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991.
Self-assembly of positively charged and charge-neutral tridentate cyclometalated platinum(II) complexes leads to nanowires and the drop-cast film containing these nanowires behaves as a n-type semiconductor. 相似文献
992.
Hong R Fernández JM Nakade H Arvizo R Emrick T Rotello VM 《Chemical communications (Cambridge, England)》2006,(22):2347-2349
Place exchange reactions were studied using dye displacement: subtle changes in ligand structure greatly affected both the rate of displacement and the stability of the monolayer. 相似文献
993.
Gómez-Zavaglia A Kaczor A Cardoso AL Pinho e Melo TM Fausto R 《The journal of physical chemistry. A》2006,110(26):8081-8092
The structure, preferred conformers, vibrational spectrum, and photochemical behavior of the novel azirine, methyl 2-chloro-3-methyl-2H-azirine-2-carboxylate (MCMAC) were investigated in low-temperature matrixes and in the neat solid amorphous state by infrared spectroscopy and quantum-chemical calculations. Two conformers of the compound were observed in argon, krypton, and xenon matrixes, in agreement with the DFT(B3LYP)/6-311++G(d,p) and MP2/6-311++G(d,p) theoretical calculations. Both conformers were found to exhibit the carboxylic ester group in the cis conformation, differing in the arrangement defined by the O=C-C-Cl dihedral angle (cis and trans, for Ct and Cc forms, respectively). The Ct conformer was found to be the most stable conformer in the gaseous phase as well as in both argon and krypton matrixes, whereas the more polar Cc conformer became the most stable form in the xenon matrix and in the neat solid amorphous phase. In situ broadband UV (lambda > 235 nm) excitation of matrix-isolated MCMAC led to azirine ring C-C and C-N bond cleavages, the latter process corresponding to the most efficient reaction channel. The photochemical cleavage of the C-N bond had never been previously observed in the case of aliphatic 2H-azirines. Two electron withdrawing substituents (methoxycarbonyl group and chlorine atom) are connected to the azirine ring in the novel MCMAC azirine. The simultaneous presence of these two groups accelerates intersystem crossing toward the triplet state where cleavage of the C-N bond takes place. The primary photoproducts resulting from the C-N and C-C ring-opening reactions were also found to undergo further photochemical decarbonylation or decarboxylation reactions. 相似文献
994.
995.
996.
We investigate the shot noise of electron transport through an Aharonov-Casher ring subject to the Rashba spin-orbit coupling (SOC). Analytic expressions for the coefficients of reflection and transmission are derived by using the Griffith boundary conditions. For this kind of SOC, the ballistic transport of electrons can be analyzed as two independent spin channels, and both of them have the same transmission and reflection coefficients. The dependences of shot noise and Landauer-Biittiker conductance on controllable factors, including the strength of Rashba SOC, the asymmetrical angle of lead-connection positions, the radius of the rings, and the wave vector (or energy) of the incident Fermi electrons, are explicitly described by some new combined parameters. The ways that the shot noise and conductance vary with Rashba SOC and with asymmetrical angle are demonstrated by numerical simulations, respectively. It is revealed that the shot noise reaches its maximum for the particular situation of half transmission and half reflection and zero shot noise occurs at conductance maxima. 相似文献
997.
A novel differential-phase-shift-keying (DPSK)/pulse-position-modulation (PPM) orthogonal modulation is pro- posed for optical labeling applications, with PPM data as the high-speed payload and DPSK signal as the optical label. The systematic setup for the proposed scheme and research on bit-error rate is presented. The results show that at the bit-error rate of 10-~, the power penalties for 70kin fiber transmission are in the range of 1-3 dB to DPSK label and 5-6 dB to PPM payload in our simulation system. This is under the condition that the large extinction ratio of 18-19 dB is used for the intensity modulators of the PPM payload, with a well received DPSK label. Thus the feasibility of the proposed scheme for all optical transmission networks is clearly verified. 相似文献
998.
Generation and Quantum Interference of Entangled Electron-Hole Pairs in a Hanbury Brown and Twiss Interferometer 下载免费PDF全文
The Hanbury Brown-Twiss interferometer is proposed to serve as a detector of the crossed Andreev reflection and to generate entangled electron-hole pairs. It is shown that the non-local electron and hole induced by the crossed Andreev reflection are entangled. Quantum interference of the entangled electron-hole pairs gives rise to a new measurable effect of the phase difference between two superconductors in the cross correlation. The present theoretical predictions can be experimentally realized within the present-day microelectronic technology. 相似文献
999.
The conversion of the frequency modulated pulse induced from frequency modulation (FM) to amplitude modulation (AM) by the polarization mode dispersion (PMD) is theoretically and experimentally investigated. When there is no polarizer at the output end of a fiber system, the amplitude modulation depth is stable by 8%. Random amplitude modulation is observed when a polarizer is placed at the output end of the fiber system. The observed minimum and maximum modulation depths in our experiment are 5% and 80%, respectively. Simulation results show that the amplitude modulation is stable by 4% induced mainly by group velocity dispersion (GVD) when there is no polarizer, and the amplitude modulation depth displays the random variation character induced by the GVD and PMD. Lastly, a new fiber system scheme is proposed and little amplitude modulation is observed at the top of the output pulse. 相似文献
1000.
We compute the analytic expression of the probability distributions FAEX,+ and FAEX,− of the normalized positive and negative AEX (Netherlands) index daily returns r(t). Furthermore, we define the α re-scaled AEX daily index positive returns r(t)α and negative returns (−r(t))α, which we call, after normalization, the α positive fluctuations and α negative fluctuations. We use the Kolmogorov-Smirnov statistical test as a method to find the values of α that optimize the data collapse of the histogram of the α fluctuations with the Bramwell-Holdsworth-Pinton (BHP) probability density function. The optimal parameters that we found are α+=0.46 and α−=0.43. Since the BHP probability density function appears in several other dissimilar phenomena, our result reveals a universal feature of stock exchange markets. 相似文献