全文获取类型
收费全文 | 5795篇 |
免费 | 1087篇 |
国内免费 | 801篇 |
专业分类
化学 | 4317篇 |
晶体学 | 102篇 |
力学 | 363篇 |
综合类 | 45篇 |
数学 | 701篇 |
物理学 | 2155篇 |
出版年
2024年 | 16篇 |
2023年 | 133篇 |
2022年 | 195篇 |
2021年 | 241篇 |
2020年 | 333篇 |
2019年 | 294篇 |
2018年 | 264篇 |
2017年 | 279篇 |
2016年 | 342篇 |
2015年 | 372篇 |
2014年 | 341篇 |
2013年 | 479篇 |
2012年 | 545篇 |
2011年 | 537篇 |
2010年 | 395篇 |
2009年 | 374篇 |
2008年 | 388篇 |
2007年 | 320篇 |
2006年 | 308篇 |
2005年 | 261篇 |
2004年 | 213篇 |
2003年 | 151篇 |
2002年 | 160篇 |
2001年 | 111篇 |
2000年 | 103篇 |
1999年 | 100篇 |
1998年 | 39篇 |
1997年 | 46篇 |
1996年 | 40篇 |
1995年 | 34篇 |
1994年 | 13篇 |
1993年 | 30篇 |
1992年 | 23篇 |
1991年 | 16篇 |
1990年 | 12篇 |
1989年 | 10篇 |
1988年 | 19篇 |
1986年 | 15篇 |
1985年 | 16篇 |
1984年 | 11篇 |
1983年 | 6篇 |
1982年 | 14篇 |
1980年 | 6篇 |
1979年 | 11篇 |
1978年 | 8篇 |
1977年 | 5篇 |
1976年 | 7篇 |
1975年 | 7篇 |
1974年 | 5篇 |
1973年 | 5篇 |
排序方式: 共有7683条查询结果,搜索用时 15 毫秒
91.
KaiKANG ChengYouKAN YiDU YuZhongLI DeShanLIU 《中国化学快报》2005,16(6):831-834
Soap-flee P(MMA-EA-MAA) particles with narrow size distribution were synthesized by seeded emulsion polymerization of methyl methacrylate (MMA), ethyl acrylate (EA) and methacrylic acid (MAA), and large voids inside the particles were generated by alkali posttreatment in the presence of 2-butanone. Results indicated that the size of void and theparticle volume were related with the amount of 2-butanone. The generation mechanism of voids was proposed. 相似文献
92.
93.
Based on density functional calculations, the mechanism and the energetic course of the chemical vapor deposition (CVD) reaction of TiCl4 with NH3 were studied at the level of B3LYP with 6-311g(d) basis set. Furthermore, the polymerization processes of dimerization, trimerization and tetramerization were investigated. The calculation results indicate that the formation of polymers is favored at the elimination reaction. On the basis of the calculated energetics, a possible mechanism of the reduction reaction has been proposed. 相似文献
94.
Jun WANG Kai Ying LIU Li WANG Ji Ling BAI 《中国化学快报》2006,17(1):49-52
The techniques of combinatorial chemistry have recently been applied to the discovery of new asymmetric catalyst for a variety of organic transformations1-3. Using combina- torial methods, it is straightforward to generate thousands of potential asymmetri… 相似文献
95.
热脱附/冷阱聚焦/气相色谱/质谱法卷烟香气分析 总被引:1,自引:0,他引:1
利用热脱附装置(TDS)对烟丝粉末进行快速升温,模拟卷烟燃吸过程中蒸馏区的部分反应,用冷阱收集所脱附的物质,以GC/MS对进行定性分析.成功的分离出了有机酸、饱和烃、芳香烃、烯烃以及含氮、氧杂原子的化合物等系列超过100种有机化合物,并且还发现了典型的存在于环境中的化学污染物——邻苯二甲酸二丁酯. 相似文献
96.
97.
98.
Kakiuchi K Okada H Kanehisa N Kai Y Kurosawa H 《The Journal of organic chemistry》1996,61(9):2972-2979
Acid-catalyzed rearrangement of 5-cyclopentylidenecyclooctanone derivatives 9a-c was examined to obtain polyspiropolyquinanes 11a-c, considered to have a unique helical structure, through cascade rearrangement pathways consisting of continuous transannular cyclization followed by successive 1,2-alkyl shifts. The substrates were prepared easily by use of the Wittig or McMurry reaction. Reaction of the 5-cyclopentylidenecyclooctanone (9a) with acid gave the expected dispirotriquinane ketone 11a in high yield. The precise mechanism was elucidated by a deuterium-labeling experiment. In the case of the ketone 9b, having another spiroannulated cyclopentane ring attached on 9a, the trispirotetraquiane 11b was not obtained but the bis-propellane-type tetrahydrofuran 25 was produced exclusively. The 5-(5'-cyclopentylidenecyclooctylidene)cyclooctanone (9c) afforded the polycyclic compounds 27-31, depending on the acid used, instead of the desired tetraspiropentaquinane 11c. The structures of the products were determined by NMR spectral data including 2D (13)C INADEQUATE spectra and X-ray crystallographic analyses. The unexpected rearrangement pathways are also discussed. 相似文献
99.
Let (S)⊄L
2(S′(∔),μ)⊄(S)* be the Gel'fand triple over the white noise space (S′(∔),μ). Let (e
n
,n>-0) be the ONB ofL
2(∔) consisting of the eigenfunctions of the s.a. operator
. In this paper the Euler operator Δ
E
is defined as the sum
, where ∂
i
stands for the differential operatorD
e
i. It is shown that Δ
E
is the infinitesimal generator of the semigroup (T
t
), where (T
t
ϕ)(x)=ϕ(e
t
x) for ϕ∈(S). Similarly to the finite dimensional case, the λ-order homogeneous test functionals are characterized by the Euler equation:
Δ
Eϕ
=λϕ. Via this characterization the λ-order homogeneous Hida distributions are defined and their properties are worked out.
Supported by the National Natural Science Foundation of China. 相似文献
100.
Determination of antibiotics such as macrolides,ionophores and tiamulin in liquid manure by HPLC–MS/MS 总被引:2,自引:0,他引:2
Michael?P.?SchlüsenerEmail author Kai?Bester Michael?Spiteller 《Analytical and bioanalytical chemistry》2003,375(7):942-947
A method for the analysis of several macrolide and ionophore antibiotics as well as tiamulin in liquid manure was developed. Reversed-phase liquid chromatography and atmospheric pressure chemical ionisation (APCI) tandem mass spectrometry was used for detection.High-performance liquid chromatographic (HPLC) separation of the antibiotics was achieved in 35 min. The analytes were extracted with ethyl acetate and the extracts were cleaned up by solid-phase extraction on a diol SPE cartridge. Recovery experiments with spiked liquid manure concentrations varying from 6 to 2,000 microg kg(-1) gave constant recovery rates. The recovery rates for the macrolides erythromycin, roxithromycin and oleandomycin were 75-94%, that for the ionophore salinomycin was 119%, while that for the pleuromutilin tiamulin was 123%, when using a macrolide internal standard. The relative standard deviation was found to be 15-36% and the limits of detection were 0.4-11.0 micro g kg(-1).The maximum concentrations found in manure samples were 43 micro g kg(-1) for tiamulin and 11 micro g kg(-1) for salinomycin. 相似文献