全文获取类型
收费全文 | 3486篇 |
免费 | 357篇 |
国内免费 | 139篇 |
专业分类
化学 | 2802篇 |
晶体学 | 31篇 |
力学 | 76篇 |
综合类 | 7篇 |
数学 | 332篇 |
物理学 | 734篇 |
出版年
2023年 | 55篇 |
2022年 | 52篇 |
2021年 | 150篇 |
2020年 | 113篇 |
2019年 | 131篇 |
2018年 | 126篇 |
2017年 | 77篇 |
2016年 | 177篇 |
2015年 | 147篇 |
2014年 | 183篇 |
2013年 | 255篇 |
2012年 | 285篇 |
2011年 | 318篇 |
2010年 | 201篇 |
2009年 | 162篇 |
2008年 | 243篇 |
2007年 | 198篇 |
2006年 | 211篇 |
2005年 | 177篇 |
2004年 | 151篇 |
2003年 | 98篇 |
2002年 | 90篇 |
2001年 | 35篇 |
2000年 | 27篇 |
1999年 | 51篇 |
1998年 | 29篇 |
1997年 | 32篇 |
1996年 | 44篇 |
1995年 | 14篇 |
1994年 | 11篇 |
1993年 | 11篇 |
1992年 | 14篇 |
1991年 | 8篇 |
1990年 | 10篇 |
1989年 | 6篇 |
1988年 | 10篇 |
1987年 | 9篇 |
1985年 | 7篇 |
1984年 | 12篇 |
1981年 | 4篇 |
1979年 | 3篇 |
1978年 | 6篇 |
1977年 | 5篇 |
1976年 | 3篇 |
1974年 | 3篇 |
1971年 | 2篇 |
1969年 | 3篇 |
1968年 | 2篇 |
1964年 | 2篇 |
1960年 | 3篇 |
排序方式: 共有3982条查询结果,搜索用时 32 毫秒
11.
Qingfa Wang Li Wang Yaquan Wang Fei He Zhenhua Li Zhentao Mi 《Reaction Kinetics and Catalysis Letters》2004,81(2):297-304
Deactivated palladium catalysts in the hydrogenation of anthraquinione were regenerated with ethanol, nitric acid, hydrogen
peroxide, boiling water and steam, respectively. The deactivated and regenerated catalysts were characterized by XPS, ICP,
TG, FTIR, TPD, XRD, etc., and studied in the hydrogenation of anthraquinone. The results showed that the main cause of catalyst deactivation is the
coverage of the active component by deposits. The treatments by hydrogen peroxide and boiling water can effectively regenerate
the deactivated catalysts.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
12.
V. V. Panić A. B. Dekanski S. K. Milonjić V. B. Mišković-Stanković B. Ž. Nikolić 《Russian Journal of Electrochemistry》2006,42(10):1055-1060
Electrocatalytic properties of RuO2/Ti anode with different coating masses, which are prepared by the alkoxide sol-gel procedure, are investigated in chlorine
and oxygen evolution reactions by polarization measurements and electrochemical impedance spectroscopy in H2SO4 and NaCl electrolytes. According to polarization measurements, the activity of anodes at overpotentials below 100 mV is independent
of coating mass. However, impedance measurements above 100 mV reveal changes in the activity of anodes in chlorine evolution
reaction for different coating masses. The diffusion limitations related to the evolved chlorine are registered in low-frequency
domain at 1.10 V (SCE), diminishing with the increase in potential to the 1.15 V (SCE). The observed impedance behavior is
discussed with respect to the activity model for activated titanium anodes in chlorine evolution reaction involving formation
of gas channels within porous coating structure. Gas channels enhance the mass transfer rate similarly to the forced convection,
which also increases the activity of anode. This is more pronounced for the anode of greater coating mass due to its more
compact surface structure. The more compact structure appears to be beneficial for gas channels formation.
Published in Russian in Elektrokhimiya, 2006, Vol. 42, No. 10, pp. 1173–1179.
The text was submitted by the authors in English. 相似文献
13.
14.
In this paper we discuss farthest-point problems in which a set or sequence S of n points in the plane is given in advance and can be preprocessed to answer various queries efficiently. First, we give a data structure that can be used to compute the point farthest from a query line segment in O(log2n) time. Our data structure needs O(nlogn) space and preprocessing time. To the best of our knowledge no solution to this problem has been suggested yet. Second, we show how to use this data structure to obtain an output-sensitive query-based algorithm for polygonal path simplification. Both results are based on a series of data structures for fundamental farthest-point queries that can be reduced to each other. 相似文献
15.
Mi Jung Lee 《Tetrahedron letters》2006,47(8):1355-1358
A new and regioselective [4+2] benzannulation protocol toward polysubstituted benzenes was developed. Nitroalkane derivative, which was prepared from Baylis-Hillman adduct, served as the four-carbon unit and Michael acceptor as a two-carbon unit. 相似文献
16.
In this paper, we give a convergence theorem and error estimates for an iteration method under new Kantorovitch-Ostrowski type condition using the information of higher derivatives at initial points. Compared with the corresponding study in [3],the convergence determination is established under one global condition, instead of two , on the function. 相似文献
17.
Xinhua Liang Zhentao Mi Yaquan Wang Li Wang Xiangwen Zhang 《Reaction Kinetics and Catalysis Letters》2004,82(2):333-337
The ammoximation of acetone to acetone oxime with 30 wt.% hydrogen peroxide over TS-1 has been studied. The conversion of
acetone and the selectivity to acetone oxime can reach 99% and 94%, respectively. The by-products are the corresponding hydrazone,
imine and small amounts of unidentified compounds. The influence of various parameters such as solvent, temperature, amounts
of catalyst and the NH3 to acetone molar ratio were investigated.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
18.
The non-resonant third-order non-linear optical properties of amorphous Ge20As25Se55 films were studied experimentally by the method of the femtosecond optical heterodyne detection of optical Kerr effect. The real and imaginary parts of complex third-order optical non-linearity could be effectively separated and their values and signs could be also determined, which were 6.6 × 10−12 and −2.4 × 10−12 esu, respectively. Amorphous Ge20As25Se55 films showed a very fast response in the range of 200 fs under ultrafast excitation. The ultrafast response and large third-order non-linearity are attributed to the ultrafast distortion of the electron orbitals surrounding the average positions of the nucleus of Ge, As and Se atoms. The high third-order susceptibility and a fast response time of amorphous Ge20As25Se55 films makes it a promising material for application in advanced techniques especially in optical switching. 相似文献
19.
Enantioselective catalytic trimethylsilylcyanations of aldehydes with 48% to 92% e.e. have been studied using the novel Ti-chiral Schiff base complexes. We have found that the catalyst led to high enantoselectivity when the molar ratio of the Schiff base 1 to Ti(O-i-Pr)4 was 2:1. 相似文献
20.
报道了FTS-20F富里叶红外光谱仪数据系统改造的工作采用IBM486计算机及新的数据接口取代了陈旧的NOVA4数据系统,文章详细描述了其硬件设计和软件编辑,改造不仅更新了FTS-20E里叶红外光谱仪,而且还使其达到90年代的水平。 相似文献