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991.
Teng Bao Jie Jin Mekdimu Mezemir Damtie Ke Wu Zhi Ming Yu Lie Wang Jun Chen Yong Zhang Ray L. Frost 《Journal of Saudi Chemical Society》2019,23(7):864-878
A zero-valent iron/rectorite nanocomposite (NZVI/rectorite) was developed as a heterogeneous H2O2 catalyst for P-chlorophenol degradation. The physicochemical properties of NZVI/rectorite were characterized by various techniques including X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy-dispersive spectrometry, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and Brunauer–Emmett–Teller analysis. Results showed that NZVI sphere nanoparticles were successfully loaded on the rectorite surface with less aggregation and good dispersion. Moreover, compared with acid-leached rectorite (30.91 m2/g), the NZVI/rectorite appeared to have larger surface area (50.75 m2/g). In addition, the effects of pH, reaction time, initial P-chlorophenol concentration, catalyst amount, and H2O2 dosage on the P-chlorophenol degradation were systematically investigated. Results showed that NZVI/rectorite presents better properties for the degradation and mineralization of P-chlorophenol compared with pristine NZVI due to the large surface area, low aggregation, and good dispersion of the former. The degradation mechanisms of P-chlorophenol by NZVI/rectorite were adsorption and reduction coupled with a Fenton-like reaction. Four successive runs of the stability and regeneration study also showed that the NZVI/rectorite were unchanged even after 100% of P-chlorophenol degradation ratio. This study has extended the application of NZVI/rectorite as environment function material for the removal of P-chlorophenol from the environment. 相似文献
992.
采用溶剂蒸发技术,辅以氩保护气氛,成功获得厘米级氯掺杂γ-CuI透明单晶.研究了氯掺杂对晶体生长溶液的稳定性、晶体结构及发光性能的影响.通过引入氩气氛,掺氯生长液及晶体的氧化问题得到了极大改善.X射线激发发射光谱表明,γ-CuI:Cl晶体的超快近带边发射得到显著增强,光输出约为PbWO4晶体的89;,深能级发射强度也受到极大抑制.并且快成分的衰减时间达到亚纳秒量级.实验结果均表明γ-CuI:Cl单晶具有较好的结晶性和光学性能,有望应用于超高辐射检测和超快计数率成像领域. 相似文献
993.
The spin Hamiltonian parameters (SHPs) and the local structures for impurity W5+ in the Zn3(PO4)2ZnO nanopowders doped with WO3 under different concentrations are theoretically investigated using the perturbation calculations of these parameters. The exponential functions of the related quantities (cubic field parameter Dq, covalency factor N, relative tetragonal compression ratio τ and core polarisation constant κ) of concentration x with totally four adjustable coefficients a, b, c and d are adopted to fit the concentration dependences of the experimental d-d transition bands and SHPs. The impurity W5+ centres demonstrate moderate tetragonal compression ratios τ (~3.1%) due to the Jahn–Teller effect. With the increase of WO3 concentration, Dq and N show moderately decreasing rules, while τ and κ exhibit slightly and moderately increasing tendencies with x, respectively. The mechanisms of the above concentration dependences of these quantities are analysed from the modifications of the local crystal-field strength and electron cloud density around the impurity W5+ with the variation of x. Present theoretical studies would be useful to the exploration of the structural properties and optical applications for WO3 doped Zn3(PO4)2ZnO nanopowders. 相似文献
994.
EFFECT OF THE SUBSTITUTION OF Ga AND Sn FOR Cu ON THE ELECTRONIC STRUCTURE AND SUPERCONDUCTIVITY OF La1.85Sr0.15CuO4 下载免费PDF全文
The electronic structure of La1.85Sr0.15CuO4, as well as the two cases of substitution of Ga and Sn for Cu, has been studied by the recursion method. The change of hole concentration and the effective local magnetic moment have also been calculated. Our calculations show that Ga and Sn destroy the two-dimensional character of the CuO2 plane and lead to the disorder of the electronic structure, accompanied by the migration of electrons which canines the decrease of the hole concentration in the CuO2 planes. From our point of view, these changes may be responsible for the destruction of superconductivity of the Ga and Sn-doped systems. 相似文献
995.
以NiFeNb为种子层,制备(Ni79Fe21)1-xNbx(5nm)/(Ni79Fe21) (20nm)/Ta(3nm)系列膜,并对其颗粒大小、 磁滞回线及表面粗糙度等进行测量,探讨种子层中Nb含量x对坡莫合金磁滞回线的影响.结果 表明,以NiFeNb作种子层能更好地改善坡莫合金的微结构. Nb含量为23%时的磁滞回线有最 小的最大磁能积、矫顽力.种子层影响坡莫合金磁滞回线的一个重要原因是脱附激活能等因 素造成种子层具有不同的表面粗糙度,进而使坡莫合金具有不同的微结构和磁性能.
关键词:
NiFeNb种子层
坡莫合金
磁滞回线
粗糙度 相似文献
996.
997.
本文讨论具有三个非线性项的Davey-Stewartson方程的散射算子在整个能量空间H~1中存在。 相似文献
998.
999.
重元素高电离的离子特性对研究激光核聚变和X射线激光等都很重要,本文用3d^94s,3d^94d,3d^94p,3d^94f组态相互作用研究了类镍铱离子光谱跃迁。 相似文献
1000.
郝江浩 《数学的实践与认识》2004,34(3):154-158
主要应用 Hopf极值原理 ,对一类非线性四阶椭圆型方程Δ2 u +h( x,u,Δu) =0进行研究 ,得到解的泛函的极值原理 .类似的文章结果也有许多 ,其方法均为构造适当的“P-泛函”,但是以前的结果都对方程有较强的要求限制 .本文通过构造新的泛函 ,减弱了要求限制 .同时对方程Δ2 u +λh( x,u,Δu) =0的特征值给出了估计 . 相似文献