powder X-ray diffractions and thermalgravimetric analysis. In addition, complex 1 exhibits coordination induced photoluminescent property.     

4-(1,2,4-三唑-5-酮-4-基)-3-硫代脲酸乙酯的合成、晶体结构及理论计算

4-氨基-1,2,4-三唑-5-酮(ATO)与硫氰酸钾、氯甲酸乙酯在乙酸乙酯中反应, 合成了4-(1,2,4-三唑-5-酮-4-基)-3-硫代脲酸乙酯, 在室温下采用缓慢蒸发溶剂二甲基甲酰胺得到合适的可用于X射线衍射的单晶. 晶体属六方系, 空间群为R-3, 晶体结构参数为a＝2.60524(7) nm, b＝2.60524(7) nm, c＝0.82579(6) nm, γ＝120°, V＝4.8540(4) nm³, D_c＝1.442 g/cm³, μ＝0.300 mm^－1, F(000)＝2190, Z＝18, R₁＝0.0569, wR₂＝0.1424. 选取标题化合物的一个结构单元作为初始模型, 运用Gaussian 03程序对化合物进行了HF/6-311G, MP2/6-311G和B3LYP/6-311G水平的几何全优化，并对其原子电荷及自然键轨道(NBO)进行了分析.     

卟啉-Salen化合物对含氮杂环客体的分子识别

A novel porphyrin-salen compound and corresponding zinc(Ⅱ)porphyrin-salen compound(ZnPSC_(10))cova-lently linked by a flexible alkoxy chain(—O(CH)_(10)O—)have been synthesized and characterized.Molecular rec-ognition of three N-heterocyclic guests,pyridine,1,4-diazobycyclo[2,2,2]octane(DABCO)and pyrazine,with thehost ZnPSC_(10)was investigated.Binding constants were determined by means of UV-vis titration method.Thebinding mode of ZnPSC_(10)with DABCO has been discussed in detail by using ~1H NMR.It was found that the con-formations of the recognition system changed from closed to open with the adding of DABCO.