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绿色化学与绿色化学教育 总被引:124,自引:10,他引:114
本文介绍了绿色化学的定义和内涵,绿色化学的 12条原则,“原子经济”概念,绿色化学的研究动态以及实施绿色化学教育的意义和方法。 相似文献
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简要介绍了2009年美国“总统绿色化学挑战奖”的5个获奖项目:伊士曼化学品公司获得更绿色合成路线奖;世界微波化学技术的领导者CEM公司获得了更绿色反应条件奖;Procter&Gamble和Cook Composites&Polymers公司共同分享了设计更绿色化学品奖;绿色能源系统公司获得小企业奖;卡耐基-梅隆大学Matyjaszewski教授获得学术奖。 相似文献
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Areas of fusion and crystallization peaks of K3TaO2F4 and KTaF6 were measured using the DSC mode of a high-temperature calorimeter (SETARAM 1800 K). On the basis of these quantities, considering
the temperature dependence of the calorimeter sensitivity, values of the fusion enthalpy of K3TaO2F4 at the fusion temperature of 1181 K of (43 ± 4) kJ mol−1 and of KTaF6 at the fusion temperature of 760 K of (8 ± 1) kJ mol−1 were determined. 相似文献
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V. M. Novotortsev S. F. Marenkin I. V. Fedorchenko A. V. Kochura 《Russian Journal of Inorganic Chemistry》2010,55(11):1762-1773
The results of studying phase equilibria of ternary AIIBIVCV systems have been reported. Physicochemical foundations have been developed for the synthesis of new ferromagnets with Curie
temperatures above room temperature structurally compatible with basic semiconducting materials. Methods of synthesis and
physicochemical properties of manganese-doped AIIBIVC2V ferromagnets have been described. The results of theoretical simulation of magnetic properties have been considered and basic
approaches to the explanation of the emergence of ferromagnetism in AIIBIVC2V doped with 3d metals have been surveyed. The most promising ways to produce and study dilute magnetic semiconductors as spintronics materials
have been presented. 相似文献
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Areas of fusion and crystallization peaks of K3NbO2F4 were measured using the DCS mode of a high-temperature calorimeter (SETARAM 1800 K). On the basis of these quantities, considering
the temperature dependence of the calorimeter sensitivity, the value of the fusion enthalpy of K3NbO2F4 of (98 ± 6) kJ mol−1 was determined at the fusion temperature of 1257 K. 相似文献
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I. E. Zanin K. B. Aleinikova M. M. Afanasiev M. Yu. Antipin 《Journal of Structural Chemistry》2004,45(5):844-848
The structure of Zn3P2 (P 42/nmc, a = b = 8. 0785 Å, c = 11. 3966 Å) was solved and refined to R = 3. 2% in a precision X-ray diffraction experiment (λ-MoK
a, graphite monochromator on a primary beam, 27,496 reflections) . Interatomic distances and bond angles have been determined. The fcc lattice of the structure is built from phosphorus atoms, and the zinc atoms occupy 3/4 of all tetrahedral voids; the structure is described by two equivalent models where 1/4 occupied (by zinc atoms) and 1/4 vacant voids change places. The zinc atoms that occupy the voids following the diamond principle do not change places.Original Russian Text Copyright © 2004 by I. E. Zanin, K. B. Aleinikova, M. M. Afanasiev, and M. Yu. Antipin__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 889–892, September–October, 2004. 相似文献
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Aleksandra Yu. Tarasova Yu. V. Seryotkin V. M. Pashkov Ludmila I. Isaenko 《Journal of Thermal Analysis and Calorimetry》2011,104(2):795-796
The temperature dependence of unit cell parameters for monoclinic KPb2Cl5 and tetragonal RbPb2Br5 crystals was studied in the range of 100–298 K. Linear and volume thermal expansion coefficients were determined. 相似文献
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科学史奠基者乔治·萨顿在《科学史导论》第二卷的第一部分对我国宋代酿酒著作《北山酒经》予以了简要描述,出现了“spirits”“distillation”等字样;而《北山酒经》被众多学者认为其描述对象是发酵酒(黄酒)。本文从东西方蒸馏技术和相关著作的文本分析对《科学史导论》中提及的蒸馏技术和蒸馏酒存在的可能性提出了质疑。 相似文献
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Russell G. Baughman Kenneth L. Martin Rajendra K. Singh James O. Stoffer 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(2):o103-o106
In 2,4‐dihydroxybenzaldehyde 2,4‐dinitrophenylhydrazone N,N‐dimethylformamide solvate {or 4‐[(2,4‐dinitrophenyl)hydrazonomethyl]benzene‐1,3‐diol N,N‐dimethylformamide solvate}, C13H10N4O6·C3H7NO, (X), 2,4‐dihydroxyacetophenone 2,4‐dinitrophenylhydrazone N,N‐dimethylformamide solvate (or 4‐{1‐[(2,4‐dinitrophenyl)hydrazono]ethyl}benzene‐1,3‐diol N,N‐dimethylformamide solvate), C14H12N4O6·C3H7NO, (XI), and 2,4‐dihydroxybenzophenone 2,4‐dinitrophenylhydrazone N,N‐dimethylacetamide solvate (or 4‐{[(2,4‐dinitrophenyl)hydrazono]phenylmethyl}benzene‐1,3‐diol N,N‐dimethylacetamide solvate), C19H14N4O6·C4H9NO, (XII), the molecules all lack a center of symmetry, crystallize in centrosymmetric space groups and have been observed to exhibit non‐linear optical activity. In each case, the hydrazone skeleton is fairly planar, facilitated by the presence of two intramolecular hydrogen bonds and some partial N—N double‐bond character. Each molecule is hydrogen bonded to one solvent molecule. 相似文献
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L. E. Derlyukova M. V. Vinokurova T. A. Anufrieva 《Russian Journal of Inorganic Chemistry》2008,53(9):1371-1375
The reaction of Bi2O3 + Fe2O3 mixtures with chlorine and SO2 at 250–700°C is studied. At 300–500°C, the degree of bismuth chloride sublimation from the oxide mixture increases in the presence of SO2. Chemical sublimation of FeCl3 occurs after BiCl3 is virtually completely recovered from the solid phase. 相似文献
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The results concerning the synthesis, structure and thermal properties of V2O5-MoO3-Ag2O samples in the vanadium rich region of ternary system are presented in the form of quasi-binary phase diagrams in which
at constant V2O5/MoO3 molar ratios, equal 9:1, 7:3 and 1:1, the content of Ag2O was variable. A new ternary phase isostructural with NaVMoO6 has been detected in the investigated system. 相似文献