蒸馏沉淀聚合过程中交联度对单分散聚合物微球形成的影响

以苯乙烯为单体、二乙烯基苯(DVB)为交联剂,过氧化二苯甲酰(BPO)为引发剂研究了蒸馏沉淀聚合法制备聚合物微球过程中交联单体二乙烯苯的用量对单分散聚合物微球成球的影响.结果表明,增加二乙烯基苯的比例,即提高交联度有利于形成单分散的聚合物微球.     

含4-氨基哌啶片段的6,7-二甲氧基喹啉衍生物的合成及抗肿瘤活性

以2-氨基-4,5-二甲氧基苯甲酸（2）和环酮（环戊酮、环己酮）为原料,在三氯氧磷作用下“一锅法”合成6,7-二甲氧基喹啉中间体（3）,再与4-氨基哌啶或4-异丙基-1-氨基环己烷（4）发生Buchwald-Hartwig偶联反应,得到含有4-氨基哌啶或4-异丙基-1-氨基环己烷片段的6,7-二甲氧基喹啉衍生物（1a～1f）,产物及中间体结构通过¹H NMR、¹³C NMR、MS及元素分析进行表征。初步抗肿瘤活性测试表明,所合成化合物对HepG2、MCF-7、PC3和HeLa均有明显的抑制活性,尤其是化合物1b展现出较强的MCF-7抑制活性(IC₅₀ =11.2μmol/L),甚至强于当前乳腺癌的一线治疗药物4-羟基他莫昔芬(IC₅₀ =15.1μmol/L);此外,标题化合物对正常的乳腺上皮细胞MCF-10A没有毒性。     

逻辑函数高阶布尔e偏导数求解算法的实现

针对已有方法在求解布尔e偏导数时只能解决小规模电路的问题,提出了一种基于逻辑函数不相交运算的大函数高阶布尔e偏导数的求解算法.该方法将逻辑函数转化为不相交乘积项的集合,用逻辑函数的不相交运算替代布尔e导数运算中的逻辑“与”运算;并将不包含待求导变量的乘积项拆分出来,不参与布尔e导数运算,以达到降低算法复杂度、提高算法速度的目的.提出的算法用C语言编程实现,并用MCNC测试电路进行了测试.实验结果显示,本算法能快速实现大函数高阶布尔e偏导数的求解,求解效率与参与不相交运算的乘积项数量有关,但对输入变量的数量不敏感.     

Catalytic properties of carboxylic acid functionalized-polymer microsphere-stabilized gold metallic colloids

Polymer-microsphere-stabilized gold metallic colloids have been prepared by a novel strategy of simple and convenient reduction of the metallic salt through the stabilization of the active carboxylic acid group on the gel and surface layer of the microsphere. The nature of the interaction between the carboxylic acid and Au nanoparticles was studied in detail by XPS. Preliminary results indicate that polymer-microsphere-stabilized gold colloids are active catalysts for the reduction of 4-nitrophenol to 4-aminophenol with sodium borohydride as reductant. The catalytic properties of the stabilized catalyst for recycling were also investigated.     

Electrospinning Synthesis and Photoluminescence Properties of SnO2：xEu3＋ Nanofibers

NnO2：xEu3＋（x=O, 1%, 3%, 5%, molar fraction） fibers were synthesized by electrospinning technology. The size of the as-prepared fibers is relatively uniform and the average diameter is about 200 nm with a large draw ratio. The as-prepared Eu3＋ doped SnO2 nanofibers have a rutile structure and consist of crystallitc grains with an average size of about 10 nm. A slight red shift of the A1gand Bag vibration modes and an additional peak at 288 nm were observed in the Raman spectra of the nanofibers. The energies of bandgaps of the SnO2 nanofiber with Eu doping of 1% and 3% are 2.64 eV, and the energy of bandgap is 2.94 eV with Eu doping of 5%（molar fraction）. There is only orange emission（5D0→7F1 magnetic dipole transition） for Eu doped SnO2 nanofibers, and no red emission could be observed. The orange emission upon indirect excitation splits into three peaks and the peak intensity at the excitation wavelength of 275 nm is higher than that at the excitation wavelength of 488 nm.     

Impact of silicon dopant on the absorption and Raman spectroscopy of metal clusters with seven atoms

The structural, optical, and magnetic properties of silicon-doped copper, silver, and gold clusters with D_5h symmetry and seven atoms have been investigated using density functional theory calculations. The global optimized structures of silicon-doped metal clusters are predicted to have a higher HOMO–LUMO gap and higher binding energy than nondoped metal clusters, and nondoped metal clusters have a higher magnetic moment than silicon-doped metal clusters. The silicon doping in metal clusters changes absorption strength and range of absorption wavelength. The silicon dopant also provides a significant impact on the absorption and Raman spectroscopy of nondoped metal clusters. The Raman activities of silicon-doped and nondoped metal clusters are helpful in determining the size and structure of the experimental clusters.     

Spectral indices to assess the carotenoid/chlorophyll ratio from adaxial and abaxial leaf reflectance

The ratio between the carotenoid and chlorophyll concentrations can indicate the physiology and phenology of plants. Most of the vegetation indices related to the ratio between the carotenoid and chlorophyll contents only consider the reflectance from the adaxial leaf surface. In this study, it was found that the leaf reflectance from the abaxial surface is lower than that of the adaxial surface in the visible wavelength region. On the contrary, the reflectance is higher on the adaxial surface in the near-infrared wavelength region. The difference ratio index resulted in the best correlation with the carotenoid/chlorophyll ratio and was the most robust among all the spectral indices studied when the spectral information on the adaxial and abaxial surfaces was pooled. The result indicated that this index can accurately estimate the carotenoid/chlorophyll ratio because of the insensitivity to the differences between adaxial and abaxial leaf surfaces.     

YBCO带材低熔点焊接接头研究进展

以YBa_(2)Cu_(3)O_(7)(YBCO)带材为代表的二代高温超导带材被广泛应用于各类超导装备中,由于YBCO超导带材生产长度的限制,其接头技术将在带材的实用化发展中起到至关重要的作用,其中低熔点焊料焊接接头技术由于其工艺简单且能够满足目前二代高温超导材料的应用需求,成为现阶段接头制备的主流技术.本文基于YBCO基本属性,结合目前国内外的YBCO带材生产现状,系统全面地调研了低熔点焊料焊接接头技术的制作工艺及其性能的影响因素,明确了低熔点焊料焊接接头的关键影响因素,梳理了二代高温超导带材接头的焊接工艺流程,为二代高温超导带材接头的制备提供参考。     

共焦波导结构回旋行波管的设计与仿真

针对0.14 THz大气窗口,利用CST微波工作室和3维粒子模拟软件,对共焦波导结构的太赫兹回旋行波管进行了冷腔色散和注波互作用的模拟研究。以TE06模式作为互作用工作模式,在电压为35 kV、电流为2 A、横纵速度比为0.85的电子束参数下,当输入信号为1 W时,得到最高2 kW的微波功率输出,3 dB带宽为3.5 GHz,增益为30 dB。     

基于统计最优和波叠加的联合局部近场声全息

提出了一种基于统计最优近场声全息和波叠加法的联合局部近场声全息技术。首先利用两次统计最优近场声全息的声源定位结果来指导配置等效源,其后利用波叠加法进行局部声场重构。该技术适合于中低频声场的局部重建,计算快速,重建精度高;可以在测量数据有缺失的情况下重建声场。进行了脉动球声源模型的数值仿真,并在半消声室内对电机噪声源进行了实验,仿真实验都准确地重构了声源所辐射的外部声场。该技术可以重建任意类球形声源辐射的声场。